{"id":"https://openalex.org/W2008224435","doi":"https://doi.org/10.1002/chem.201203623","title":"Asymmetric Counteranion\u2010Directed Catalytic Hosomi\u2013Sakurai Reaction","display_name":"Asymmetric Counteranion\u2010Directed Catalytic Hosomi\u2013Sakurai Reaction","publication_year":2012,"publication_date":"2012-11-23","ids":{"openalex":"https://openalex.org/W2008224435","doi":"https://doi.org/10.1002/chem.201203623","mag":"2008224435","pmid":"https://pubmed.ncbi.nlm.nih.gov/23180552"},"language":"en","primary_location":{"id":"doi:10.1002/chem.201203623","doi":"https://doi.org/10.1002/chem.201203623","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.201203623","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"http://hdl.handle.net/10251/29585","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5082979214","display_name":"Manuel van Gemmeren","orcid":"https://orcid.org/0000-0003-3080-3579","observed_orcids":["https://orcid.org/0000-0003-3080-3579"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Manuel Mahlau","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 M\u00fclheim an der Ruhr, Germany","Research Department List, Max-Planck-Institut f\u00fcr Kohlenforschung, Max Planck Society"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 M\u00fclheim an der Ruhr, Germany","institution_ids":["https://openalex.org/I4210090782"]},{"raw_affiliation_string":"Research Department List, Max-Planck-Institut f\u00fcr Kohlenforschung, Max Planck Society","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017559071","display_name":"Pilar Garc\u0131\u0301a Garc\u0131\u0301a","orcid":"https://orcid.org/0000-0003-0740-9151","observed_orcids":["https://orcid.org/0000-0003-0740-9151"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Pilar Garc\u00eda\u2010Garc\u00eda","raw_affiliation_strings":["Max-Planck-Institut fu\u0308r Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mu\u0308lheim an der Ruhr (Germany),","Research Department List, Max-Planck-Institut f\u00fcr Kohlenforschung, Max Planck Society"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut fu\u0308r Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mu\u0308lheim an der Ruhr (Germany),","institution_ids":["https://openalex.org/I4210090782"]},{"raw_affiliation_string":"Research Department List, Max-Planck-Institut f\u00fcr Kohlenforschung, Max Planck Society","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5040055598","display_name":"Benjamin List","orcid":"https://orcid.org/0000-0002-9804-599X","observed_orcids":["https://orcid.org/0000-0002-9804-599X"]},"institutions":[{"id":"https://openalex.org/I149899117","display_name":"Max Planck Society","ror":"https://ror.org/01hhn8329","country_code":"DE","type":"nonprofit","lineage":["https://openalex.org/I149899117"]},{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Benjamin List","raw_affiliation_strings":["Max-Planck-Institut fu\u0308r Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mu\u0308lheim an der Ruhr (Germany),","Research Department List, Max-Planck-Institut f\u00fcr Kohlenforschung, Max Planck Society"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut fu\u0308r Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mu\u0308lheim an der Ruhr (Germany),","institution_ids":["https://openalex.org/I4210090782"]},{"raw_affiliation_string":"Research Department List, Max-Planck-Institut f\u00fcr Kohlenforschung, Max Planck Society","institution_ids":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5040055598"],"corresponding_institution_ids":["https://openalex.org/I149899117","https://openalex.org/I4210090782"],"apc_list":{"value":4640,"currency":"USD","value_usd":4640},"apc_paid":null,"fwci":4.5622,"has_fulltext":false,"cited_by_count":83,"citation_normalized_percentile":{"value":0.95358327,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":100},"biblio":{"volume":"18","issue":"51","first_page":"16283","last_page":"16287"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9746000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9746000170707703,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.009499999694526196,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.002300000051036477,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hosomi-sakurai-reaction","display_name":"Hosomi-Sakurai reaction","score":0.9639999866485596},{"id":"https://openalex.org/keywords/asymmetric-catalysis","display_name":"asymmetric catalysis","score":0.8009999990463257},{"id":"https://openalex.org/keywords/lewis-acid-catalysis","display_name":"Lewis acid catalysis","score":0.8119999766349792},{"id":"https://openalex.org/keywords/enantioselective-allylation","display_name":"enantioselective allylation","score":0.699999988079071},{"id":"https://openalex.org/keywords/aromatic-aldehydes","display_name":"aromatic aldehydes","score":0.8059999942779541},{"id":"https://openalex.org/keywords/allylsilanes","display_name":"allylsilanes","score":0.9430000185966492},{"id":"https://openalex.org/keywords/organocatalysis","display_name":"organocatalysis","score":0.6169999837875366}],"concepts":[{"id":"https://openalex.org/C93237805","wikidata":"https://www.wikidata.org/wiki/Q5375227","display_name":"Enantiopure drug","level":4,"score":0.8916095495223999},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.8508137464523315},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.8012396097183228},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6204309463500977},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5064867734909058},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.4931735396385193},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.4194389283657074},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3069034218788147}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1002/chem.201203623","doi":"https://doi.org/10.1002/chem.201203623","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.201203623","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},{"id":"pmid:23180552","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/23180552","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry (Weinheim an der Bergstrasse, Germany)","raw_type":"Journal Article"},{"id":"pmh:oai:pure.mpg.de:item_1584834","doi":null,"is_oa":false,"landing_page_url":"https://hdl.handle.net/11858/00-001M-0000-0010-81E3-5","pdf_url":null,"source":{"id":"https://openalex.org/S4306400654","display_name":"MPG.PuRe (Max Planck Society)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I149899117","host_organization_name":"Max Planck Society","host_organization_lineage":["https://openalex.org/I149899117"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:riunet.upv.es:10251/29585","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/10251/29585","pdf_url":null,"source":{"id":"https://openalex.org/S4306400639","display_name":"RiuNet (Universitat Polit\u00e8cnica de Val\u00e8ncia)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I60053951","host_organization_name":"Universitat Polit\u00e8cnica de Val\u00e8ncia","host_organization_lineage":["https://openalex.org/I60053951"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"pmh:oai:riunet.upv.es:10251/29585","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/10251/29585","pdf_url":null,"source":{"id":"https://openalex.org/S4306400639","display_name":"RiuNet (Universitat Polit\u00e8cnica de Val\u00e8ncia)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I60053951","host_organization_name":"Universitat Polit\u00e8cnica de Val\u00e8ncia","host_organization_lineage":["https://openalex.org/I60053951"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322434","display_name":"Max-Planck-Gesellschaft","ror":"https://ror.org/01hhn8329"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":94,"referenced_works":["https://openalex.org/W143583011","https://openalex.org/W802666831","https://openalex.org/W1964422689","https://openalex.org/W1964819974","https://openalex.org/W1966048979","https://openalex.org/W1966210871","https://openalex.org/W1969641609","https://openalex.org/W1970938769","https://openalex.org/W1971157427","https://openalex.org/W1971675274","https://openalex.org/W1976004881","https://openalex.org/W1979055113","https://openalex.org/W1980824974","https://openalex.org/W1987520492","https://openalex.org/W1990061437","https://openalex.org/W1991994554","https://openalex.org/W1998910384","https://openalex.org/W1999408378","https://openalex.org/W1999443251","https://openalex.org/W1999760120","https://openalex.org/W2009901162","https://openalex.org/W2011529244","https://openalex.org/W2020222397","https://openalex.org/W2022287054","https://openalex.org/W2023224723","https://openalex.org/W2023295549","https://openalex.org/W2028295464","https://openalex.org/W2031887841","https://openalex.org/W2035616270","https://openalex.org/W2036519845","https://openalex.org/W2039881604","https://openalex.org/W2041726370","https://openalex.org/W2043554130","https://openalex.org/W2045722795","https://openalex.org/W2054742208","https://openalex.org/W2056071453","https://openalex.org/W2057996273","https://openalex.org/W2059678271","https://openalex.org/W2059824140","https://openalex.org/W2061141313","https://openalex.org/W2065888585","https://openalex.org/W2075312796","https://openalex.org/W2079314625","https://openalex.org/W2087825284","https://openalex.org/W2090910132","https://openalex.org/W2090947896","https://openalex.org/W2093453703","https://openalex.org/W2093622714","https://openalex.org/W2096508062","https://openalex.org/W2097676741","https://openalex.org/W2097718005","https://openalex.org/W2098836837","https://openalex.org/W2103014247","https://openalex.org/W2103808099","https://openalex.org/W2110424499","https://openalex.org/W2111812652","https://openalex.org/W2112809931","https://openalex.org/W2113573800","https://openalex.org/W2114741594","https://openalex.org/W2118805104","https://openalex.org/W2121252264","https://openalex.org/W2122834780","https://openalex.org/W2131599528","https://openalex.org/W2131960791","https://openalex.org/W2141094087","https://openalex.org/W2141705345","https://openalex.org/W2149631772","https://openalex.org/W2149831012","https://openalex.org/W2153721661","https://openalex.org/W2162835685","https://openalex.org/W2163760265","https://openalex.org/W2164259254","https://openalex.org/W2166686829","https://openalex.org/W2167137322","https://openalex.org/W2170070362","https://openalex.org/W2331395706","https://openalex.org/W2486531950","https://openalex.org/W2949108923","https://openalex.org/W2950761792","https://openalex.org/W2951578027","https://openalex.org/W2951683774","https://openalex.org/W2951685811","https://openalex.org/W2952391291","https://openalex.org/W2952397576","https://openalex.org/W2952586749","https://openalex.org/W2952682439","https://openalex.org/W2953174447","https://openalex.org/W3004534607","https://openalex.org/W4229586995","https://openalex.org/W4235073603","https://openalex.org/W4235569490","https://openalex.org/W4238711320","https://openalex.org/W4240318099","https://openalex.org/W4246258214"],"related_works":["https://openalex.org/W7045353282","https://openalex.org/W7045918867","https://openalex.org/W2950920206","https://openalex.org/W751746370","https://openalex.org/W2167137322","https://openalex.org/W2048272413","https://openalex.org/W2951868448","https://openalex.org/W2949065697","https://openalex.org/W2551400967","https://openalex.org/W4235569490"],"abstract_inverted_index":{"Counteranion":[0],"control":[1],"enables":[2],"the":[3,27,35,42,48,57],"enantioselective,":[4],"organo":[5],"Lewis":[6],"acid":[7],"catalyzed":[8],"Hosomi-Sakurai":[9],"reaction":[10],"of":[11,29,59],"(hetero)aromatic":[12],"aldehydes":[13],"and":[14,46],"allylsilanes":[15],"using":[16],"an":[17,51],"easily":[18],"handled":[19],"disulfonimide":[20,53],"precatalyst":[21],"(see":[22],"scheme).":[23],"The":[24],"key":[25],"to":[26,33],"success":[28],"this":[30],"system":[31],"is":[32],"turn":[34],"usually":[36],"undesired":[37],"silylium":[38],"ion":[39],"catalysis":[40],"into":[41],"desired":[43],"catalytic":[44],"regime":[45],"pair":[47],"cation":[49],"with":[50],"enantiopure":[52],"anion,":[54],"thereby":[55],"applying":[56],"concept":[58],"asymmetric":[60],"counteranion-directed":[61],"catalysis.":[62]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":7},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":6},{"year":2019,"cited_by_count":8},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":13},{"year":2015,"cited_by_count":10},{"year":2014,"cited_by_count":12},{"year":2013,"cited_by_count":9}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}