{"id":"https://openalex.org/W2007757764","doi":"https://doi.org/10.1021/ja00035a039","title":"Experimental evaluation of transition structure geometry for an aryl bromide-alkyllithium exchange reaction: new information relevant to the reaction mechanism","display_name":"Experimental evaluation of transition structure geometry for an aryl bromide-alkyllithium exchange reaction: new information relevant to the reaction mechanism","publication_year":1992,"publication_date":"1992-04-01","ids":{"openalex":"https://openalex.org/W2007757764","doi":"https://doi.org/10.1021/ja00035a039","mag":"2007757764"},"language":"en","primary_location":{"id":"doi:10.1021/ja00035a039","doi":"https://doi.org/10.1021/ja00035a039","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00035a039","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072926516","display_name":"Peter Andrew Beak","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Peter Beak","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5032952322","display_name":"David John Allen","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"David J. Allen","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.9694,"has_fulltext":false,"cited_by_count":52,"citation_normalized_percentile":{"value":0.83963465,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"114","issue":"9","first_page":"3420","last_page":"3425"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.7103999853134155,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.7103999853134155,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.2612000107765198,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.008200000040233135,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/transition-state-structure","display_name":"transition state structure","score":0.6840000152587891},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.9190000295639038},{"id":"https://openalex.org/keywords/alkyllithium","display_name":"lithium alkyls","score":0.4359999895095825},{"id":"https://openalex.org/keywords/aryl-halides","display_name":"aryl halides","score":0.7649999856948853},{"id":"https://openalex.org/keywords/nucleophilic-aromatic-substitution","display_name":"nucleophilic aromatic substitution","score":0.597000002861023}],"concepts":[{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.5901768207550049},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.5565645694732666},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.5517381429672241},{"id":"https://openalex.org/C2778447006","wikidata":"https://www.wikidata.org/wiki/Q1156474","display_name":"Icon","level":2,"score":0.46019935607910156},{"id":"https://openalex.org/C518677369","wikidata":"https://www.wikidata.org/wiki/Q202833","display_name":"Social media","level":2,"score":0.4107625186443329},{"id":"https://openalex.org/C23123220","wikidata":"https://www.wikidata.org/wiki/Q816826","display_name":"Information retrieval","level":1,"score":0.3899596035480499},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.29890912771224976},{"id":"https://openalex.org/C161191863","wikidata":"https://www.wikidata.org/wiki/Q199655","display_name":"Library science","level":1,"score":0.2824707627296448},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.27789610624313354},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17680996656417847},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja00035a039","doi":"https://doi.org/10.1021/ja00035a039","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00035a039","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2049397000","https://openalex.org/W2280086693","https://openalex.org/W1966663933","https://openalex.org/W2332889912","https://openalex.org/W2148489610","https://openalex.org/W2314299720","https://openalex.org/W2015990737","https://openalex.org/W1963895337","https://openalex.org/W2026494340","https://openalex.org/W4390107238"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTExperimental":[3],"evaluation":[4],"of":[5,61,96,122],"transition":[6],"structure":[7],"geometry":[8],"for":[9,154],"an":[10],"aryl":[11],"bromide-alkyllithium":[12],"exchange":[13],"reaction:":[14],"new":[15],"information":[16,110,160],"relevant":[17],"to":[18,83,88],"the":[19,58,89,94,123,134,147,150,155,162,168],"reaction":[20],"mechanismPeter":[21],"Beak":[22],"and":[23,71,76,105,149,166,182,184],"David":[24],"J.":[25,28],"AllenCite":[26],"this:":[27],"Am.":[29],"Chem.":[30],"Soc.":[31],"1992,":[32],"114,":[33],"9,":[34],"3420\u20133425Publication":[35],"Date":[36],"(Print):April":[37],"1,":[38],"1992Publication":[39],"History":[40],"Published":[41],"online1":[42],"May":[43],"2002Published":[44],"inissue":[45],"1":[46],"April":[47],"1992https://pubs.acs.org/doi/10.1021/ja00035a039https://doi.org/10.1021/ja00035a039research-articleACS":[48],"PublicationsRequest":[49],"reuse":[50],"permissionsArticle":[51],"Views546Altmetric-Citations48LEARN":[52],"ABOUT":[53],"THESE":[54],"METRICSArticle":[55],"Views":[56],"are":[57,80,93],"COUNTER-compliant":[59],"sum":[60],"full":[62],"text":[63],"article":[64,128],"downloads":[65],"since":[66],"November":[67],"2008":[68],"(both":[69],"PDF":[70],"HTML)":[72],"across":[73],"all":[74],"institutions":[75],"individuals.":[77],"These":[78],"metrics":[79],"regularly":[81],"updated":[82,106],"reflect":[84],"usage":[85],"leading":[86],"up":[87],"last":[90],"few":[91],"days.Citations":[92],"number":[95],"other":[97],"articles":[98],"citing":[99],"this":[100],"article,":[101],"calculated":[102],"by":[103],"Crossref":[104,112],"daily.":[107],"Find":[108,158],"more":[109,159],"about":[111,146],"citation":[113],"counts.The":[114],"Altmetric":[115,163],"Attention":[116,164],"Score":[117,165],"is":[118,170],"a":[119,126,139],"quantitative":[120],"measure":[121],"attention":[124],"that":[125],"research":[127],"has":[129],"received":[130],"online.":[131],"Clicking":[132],"on":[133,161],"donut":[135],"icon":[136],"will":[137],"load":[138],"page":[140],"at":[141],"altmetric.com":[142],"with":[143,178],"additional":[144],"details":[145],"score":[148,169],"social":[151],"media":[152],"presence":[153],"given":[156],"article.":[157],"how":[167],"calculated.":[171],"Share":[172,187],"Add":[173],"toView":[174],"InAdd":[175],"Full":[176],"Text":[177],"ReferenceAdd":[179],"Description":[180],"ExportRISCitationCitation":[181],"abstractCitation":[183],"referencesMore":[185],"Options":[186],"onFacebookTwitterWechatLinked":[188],"InRedditEmail":[189],"Other":[190],"access":[191],"optionsGet":[192],"e-AlertscloseSupporting":[193],"Info":[194],"(1)\u00bbSupporting":[195],"Information":[196,198],"Supporting":[197],"Get":[199],"e-Alerts":[200]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":2},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":4}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}