{"id":"https://openalex.org/W2007679987","doi":"https://doi.org/10.1021/la048357u","title":"Preparation of Poly(\u03b5-caprolactone) Brushes at the Surface of Conducting Substrates","display_name":"Preparation of Poly(\u03b5-caprolactone) Brushes at the Surface of Conducting Substrates","publication_year":2004,"publication_date":"2004-10-23","ids":{"openalex":"https://openalex.org/W2007679987","doi":"https://doi.org/10.1021/la048357u","mag":"2007679987","pmid":"https://pubmed.ncbi.nlm.nih.gov/15544400"},"language":"en","primary_location":{"id":"doi:10.1021/la048357u","doi":"https://doi.org/10.1021/la048357u","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la048357u","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5037543045","display_name":"Samu\u00ebl Voccia","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I157674565","display_name":"University of Li\u00e8ge","ror":"https://ror.org/00afp2z80","country_code":"BE","type":"education","lineage":["https://openalex.org/I157674565"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"S. Voccia","raw_affiliation_strings":["Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium","institution_ids":["https://openalex.org/I157674565"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017726151","display_name":"Lo\u00efc Bech","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I157674565","display_name":"University of Li\u00e8ge","ror":"https://ror.org/00afp2z80","country_code":"BE","type":"education","lineage":["https://openalex.org/I157674565"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"L. Bech","raw_affiliation_strings":["Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium","institution_ids":["https://openalex.org/I157674565"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108203092","display_name":"Bernard Gilbert","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I157674565","display_name":"University of Li\u00e8ge","ror":"https://ror.org/00afp2z80","country_code":"BE","type":"education","lineage":["https://openalex.org/I157674565"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"B. Gilbert","raw_affiliation_strings":["Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium","institution_ids":["https://openalex.org/I157674565"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111372181","display_name":"Robert J\u00e9r\u00f4me","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I157674565","display_name":"University of Li\u00e8ge","ror":"https://ror.org/00afp2z80","country_code":"BE","type":"education","lineage":["https://openalex.org/I157674565"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"R. J\u00e9r\u00f4me","raw_affiliation_strings":["Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium","institution_ids":["https://openalex.org/I157674565"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5068217923","display_name":"Christine J\u00e9r\u00f4me","orcid":"https://orcid.org/0000-0001-8442-5740","observed_orcids":["https://orcid.org/0000-0001-8442-5740"]},"institutions":[{"id":"https://openalex.org/I157674565","display_name":"University of Li\u00e8ge","ror":"https://ror.org/00afp2z80","country_code":"BE","type":"education","lineage":["https://openalex.org/I157674565"]}],"countries":["BE"],"is_corresponding":false,"raw_author_name":"C. J\u00e9r\u00f4me","raw_affiliation_strings":["Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Education and Research on Macromolecules (C.E.R.M.), University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium, and Laboratory of Analytical Chemistry and Electrochemistry, University of Liege, B6 Sart-Tilman, B-4000 Liege, Belgium","institution_ids":["https://openalex.org/I157674565"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I157674565"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.3752,"has_fulltext":false,"cited_by_count":20,"citation_normalized_percentile":{"value":0.54725008,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"20","issue":"24","first_page":"10670","last_page":"10678"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.9301999807357788,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.9301999807357788,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.06199999898672104,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polycaprolactone","display_name":"polycaprolactone","score":0.9399999976158142},{"id":"https://openalex.org/keywords/polymer-brushes","display_name":"polymer brushes","score":0.828000009059906},{"id":"https://openalex.org/keywords/conductive-substrates","display_name":"conductive substrates","score":0.9079999923706055},{"id":"https://openalex.org/keywords/electropolymerization","display_name":"electropolymerization","score":0.9769999980926514},{"id":"https://openalex.org/keywords/polyacrylate","display_name":"polyacrylate","score":0.7599999904632568},{"id":"https://openalex.org/keywords/cathodic-potential","display_name":"cathode potential","score":0.6970000267028809},{"id":"https://openalex.org/keywords/chemisorption","display_name":"chemisorption","score":0.9070000052452087},{"id":"https://openalex.org/keywords/ring-opening-polymerization","display_name":"ring-opening polymerization","score":0.8320000171661377},{"id":"https://openalex.org/keywords/grafting","display_name":"grafting","score":0.5649999976158142},{"id":"https://openalex.org/keywords/surface-modification","display_name":"surface modification","score":0.3970000147819519}],"concepts":[{"id":"https://openalex.org/C119394753","wikidata":"https://www.wikidata.org/wiki/Q188245","display_name":"Polyester","level":2,"score":0.7135515213012695},{"id":"https://openalex.org/C2781111393","wikidata":"https://www.wikidata.org/wiki/Q288104","display_name":"Caprolactone","level":4,"score":0.6657537817955017},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.6405739188194275},{"id":"https://openalex.org/C2779989194","wikidata":"https://www.wikidata.org/wiki/Q343016","display_name":"Acrylate","level":4,"score":0.6175653338432312},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.6138911247253418},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5794359445571899},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.4912802577018738},{"id":"https://openalex.org/C203897987","wikidata":"https://www.wikidata.org/wiki/Q900770","display_name":"Ring-opening polymerization","level":4,"score":0.43442100286483765},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.41441112756729126},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.3190403878688812},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.27842748165130615},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.24529153108596802},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D000179","descriptor_name":"Acrylates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D004553","descriptor_name":"Electric Conductivity","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D008567","descriptor_name":"Membranes, Artificial","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011091","descriptor_name":"Polyesters","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D011091","descriptor_name":"Polyesters","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D012680","descriptor_name":"Sensitivity and Specificity","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013499","descriptor_name":"Surface Properties","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D017550","descriptor_name":"Spectroscopy, Fourier Transform Infrared","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D018625","descriptor_name":"Microscopy, Atomic Force","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":3,"locations":[{"id":"doi:10.1021/la048357u","doi":"https://doi.org/10.1021/la048357u","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la048357u","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},{"id":"pmid:15544400","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/15544400","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir : the ACS journal of surfaces and colloids","raw_type":"Journal Article"},{"id":"pmh:oai:orbi.ulg.ac.be:2268/7431","doi":null,"is_oa":false,"landing_page_url":"https://orbi.uliege.be/handle/2268/7431","pdf_url":null,"source":{"id":"https://openalex.org/S4306401300","display_name":"ORBi (University of Li\u00e8ge)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I157674565","host_organization_name":"University of Li\u00e8ge","host_organization_lineage":["https://openalex.org/I157674565"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Langmuir, 20 (24), 10670-10678 (2004-11-23)","raw_type":"http://purl.org/coar/resource_type/c_6501"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320309102","display_name":"City University of New York","ror":"https://ror.org/00453a208"},{"id":"https://openalex.org/F4320321390","display_name":"Fonds De La Recherche Scientifique - FNRS","ror":"https://ror.org/03q83t159"},{"id":"https://openalex.org/F4320334840","display_name":"Fonds pour la Formation \u00e0 la Recherche dans l\u2019Industrie et dans l\u2019Agriculture","ror":"https://ror.org/03q83t159"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":18,"referenced_works":["https://openalex.org/W1970111938","https://openalex.org/W1971975274","https://openalex.org/W1984755890","https://openalex.org/W1993095184","https://openalex.org/W1998789887","https://openalex.org/W2000942311","https://openalex.org/W2002424423","https://openalex.org/W2013055567","https://openalex.org/W2015785830","https://openalex.org/W2016760957","https://openalex.org/W2030275481","https://openalex.org/W2039143442","https://openalex.org/W2056516241","https://openalex.org/W2067796878","https://openalex.org/W2091651954","https://openalex.org/W2100252935","https://openalex.org/W2588990374","https://openalex.org/W4323875271"],"related_works":["https://openalex.org/W7056099831","https://openalex.org/W1971893685","https://openalex.org/W2244914945","https://openalex.org/W2005757050","https://openalex.org/W2033387283","https://openalex.org/W2066369950","https://openalex.org/W4232441003","https://openalex.org/W2046873382","https://openalex.org/W2009665117","https://openalex.org/W2323778856"],"abstract_inverted_index":{"This":[0],"paper":[1],"reports":[2],"on":[3],"the":[4,10,26,37,43,56,60],"preparation":[5],"of":[6,12,25,28,63],"polyester":[7],"brushes":[8],"at":[9,42],"surface":[11],"electrically":[13],"conducting":[14],"materials.":[15],"A":[16],"two-step":[17],"strategy":[18],"has":[19],"been":[20],"worked":[21],"out":[22],"that":[23,36],"consists":[24],"electropolymerization":[27],"an":[29],"acrylate":[30],"under":[31],"a":[32,46],"cathodic":[33],"potential,":[34],"such":[35],"polyacrylate":[38,57],"layer":[39],"is":[40,65],"chemisorbed":[41],"surface.":[44],"In":[45],"second":[47],"step,":[48],"either":[49],"preformed":[50],"poly(epsilon-caprolactone)":[51],"chains":[52],"are":[53],"grafted":[54],"onto":[55],"sublayer":[58],"or":[59],"ring-opening":[61],"polymerization":[62],"epsilon-caprolactone":[64],"initiated":[66],"from":[67],"it.":[68]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2012,"cited_by_count":4}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}