{"id":"https://openalex.org/W2007349652","doi":"https://doi.org/10.1021/ma961694s","title":"Emulsion Stabilization and Flocculation in CO2. 2. Dynamic Light Scattering","display_name":"Emulsion Stabilization and Flocculation in CO2. 2. Dynamic Light Scattering","publication_year":1997,"publication_date":"1997-08-01","ids":{"openalex":"https://openalex.org/W2007349652","doi":"https://doi.org/10.1021/ma961694s","mag":"2007349652"},"language":"en","primary_location":{"id":"doi:10.1021/ma961694s","doi":"https://doi.org/10.1021/ma961694s","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma961694s","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5090936976","display_name":"Matthew Z. Yates","orcid":"https://orcid.org/0000-0002-5588-2413","observed_orcids":["https://orcid.org/0000-0002-5588-2413"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]},{"id":"https://openalex.org/I86519309","display_name":"The University of Texas at Austin","ror":"https://ror.org/00hj54h04","country_code":"US","type":"education","lineage":["https://openalex.org/I86519309"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"M. Z. Yates","raw_affiliation_strings":["Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","University of Texas at Austin#TAB#"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","institution_ids":["https://openalex.org/I114027177"]},{"raw_affiliation_string":"Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"University of Texas at Austin#TAB#","institution_ids":["https://openalex.org/I86519309"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038848826","display_name":"Mark L. O\u2019Neill","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]},{"id":"https://openalex.org/I86519309","display_name":"The University of Texas at Austin","ror":"https://ror.org/00hj54h04","country_code":"US","type":"education","lineage":["https://openalex.org/I86519309"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"M. L. O'Neil","raw_affiliation_strings":["Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","University of Texas at Austin#TAB#"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","institution_ids":["https://openalex.org/I114027177"]},{"raw_affiliation_string":"Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"University of Texas at Austin#TAB#","institution_ids":["https://openalex.org/I86519309"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080881086","display_name":"Keith P. Johnston","orcid":"https://orcid.org/0000-0002-0915-1337","observed_orcids":["https://orcid.org/0000-0002-0915-1337"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]},{"id":"https://openalex.org/I86519309","display_name":"The University of Texas at Austin","ror":"https://ror.org/00hj54h04","country_code":"US","type":"education","lineage":["https://openalex.org/I86519309"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"K. P. Johnston","raw_affiliation_strings":["Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","University of Texas at Austin#TAB#"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","institution_ids":["https://openalex.org/I114027177"]},{"raw_affiliation_string":"Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"University of Texas at Austin#TAB#","institution_ids":["https://openalex.org/I86519309"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109922330","display_name":"S. E. Webber","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I86519309","display_name":"The University of Texas at Austin","ror":"https://ror.org/00hj54h04","country_code":"US","type":"education","lineage":["https://openalex.org/I86519309"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"S. Webber","raw_affiliation_strings":["Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","institution_ids":["https://openalex.org/I86519309"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067618974","display_name":"Dorian A. Canelas","orcid":"https://orcid.org/0000-0001-7486-490X","observed_orcids":["https://orcid.org/0000-0001-7486-490X"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]},{"id":"https://openalex.org/I86519309","display_name":"The University of Texas at Austin","ror":"https://ror.org/00hj54h04","country_code":"US","type":"education","lineage":["https://openalex.org/I86519309"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"D. A. Canelas,","raw_affiliation_strings":["Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","University of North Carolina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","institution_ids":["https://openalex.org/I114027177"]},{"raw_affiliation_string":"Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"University of North Carolina","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5096807758","display_name":"and D. E. Betts","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"D. E. Betts, and","raw_affiliation_strings":["University of North Carolina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of North Carolina","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5057642544","display_name":"Joseph M. DeSimone","orcid":"https://orcid.org/0000-0001-9521-5095","observed_orcids":["https://orcid.org/0000-0001-9521-5095","https://orcid.org/0000-0002-1764-8634"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]},{"id":"https://openalex.org/I86519309","display_name":"The University of Texas at Austin","ror":"https://ror.org/00hj54h04","country_code":"US","type":"education","lineage":["https://openalex.org/I86519309"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"J. M. DeSimone","raw_affiliation_strings":["Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","University of North Carolina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"Department of Chemistry, The University of North Carolina, Chapel Hill, North Carolina, 27599-3290","institution_ids":["https://openalex.org/I114027177"]},{"raw_affiliation_string":"Department of Chemistry, The University of Texas at Austin, Austin, Texas, 78712","institution_ids":["https://openalex.org/I86519309"]},{"raw_affiliation_string":"University of North Carolina","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":8.0332,"has_fulltext":false,"cited_by_count":58,"citation_normalized_percentile":{"value":0.98612919,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":96},"biblio":{"volume":"30","issue":"17","first_page":"5060","last_page":"5067"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10721","display_name":"Surfactants and Colloidal Systems","score":0.3522999882698059,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10721","display_name":"Surfactants and Colloidal Systems","score":0.3522999882698059,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11915","display_name":"Pickering emulsions and particle stabilization","score":0.29170000553131104,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10402","display_name":"Phase Equilibria and Thermodynamics","score":0.22949999570846558,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/emulsion-stabilization","display_name":"emulsion stabilization","score":0.7929999828338623},{"id":"https://openalex.org/keywords/flocculation","display_name":"flocculation","score":0.9110000133514404},{"id":"https://openalex.org/keywords/liquid-co2","display_name":"liquid CO2","score":0.9020000100135803},{"id":"https://openalex.org/keywords/steric-stabilization","display_name":"steric stabilization","score":0.847000002861023},{"id":"https://openalex.org/keywords/poly-2-ethylhexyl-acrylate","display_name":"poly(2-ethylhexyl acrylate)","score":0.9490000009536743},{"id":"https://openalex.org/keywords/block-copolymers","display_name":"block copolymers","score":0.7419999837875366},{"id":"https://openalex.org/keywords/depletion-flocculation","display_name":"depletion flocculation","score":0.722000002861023},{"id":"https://openalex.org/keywords/droplet-size","display_name":"droplet size","score":0.8349999785423279},{"id":"https://openalex.org/keywords/co2-density","display_name":"CO2 density","score":0.531000018119812},{"id":"https://openalex.org/keywords/hydrodynamic-diameter","display_name":"hydrodynamic diameter","score":0.5410000085830688}],"concepts":[{"id":"https://openalex.org/C148815931","wikidata":"https://www.wikidata.org/wiki/Q900689","display_name":"Flocculation","level":2,"score":0.877839982509613},{"id":"https://openalex.org/C14631669","wikidata":"https://www.wikidata.org/wiki/Q896108","display_name":"Dynamic light scattering","level":3,"score":0.7591537237167358},{"id":"https://openalex.org/C11432220","wikidata":"https://www.wikidata.org/wiki/Q1975334","display_name":"Dispersity","level":2,"score":0.6731259822845459},{"id":"https://openalex.org/C2778123984","wikidata":"https://www.wikidata.org/wiki/Q187634","display_name":"Emulsion","level":2,"score":0.5665863156318665},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.5501599311828613},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.5229873657226562},{"id":"https://openalex.org/C2779989194","wikidata":"https://www.wikidata.org/wiki/Q343016","display_name":"Acrylate","level":4,"score":0.5181354284286499},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4776824116706848},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4151310920715332},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.4147361218929291},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3941410779953003},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.3255370855331421},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.2516947388648987},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14865142107009888},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.13054153323173523},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ma961694s","doi":"https://doi.org/10.1021/ma961694s","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma961694s","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":33,"referenced_works":["https://openalex.org/W297289870","https://openalex.org/W1493641014","https://openalex.org/W1503363495","https://openalex.org/W1978899214","https://openalex.org/W1981367888","https://openalex.org/W1992205266","https://openalex.org/W1994552236","https://openalex.org/W1998463203","https://openalex.org/W2018777619","https://openalex.org/W2020773108","https://openalex.org/W2025740130","https://openalex.org/W2031238164","https://openalex.org/W2031776732","https://openalex.org/W2043639591","https://openalex.org/W2052813979","https://openalex.org/W2054057514","https://openalex.org/W2063549197","https://openalex.org/W2065150533","https://openalex.org/W2066099340","https://openalex.org/W2069520354","https://openalex.org/W2070091059","https://openalex.org/W2070525627","https://openalex.org/W2072119680","https://openalex.org/W2072130333","https://openalex.org/W2074854282","https://openalex.org/W2085667513","https://openalex.org/W2089666498","https://openalex.org/W2090735073","https://openalex.org/W2091816657","https://openalex.org/W2133218527","https://openalex.org/W2494402508","https://openalex.org/W2911653961","https://openalex.org/W4244330609"],"related_works":["https://openalex.org/W2052813979","https://openalex.org/W2139802870","https://openalex.org/W2792485787","https://openalex.org/W2085166538","https://openalex.org/W2763815505","https://openalex.org/W1972652812","https://openalex.org/W2070525627","https://openalex.org/W1970821944","https://openalex.org/W2064376491","https://openalex.org/W2116457604"],"abstract_inverted_index":{"Dynamic":[0],"light":[1],"scattering":[2],"(DLS)":[3],"was":[4],"used":[5],"to":[6,133,214],"investigate":[7],"steric":[8,43],"stabilization":[9],"and":[10,60,104,157,174,200],"flocculation":[11,116,208],"of":[12,81,86,100,108,113,119,138,148,171,186,197,203,209],"dilute":[13],"poly(2-ethylhexyl":[14],"acrylate)":[15,50],"(PEHA,":[16],"M":[17,52,66,74],"w":[18,53],"=":[19,54,68,76],"92K)":[20],"emulsions":[21,121,140,165,187],"in":[22,32,92,150,224],"liquid":[23],"CO":[24,39,93,127,151],"2":[25,40,94,128,152],"at":[26,37,130],"25":[27],"\u00b0C":[28],"by":[29,124,219],"monitoring":[30],"changes":[31],"droplet":[33,169,184],"size":[34,170,185],"over":[35,177],"time":[36,195],"various":[38],"densities.":[41],"Two":[42],"stabilizers":[44],"were":[45,90,122],"investigated:":[46],"a":[47,61,79,105,215],"homopolymer,":[48],"poly(1,1-dihydroperfluorooctyl":[49],"(PFOA,":[51],"1":[55],"\u00d7":[56],"10":[57],"6":[58],"),":[59],"block":[62,158],"copolymer,":[63],"polystyrene":[64],"(":[65,73],"n":[67,75],"4.5K":[69],"g/mol)-":[70],"b":[71,88,191,221],"-PFOA":[72,89,192,222],"25K).":[77],"For":[78],"concentration":[80],"0.03":[82],"wt":[83],"%,":[84],"aggregates":[85,223],"PS-":[87,190,220],"observed":[91],"with":[95,143,189,194],"an":[96,167],"average":[97,168,183],"hydrodynamic":[98],"diameter":[99],"approximately":[101],"80":[102],"nm":[103,173],"polydispersity":[106],"index":[107],"0.2\u22120.3":[109],"from":[110],"the":[111,126,139,144,155,162,164,182,204,210],"method":[112],"cumulants.":[114],"Critical":[115],"densities":[117],"(CFDs)":[118],"PEHA":[120],"determined":[123],"lowering":[125],"density":[129,147],"constant":[131],"temperature":[132],"induce":[134],"flocculation.":[135],"The":[136,207],"CFDs":[137],"agree":[141],"closely":[142],"\u03d1":[145],"point":[146],"PFOA":[149],"for":[153],"both":[154],"homopolymer":[156],"copolymer":[159],"stabilizers.":[160],"Above":[161],"CFD,":[163],"have":[166],"400\u2212600":[172],"are":[175],"stable":[176],"several":[178],"hours.":[179],"With":[180],"shear,":[181],"stabilized":[188],"decreases":[193],"because":[196],"shear-enhanced":[198],"flocculation,":[199],"subsequent":[201],"sedimentation":[202],"flocculated":[205],"droplets.":[206],"emulsion":[211],"is":[212],"attributed":[213],"depletion":[216],"mechanism":[217],"induced":[218],"solution.":[225]},"counts_by_year":[{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-16T09:59:22.235173","created_date":"2016-06-24T00:00:00"}