{"id":"https://openalex.org/W2006949604","doi":"https://doi.org/10.1021/jz300802k","title":"Probing the Structure and Chemistry of Perylenetetracarboxylic Dianhydride on Graphene Before and After Atomic Layer Deposition of Alumina","display_name":"Probing the Structure and Chemistry of Perylenetetracarboxylic Dianhydride on Graphene Before and After Atomic Layer Deposition of Alumina","publication_year":2012,"publication_date":"2012-07-11","ids":{"openalex":"https://openalex.org/W2006949604","doi":"https://doi.org/10.1021/jz300802k","mag":"2006949604","pmid":"https://pubmed.ncbi.nlm.nih.gov/22905282","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/3419543"},"language":"en","primary_location":{"id":"doi:10.1021/jz300802k","doi":"https://doi.org/10.1021/jz300802k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jz300802k","pdf_url":null,"source":{"id":"https://openalex.org/S123480357","display_name":"The Journal of Physical Chemistry Letters","issn_l":"1948-7185","issn":["1948-7185"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry Letters","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3419543","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5053375713","display_name":"James E. Johns","orcid":"https://orcid.org/0000-0001-6164-0384","observed_orcids":["https://orcid.org/0000-0001-6164-0384"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James E. Johns","raw_affiliation_strings":["Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089721235","display_name":"Hunter J. Karmel","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hunter J. Karmel","raw_affiliation_strings":["Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020460417","display_name":"Justice M. P. Alaboson","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Justice M. P. Alaboson","raw_affiliation_strings":["Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5020649130","display_name":"Mark C. Hersam","orcid":"https://orcid.org/0000-0003-4120-1426","observed_orcids":["https://orcid.org/0000-0003-4120-1426"]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Mark C. Hersam","raw_affiliation_strings":["Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments\rof Materials Science and Engineering, Chemistry,\rand Medicine, Northwestern University,\rEvanston Illinois 60208-3108, United States","institution_ids":["https://openalex.org/I111979921"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5020649130"],"corresponding_institution_ids":["https://openalex.org/I111979921"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.0301,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.73304704,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"3","issue":"15","first_page":"1974","last_page":"1979"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10083","display_name":"Graphene research and applications","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10083","display_name":"Graphene research and applications","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10472","display_name":"Semiconductor materials and devices","score":0.009200000204145908,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10275","display_name":"2D Materials and Applications","score":0.002300000051036477,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ptcda","display_name":"PTCDA","score":0.9769999980926514},{"id":"https://openalex.org/keywords/graphene","display_name":"graphene","score":0.8970000147819519},{"id":"https://openalex.org/keywords/atomic-layer-deposition","display_name":"atomic layer deposition","score":0.9369999766349792},{"id":"https://openalex.org/keywords/alumina","display_name":"alumina","score":0.8450000286102295},{"id":"https://openalex.org/keywords/trimethylaluminum","display_name":"trimethylaluminum","score":0.6890000104904175},{"id":"https://openalex.org/keywords/frank-van-der-merwe-growth","display_name":"layer-by-layer growth","score":0.7369999885559082},{"id":"https://openalex.org/keywords/island-formation","display_name":"island formation","score":0.9639999866485596},{"id":"https://openalex.org/keywords/photoluminescence","display_name":"photoluminescence","score":0.7400000095367432},{"id":"https://openalex.org/keywords/dielectric-passivation","display_name":"dielectric passivation","score":0.5429999828338623},{"id":"https://openalex.org/keywords/ultrathin-dielectrics","display_name":"ultrathin dielectric films","score":0.7749999761581421}],"concepts":[{"id":"https://openalex.org/C30080830","wikidata":"https://www.wikidata.org/wiki/Q169917","display_name":"Graphene","level":2,"score":0.8108282089233398},{"id":"https://openalex.org/C69544855","wikidata":"https://www.wikidata.org/wiki/Q757625","display_name":"Atomic layer deposition","level":3,"score":0.7445241212844849},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.6104110479354858},{"id":"https://openalex.org/C64297162","wikidata":"https://www.wikidata.org/wiki/Q1987070","display_name":"Deposition (geology)","level":3,"score":0.6065483093261719},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.5848237872123718},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4947066009044647},{"id":"https://openalex.org/C62960913","wikidata":"https://www.wikidata.org/wiki/Q1809389","display_name":"Layer by layer","level":3,"score":0.4416864216327667},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.37822985649108887},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.34635066986083984},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.07018232345581055},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.07000920176506042},{"id":"https://openalex.org/C151730666","wikidata":"https://www.wikidata.org/wiki/Q7205","display_name":"Paleontology","level":1,"score":0.0},{"id":"https://openalex.org/C2816523","wikidata":"https://www.wikidata.org/wiki/Q180184","display_name":"Sediment","level":2,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/jz300802k","doi":"https://doi.org/10.1021/jz300802k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jz300802k","pdf_url":null,"source":{"id":"https://openalex.org/S123480357","display_name":"The Journal of Physical Chemistry Letters","issn_l":"1948-7185","issn":["1948-7185"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry Letters","raw_type":"journal-article"},{"id":"pmid:22905282","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/22905282","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry letters","raw_type":"Journal Article"},{"id":"pmh:oai:europepmc.org:2701503","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3419543","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:3419543","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3419543","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"J Phys Chem Lett","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:europepmc.org:2701503","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3419543","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"Text"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2003564788","display_name":"Postdoctoral Rheumatology Training","funder_award_id":"5t32ar007611-20","funder_id":"https://openalex.org/F4320332161","funder_display_name":"National Institutes of Health"},{"id":"https://openalex.org/G474454551","display_name":null,"funder_award_id":"T32\u2010AR\u2010007611","funder_id":"https://openalex.org/F4320337362","funder_display_name":"National Institute of Arthritis and Musculoskeletal and Skin Diseases"}],"funders":[{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320337362","display_name":"National Institute of Arthritis and Musculoskeletal and Skin Diseases","ror":"https://ror.org/006zn3t30"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W1964806350","https://openalex.org/W1965432323","https://openalex.org/W1965510035","https://openalex.org/W1968212566","https://openalex.org/W1975691503","https://openalex.org/W1980877490","https://openalex.org/W1990051824","https://openalex.org/W1998860239","https://openalex.org/W1999724273","https://openalex.org/W2006612646","https://openalex.org/W2013837027","https://openalex.org/W2014694192","https://openalex.org/W2017283704","https://openalex.org/W2018498215","https://openalex.org/W2021774822","https://openalex.org/W2022512210","https://openalex.org/W2034716588","https://openalex.org/W2047186510","https://openalex.org/W2049201711","https://openalex.org/W2051220295","https://openalex.org/W2055783607","https://openalex.org/W2060715065","https://openalex.org/W2073617719","https://openalex.org/W2074596748","https://openalex.org/W2075362245","https://openalex.org/W2075977593","https://openalex.org/W2075987945","https://openalex.org/W2076639397","https://openalex.org/W2080880982","https://openalex.org/W2085092801","https://openalex.org/W2087899039","https://openalex.org/W2114116118","https://openalex.org/W2135592020","https://openalex.org/W2158932701"],"related_works":["https://openalex.org/W2087899039","https://openalex.org/W1994245215","https://openalex.org/W2200842989","https://openalex.org/W2036528418","https://openalex.org/W2259518256","https://openalex.org/W2038293987","https://openalex.org/W2047186510","https://openalex.org/W3045855862","https://openalex.org/W2028896140","https://openalex.org/W2552450793"],"abstract_inverted_index":{"The":[0],"superlative":[1],"electronic":[2],"properties":[3],"of":[4,12,23,72,91,93,103,122],"graphene":[5,27,58,98,155],"suggest":[6],"its":[7],"use":[8],"as":[9,39],"the":[10,24,32,65,73,87,106,120,123,127],"foundation":[11],"next":[13],"generation":[14],"integrated":[15],"circuits.":[16],"However,":[17],"this":[18],"application":[19],"requires":[20],"precise":[21],"control":[22],"interface":[25,75,153],"between":[26,129,154],"and":[28,69,89,100,112,132,150,156],"other":[29],"materials,":[30],"especially":[31],"metal":[33],"oxides":[34],"that":[35,43,139],"are":[36],"commonly":[37],"used":[38],"gate":[40],"dielectrics.":[41],"Towards":[42],"end,":[44],"organic":[45,152],"seeding":[46],"layers":[47],"have":[48],"been":[49],"empirically":[50],"shown":[51],"to":[52,85],"seed":[53],"ultrathin":[54],"dielectric":[55,158],"growth":[56,124,131],"on":[57,97],"via":[59],"atomic":[60],"layer":[61],"deposition":[62,102],"(ALD),":[63],"although":[64],"underlying":[66],"chemical":[67],"mechanisms":[68],"structural":[70],"details":[71,121],"molecule/dielectric":[74],"remain":[76],"unknown.":[77],"Here,":[78],"confocal":[79],"resonance":[80],"Raman":[81],"spectroscopy":[82],"is":[83,141],"employed":[84],"quantify":[86],"structure":[88],"chemistry":[90],"monolayers":[92],"3,4,9,10-perylenetetracarboxylic":[94],"dianhydride":[95],"(PTCDA)":[96],"before":[99],"after":[101],"alumina":[104],"with":[105],"ALD":[107],"precursors":[108],"trimethyl":[109],"aluminum":[110],"(TMA)":[111],"water.":[113],"Photoluminescence":[114],"measurements":[115],"provide":[116],"further":[117],"insight":[118],"into":[119],"mechanism,":[125],"including":[126],"transition":[128],"layer-by-layer":[130],"island":[133],"formation.":[134],"Overall,":[135],"these":[136],"results":[137],"reveal":[138],"PTCDA":[140],"not":[142],"consumed":[143],"during":[144],"ALD,":[145],"thereby":[146],"preserving":[147],"a":[148],"well-defined":[149],"passivating":[151],"deposited":[157],"thin":[159],"films.":[160]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":4}],"updated_date":"2026-10-28T10:33:24.094632","created_date":"2016-06-24T00:00:00"}
