{"id":"https://openalex.org/W2006833352","doi":"https://doi.org/10.1149/1.2127710","title":"Activation Energies of Anodic Gold Reactions in Aqueous Alkaline Cyanide","display_name":"Activation Energies of Anodic Gold Reactions in Aqueous Alkaline Cyanide","publication_year":1981,"publication_date":"1981-08-01","ids":{"openalex":"https://openalex.org/W2006833352","doi":"https://doi.org/10.1149/1.2127710","mag":"2006833352"},"language":"en","primary_location":{"id":"doi:10.1149/1.2127710","doi":"https://doi.org/10.1149/1.2127710","is_oa":true,"landing_page_url":"https://doi.org/10.1149/1.2127710","pdf_url":"https://iopscience.iop.org/article/10.1149/1.2127710/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://iopscience.iop.org/article/10.1149/1.2127710/pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5113840728","display_name":"Christopher P. Thurgood","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"C. P. Thurgood","raw_affiliation_strings":["Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4","institution_ids":["https://openalex.org/I185261750"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5004736581","display_name":"Donald W. Kirk","orcid":"https://orcid.org/0000-0002-9469-3500","observed_orcids":["https://orcid.org/0000-0002-9469-3500"]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"D. W. Kirk","raw_affiliation_strings":["Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4","institution_ids":["https://openalex.org/I185261750"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019855990","display_name":"Frank R. FOULKES","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"F. R. Foulkes","raw_affiliation_strings":["Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4","institution_ids":["https://openalex.org/I185261750"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5067498900","display_name":"William F. Graydon","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"W. F. Graydon","raw_affiliation_strings":["Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering and Applied Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A4","institution_ids":["https://openalex.org/I185261750"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I185261750"],"apc_list":{"value":1950,"currency":"USD","value_usd":1950},"apc_paid":null,"fwci":1.2674,"has_fulltext":true,"cited_by_count":31,"citation_normalized_percentile":{"value":0.75027788,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":94},"biblio":{"volume":"128","issue":"8","first_page":"1680","last_page":"1685"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11073","display_name":"Metal Extraction and Bioleaching","score":0.3718000054359436,"subfield":{"id":"https://openalex.org/subfields/2506","display_name":"Metals and Alloys"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11073","display_name":"Metal Extraction and Bioleaching","score":0.3718000054359436,"subfield":{"id":"https://openalex.org/subfields/2506","display_name":"Metals and Alloys"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.2849000096321106,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.09210000187158585,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/activation-energy","display_name":"activation energy","score":0.8289999961853027},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.656000018119812},{"id":"https://openalex.org/keywords/gold-cyanide-complexes","display_name":"gold cyanide complexes","score":0.6740000247955322},{"id":"https://openalex.org/keywords/rate-limiting-step","display_name":"rate-determining step","score":0.7919999957084656},{"id":"https://openalex.org/keywords/mass-transfer-effects","display_name":"mass transfer effects","score":0.8410000205039978},{"id":"https://openalex.org/keywords/diffusion-control","display_name":"diffusion control","score":0.8190000057220459},{"id":"https://openalex.org/keywords/adsorption","display_name":"adsorption","score":0.578000009059906}],"concepts":[{"id":"https://openalex.org/C2778455166","wikidata":"https://www.wikidata.org/wiki/Q55076544","display_name":"Cyanide","level":2,"score":0.7773308753967285},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7710103988647461},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.7423757314682007},{"id":"https://openalex.org/C89395315","wikidata":"https://www.wikidata.org/wiki/Q181232","display_name":"Anode","level":3,"score":0.66044020652771},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5813701748847961},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4926524758338928},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.47392067313194275},{"id":"https://openalex.org/C39353612","wikidata":"https://www.wikidata.org/wiki/Q5283759","display_name":"Atmospheric temperature range","level":2,"score":0.43773970007896423},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2770640254020691},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.20098862051963806},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.07562929391860962},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1149/1.2127710","doi":"https://doi.org/10.1149/1.2127710","is_oa":true,"landing_page_url":"https://doi.org/10.1149/1.2127710","pdf_url":"https://iopscience.iop.org/article/10.1149/1.2127710/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"},{"id":"pmh:oai:CiteSeerX.psu:10.1.1.817.6366","doi":null,"is_oa":false,"landing_page_url":"http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.817.6366","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://jes.ecsdl.org/content/128/8/1680.full.pdf","raw_type":"text"}],"best_oa_location":{"id":"doi:10.1149/1.2127710","doi":"https://doi.org/10.1149/1.2127710","is_oa":true,"landing_page_url":"https://doi.org/10.1149/1.2127710","pdf_url":"https://iopscience.iop.org/article/10.1149/1.2127710/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322015","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2006833352.pdf","grobid_xml":"https://content.openalex.org/works/W2006833352.grobid-xml"},"referenced_works_count":1,"referenced_works":["https://openalex.org/W2008048136"],"related_works":["https://openalex.org/W2036442964","https://openalex.org/W2088064138","https://openalex.org/W1988992024","https://openalex.org/W78473192","https://openalex.org/W2032670981","https://openalex.org/W1991270319","https://openalex.org/W7083585976","https://openalex.org/W158405188","https://openalex.org/W2032776061","https://openalex.org/W2896583185"],"abstract_inverted_index":{"The":[0,33,63,118,156,169,201,244,288],"kinetics":[1],"of":[2,6,23,35,48,55,66,72,125,151,218,241,275],"the":[3,13,29,67,80,84,122,126,160,166,174,198,205,211,215,219,225,248,254],"anodic":[4,49,56,217],"reactions":[5],"gold":[7,68,170,226],"in":[8,12,42,60,70,79,121,159,173,204,247,264],"aqueous":[9],"alkaline":[10],"cyanide":[11],"potential":[14,176],"range":[15,31],"\u22120.81":[16],"to":[17,77,130,179,183,223,231,261,269],"+0.64V":[18],"were":[19,38,58],"studied":[20],"by":[21,83,134],"means":[22],"potentiostatic":[24,61],"and":[25,148,193],"potentiodynamic":[26,265],"measurements":[27,266],"for":[28],"temperature":[30],"0\u00b0\u201350\u00b0C.":[32],"effects":[34],"mass":[36,154,199,286],"transfer":[37],"also":[39],"investigated.":[40],"As":[41],"earlier":[43],"works,":[44],"three":[45,127,220],"distinct":[46],"regions":[47,54,74,128,221],"activity":[50],"(":[51,140],"i.e.":[52],",":[53],"reactions)":[57],"found":[59,76,182,230,268],"measurements.":[62],"kinetic":[64],"behavior":[65],"reaction":[69,86,120,161,172,206,228,249,289],"each":[71],"these":[73],"was":[75,132,163,181,208,229,251,267,290],"behave":[78],"manner":[81],"predicted":[82],"single":[85],"mechanism":[87,162,207,250],"Au":[88,113],"+":[89,103,109],"CN":[90,110,114],"\u2212":[91,95,99,105,111,116],"\u2192":[92,100,112],"AuCN":[93,97,101,107],"ads":[94,98,102,108],"1":[96],"e":[104],"2":[106,115,278],"3":[117],"dissolution":[119,171,227],"most":[123,216],"cathodic":[124],"(\u22120.56":[129],"\u22120.26V)":[131],"characterized":[133],"a":[135,149,185,194],"high":[136,187],"apparent":[137,188,238,272],"activation":[138,189,239,273],"energy":[139,190,240,274],"93":[141],"\u00b1":[142,277],"8":[143],"kJ":[144,279],"/":[145,280],"mol":[146,281],")":[147],"lack":[150],"dependence":[152,196,284],"on":[153,197,285],"transfer.":[155,200,287],"second":[157,202],"step":[158,203,246],"identified":[164,209,252,291],"as":[165,210,253,292],"rate\u2010determining":[167,212,255],"step.":[168,213,256],"intermediate":[175],"region":[177,259],"\u22120.26":[178],"+0.39V":[180],"have":[184,270],"relatively":[186],"(47\u201355":[191],"kJ/mol)":[192],"small":[195],"In":[214],"(\u22120.39":[222],"+0.64V),":[224],"be":[232],"under":[233],"diffusion":[234],"control":[235],"with":[236,282],"an":[237,271,293],"16\u201318":[242],"kJ/mol.":[243],"third":[245],"A":[257],"fourth":[258],"(\u22120.81":[260],"\u22120.56V)":[262],"observed":[263],"62":[276],"little":[283],"adsorption":[294],"reaction.":[295]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}