{"id":"https://openalex.org/W2006808907","doi":"https://doi.org/10.1135/cccc19840433","title":"Azido derivatives of 1,6-anhydro-\u03b2-D-hexopyranoses corresponding to 3-deoxy- and 4-deoxy-D-glucosamine","display_name":"Azido derivatives of 1,6-anhydro-\u03b2-D-hexopyranoses corresponding to 3-deoxy- and 4-deoxy-D-glucosamine","publication_year":1984,"publication_date":"1984-01-01","ids":{"openalex":"https://openalex.org/W2006808907","doi":"https://doi.org/10.1135/cccc19840433","mag":"2006808907"},"language":"en","primary_location":{"id":"doi:10.1135/cccc19840433","doi":"https://doi.org/10.1135/cccc19840433","is_oa":false,"landing_page_url":"https://doi.org/10.1135/cccc19840433","pdf_url":null,"source":{"id":"https://openalex.org/S162571691","display_name":"Collection of Czechoslovak Chemical Communications","issn_l":"0010-0765","issn":["0010-0765","1212-6950"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Collection of Czechoslovak Chemical Communications","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5007551994","display_name":"Ivan \u010cern\u00fd","orcid":"https://orcid.org/0000-0001-8305-890X","observed_orcids":["https://orcid.org/0000-0001-8305-890X"]},"institutions":[{"id":"https://openalex.org/I21250087","display_name":"Charles University","ror":"https://ror.org/024d6js02","country_code":"CZ","type":"education","lineage":["https://openalex.org/I21250087"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Ivan \u010cern\u00fd","raw_affiliation_strings":["Department of Organic Chemistry, Charles University, 128 40, Prague 2"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, Charles University, 128 40, Prague 2","institution_ids":["https://openalex.org/I21250087"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006610145","display_name":"Tom\u00e1\u0161 Trnka","orcid":"https://orcid.org/0000-0003-0675-4340","observed_orcids":["https://orcid.org/0000-0003-0675-4340"]},"institutions":[{"id":"https://openalex.org/I21250087","display_name":"Charles University","ror":"https://ror.org/024d6js02","country_code":"CZ","type":"education","lineage":["https://openalex.org/I21250087"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Tom\u00e1\u0161 Trnka","raw_affiliation_strings":["Department of Organic Chemistry, Charles University, 128 40, Prague 2"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, Charles University, 128 40, Prague 2","institution_ids":["https://openalex.org/I21250087"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111678774","display_name":"Miloslav \u010cern\u00fd","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I21250087","display_name":"Charles University","ror":"https://ror.org/024d6js02","country_code":"CZ","type":"education","lineage":["https://openalex.org/I21250087"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Miloslav \u010cern\u00fd","raw_affiliation_strings":["Department of Organic Chemistry, Charles University, 128 40, Prague 2"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic Chemistry, Charles University, 128 40, Prague 2","institution_ids":["https://openalex.org/I21250087"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I21250087"],"apc_list":{"value":3660,"currency":"USD","value_usd":3660},"apc_paid":null,"fwci":1.1109,"has_fulltext":false,"cited_by_count":12,"citation_normalized_percentile":{"value":0.69250137,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"49","issue":"2","first_page":"433","last_page":"443"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10835","display_name":"Carbohydrate Chemistry and Synthesis","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10432","display_name":"DNA and Nucleic Acid Chemistry","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10602","display_name":"Glycosylation and Glycoproteins Research","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/azido-sugars","display_name":"azido sugars","score":0.8090000152587891},{"id":"https://openalex.org/keywords/lithium-azide","display_name":"lithium azide","score":0.7919999957084656},{"id":"https://openalex.org/keywords/acetolysis","display_name":"acetolysis","score":0.7419999837875366},{"id":"https://openalex.org/keywords/deacetylation","display_name":"deacetylation","score":0.8399999737739563},{"id":"https://openalex.org/keywords/trimethylsilylation","display_name":"trimethylsilylation","score":0.7609999775886536},{"id":"https://openalex.org/keywords/hydrogenation","display_name":"hydrogenation","score":0.6729999780654907},{"id":"https://openalex.org/keywords/n-acetylation","display_name":"N-acetylation","score":0.949999988079071},{"id":"https://openalex.org/keywords/deoxy-sugars","display_name":"deoxy sugars","score":0.5189999938011169}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9077069759368896},{"id":"https://openalex.org/C2780997848","wikidata":"https://www.wikidata.org/wiki/Q407627","display_name":"Azide","level":2,"score":0.8331041932106018},{"id":"https://openalex.org/C111771559","wikidata":"https://www.wikidata.org/wiki/Q66295","display_name":"Derivative (finance)","level":2,"score":0.6135416030883789},{"id":"https://openalex.org/C2908590512","wikidata":"https://www.wikidata.org/wiki/Q327506","display_name":"D-Glucosamine","level":3,"score":0.5301973223686218},{"id":"https://openalex.org/C119157956","wikidata":"https://www.wikidata.org/wiki/Q796604","display_name":"Acetylation","level":3,"score":0.5250170826911926},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.4889882802963257},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.4776019752025604},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.47198182344436646},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4530692398548126},{"id":"https://openalex.org/C135731615","wikidata":"https://www.wikidata.org/wiki/Q658656","display_name":"Nucleophilic substitution","level":2,"score":0.4145289361476898},{"id":"https://openalex.org/C2776851017","wikidata":"https://www.wikidata.org/wiki/Q409079","display_name":"Aldose","level":3,"score":0.4102213382720947},{"id":"https://openalex.org/C2778125326","wikidata":"https://www.wikidata.org/wiki/Q327506","display_name":"Glucosamine","level":2,"score":0.34152117371559143},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.31197112798690796},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.24640512466430664},{"id":"https://openalex.org/C194671627","wikidata":"https://www.wikidata.org/wiki/Q192639","display_name":"Glycoside","level":2,"score":0.15027853846549988},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.12869185209274292},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C106159729","wikidata":"https://www.wikidata.org/wiki/Q2294553","display_name":"Financial economics","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C104317684","wikidata":"https://www.wikidata.org/wiki/Q7187","display_name":"Gene","level":2,"score":0.0},{"id":"https://openalex.org/C162324750","wikidata":"https://www.wikidata.org/wiki/Q8134","display_name":"Economics","level":0,"score":0.0},{"id":"https://openalex.org/C134018914","wikidata":"https://www.wikidata.org/wiki/Q162606","display_name":"Endocrinology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1135/cccc19840433","doi":"https://doi.org/10.1135/cccc19840433","is_oa":false,"landing_page_url":"https://doi.org/10.1135/cccc19840433","pdf_url":null,"source":{"id":"https://openalex.org/S162571691","display_name":"Collection of Czechoslovak Chemical Communications","issn_l":"0010-0765","issn":["0010-0765","1212-6950"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Collection of Czechoslovak Chemical Communications","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2950137558","https://openalex.org/W2604827950","https://openalex.org/W2039814620","https://openalex.org/W2033348351","https://openalex.org/W2076017468","https://openalex.org/W2952791929","https://openalex.org/W2017881369","https://openalex.org/W2952382776","https://openalex.org/W1963649092","https://openalex.org/W2952622638"],"abstract_inverted_index":{"Nucleophilic":[0],"substitution":[1],"of":[2,39,45,49,76,95],"the":[3,37],"tosyloxy":[4],"group":[5],"in":[6,26],"1,6-anhydro-3-deoxy-2-O-p-toluenesulfonyl-\u03b2-D-arabino-hexopyranose":[7],"(II)":[8],"with":[9],"lithium":[10,34],"azide":[11,35],"gave":[12,89],"derivative":[13,64],"V":[14],"which":[15],"was":[16,31,53,66],"acetolysed":[17],"and":[18,36,41,47,73,80,86,92,98],"deacetylated":[19],"to":[20,68],"2-azido-2,3-dideoxy-D-ribo-hexose":[21],"(IX).":[22],"The":[23],"oxirane":[24],"ring":[25],"1,6":[27],":":[28],"2,3-dianhydro-4-deoxy-\u03b2-D-lyxo-hexopyranose":[29],"(XII)":[30],"opened":[32],"using":[33],"mixture":[38],"2-":[40],"3-azido":[42],"derivatives":[43,78,94],"XIII":[44,65],"D-xylo":[46],"XIV":[48],"D-arabino":[50],"configuration":[51],"formed":[52],"separated":[54],"by":[55],"an":[56],"extraction":[57],"procedure":[58],"after":[59],"previous":[60],"selective":[61],"trimethylsilylation.":[62],"Azido":[63],"converted":[67],"2-azido-2,4-dideoxy-D-xylo-hexose":[69],"(XIX)":[70],"on":[71,82,84],"acetolysis":[72],"deacetylation.":[74],"Hydrogenation":[75],"azido":[77],"IX":[79],"XIX":[81],"palladium":[83],"charcoal":[85],"subsequent":[87],"N-acetylation":[88],"corresponding":[90],"3-":[91],"4-deoxy":[93],"D-glucosamine,":[96],"XI":[97],"XXI.":[99]},"counts_by_year":[],"updated_date":"2026-11-01T11:40:01.658920","created_date":"2016-06-24T00:00:00"}