{"id":"https://openalex.org/W2006075964","doi":"https://doi.org/10.1039/tf9676302814","title":"Studies of membrane phenomena. Part 4.\u2014Membrane potential and permeability","display_name":"Studies of membrane phenomena. Part 4.\u2014Membrane potential and permeability","publication_year":1967,"publication_date":"1967-01-01","ids":{"openalex":"https://openalex.org/W2006075964","doi":"https://doi.org/10.1039/tf9676302814","mag":"2006075964"},"language":"en","primary_location":{"id":"doi:10.1039/tf9676302814","doi":"https://doi.org/10.1039/tf9676302814","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9676302814","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5068985019","display_name":"Yoshinori Toyoshima","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Y. Toyoshima","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067719873","display_name":"Yonosuke Kobatake","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Y. Kobatake","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5108348936","display_name":"Hiroshi Fujita","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"H. Fujita","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.66,"has_fulltext":false,"cited_by_count":68,"citation_normalized_percentile":{"value":0.78883861,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"63","issue":"0","first_page":"2814","last_page":"2827"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12074","display_name":"Membrane-based Ion Separation Techniques","score":0.5830000042915344,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12074","display_name":"Membrane-based Ion Separation Techniques","score":0.5830000042915344,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.40310001373291016,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10197","display_name":"Membrane Separation Technologies","score":0.0052999998442828655,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/membrane-potential","display_name":"membrane potential","score":0.9940000176429749},{"id":"https://openalex.org/keywords/membrane-permeability","display_name":"membrane permeability","score":0.9919999837875366},{"id":"https://openalex.org/keywords/counterion-dissociation","display_name":"counterion dissociation","score":0.7110000252723694},{"id":"https://openalex.org/keywords/polyelectrolyte-membranes","display_name":"polyelectrolyte membranes","score":0.8370000123977661},{"id":"https://openalex.org/keywords/electrolyte-concentration-dependence","display_name":"electrolyte concentration dependence","score":0.6679999828338623},{"id":"https://openalex.org/keywords/ion-mobility","display_name":"ion mobility","score":0.3610000014305115},{"id":"https://openalex.org/keywords/sodium-chloride","display_name":"sodium chloride","score":0.5180000066757202},{"id":"https://openalex.org/keywords/kcl","display_name":"KCl","score":0.9919999837875366},{"id":"https://openalex.org/keywords/lithium-chloride","display_name":"lithium chloride","score":0.9980000257492065}],"concepts":[{"id":"https://openalex.org/C41625074","wikidata":"https://www.wikidata.org/wiki/Q176088","display_name":"Membrane","level":2,"score":0.9018481969833374},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8448812961578369},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.8275859355926514},{"id":"https://openalex.org/C34814092","wikidata":"https://www.wikidata.org/wiki/Q2268418","display_name":"Counterion","level":3,"score":0.6463379263877869},{"id":"https://openalex.org/C120882062","wikidata":"https://www.wikidata.org/wiki/Q28352","display_name":"Permeability (electromagnetism)","level":3,"score":0.5617947578430176},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.5186273455619812},{"id":"https://openalex.org/C198621165","wikidata":"https://www.wikidata.org/wiki/Q3743588","display_name":"Strong electrolyte","level":4,"score":0.5162108540534973},{"id":"https://openalex.org/C153356533","wikidata":"https://www.wikidata.org/wiki/Q901016","display_name":"Polyelectrolyte","level":3,"score":0.45465824007987976},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.4262269139289856},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.38912367820739746},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.3465110659599304},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.3289514183998108},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.1364154815673828},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10447615385055542},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.061572372913360596},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.05961728096008301},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/tf9676302814","doi":"https://doi.org/10.1039/tf9676302814","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9676302814","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2164737067","https://openalex.org/W2005674022","https://openalex.org/W2400780044","https://openalex.org/W2086041105","https://openalex.org/W1979899012","https://openalex.org/W4239984460","https://openalex.org/W2107811720","https://openalex.org/W2323624172","https://openalex.org/W2018867043","https://openalex.org/W2006982489"],"abstract_inverted_index":{"Theoretical":[0],"equations":[1,81],"were":[2,72,118,141,187],"derived":[3,147],"for":[4,24,42,138,199,230],"the":[5,25,37,43,51,58,61,68,83,104,107,114,139,150,156,162,166,174,177,182,191,195,205,216,227,252,258,261],"membrane":[6,22,31,52,69,178,183],"potential":[7],"\u0394\u03b6":[8,86,231],"which":[9,64],"arises":[10],"between":[11],"two":[12],"electrolyte":[13,34],"solutions":[14,108,160],"of":[15,28,39,47,60,85,95,106,113,152,155,161,170,194,224,260],"different":[16],"concentrations":[17,105],"separated":[18],"by":[19,190,208],"an":[20,33],"ionizable":[21],"and":[23,45,54,87,99,101,124,133,254],"permeability":[26],"Pm":[27,88,200],"such":[29],"a":[30,212,221],"to":[32,74,220],"component,":[35],"using":[36,204],"assumptions":[38,253],"part":[40],"3":[41],"activities":[44],"mobilities":[46],"small":[48,222],"ions":[49],"in":[50,79,142,159,251,257],"phase":[53],"taking":[55],"into":[56],"account":[57],"effect":[59],"liquid":[62],"layer":[63],"remains":[65],"unstirred":[66],"on":[67,110],"surface.":[70],"Methods":[71],"developed":[73],"evaluate":[75],"all":[76],"parameters":[77,140,206],"contained":[78,250],"these":[80,209],"from":[82,149,173],"measurements":[84,117,151],"at":[89,238],"various":[90],"fixed":[91],"\u03b3":[92],"as":[93,184],"functions":[94],"C1.":[96],"Here":[97],"\u03b3=C2/C1,":[98],"C1":[100,202,233],"C2":[102],"are":[103],"placed":[109],"both":[111],"sides":[112],"membrane.":[115],"Such":[116],"made":[119],"with":[120,145,215,235],"oxidized":[121],"collodion":[122],"membranes":[123,158],"four":[125],"1":[126,128],":":[127],"electrolytes":[129],"(NaCl,":[130],"KCl,":[131],"LiCl":[132],"KIO3).":[134],"The":[135,197,242],"values":[136],"obtained":[137],"good":[143,213],"agreement":[144,214],"those":[146],"previously":[148],"electric":[153],"resistances":[154],"same":[157,163],"electrolytes.":[164],"Thus":[165],"thermodynamically":[167],"effective":[168],"fraction":[169],"counterions":[171],"dissociated":[172],"polyelectrolytes":[175],"constituting":[176],"can":[179],"permeate":[180],"through":[181],"if":[185],"it":[186],"not":[188],"affected":[189],"electrostatic":[192],"interactions":[193],"polyions.":[196],"plots":[198,229],"against":[201,232],"calculated":[203],"evaluated":[207],"methods":[210],"showed":[211],"observed":[217],"data":[218],"down":[219],"value":[223],"C1,":[225],"but":[226],"corresponding":[228],"agreed":[234],"experiment":[236],"only":[237],"relatively":[239],"high":[240],"concentrations.":[241],"latter":[243],"fact":[244],"suggests":[245],"that":[246],"some":[247],"drawback":[248],"is":[249],"approximations":[255],"incorporated":[256],"development":[259],"present":[262],"theory.":[263]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":2}],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-06-24T00:00:00"}