{"id":"https://openalex.org/W2005753110","doi":"https://doi.org/10.1039/j19680003133","title":"Hydroformylation of alkenes by use of rhodium complex catalysts","display_name":"Hydroformylation of alkenes by use of rhodium complex catalysts","publication_year":1968,"publication_date":"1968-01-01","ids":{"openalex":"https://openalex.org/W2005753110","doi":"https://doi.org/10.1039/j19680003133","mag":"2005753110"},"language":"en","primary_location":{"id":"doi:10.1039/j19680003133","doi":"https://doi.org/10.1039/j19680003133","is_oa":false,"landing_page_url":"https://doi.org/10.1039/j19680003133","pdf_url":null,"source":{"id":"https://openalex.org/S4210168731","display_name":"Journal of the Chemical Society A Inorganic Physical Theoretical","issn_l":"0022-4944","issn":["0022-4944","2050-5582"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society A: Inorganic, Physical, Theoretical","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2005753110"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"D. Evans","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"D. Evans","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051505068","display_name":"John A. Osborn","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"J. A. Osborn","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5015414548","display_name":"Grant R. Wilkinson","orcid":"https://orcid.org/0000-0001-9701-3016","observed_orcids":["https://orcid.org/0000-0001-9701-3016"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"G. Wilkinson","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":4.9924,"has_fulltext":false,"cited_by_count":697,"citation_normalized_percentile":{"value":0.9684394,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":null,"issue":null,"first_page":"3133","last_page":"3133"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydroformylation","display_name":"hydroformylation","score":0.9459999799728394},{"id":"https://openalex.org/keywords/alkenes","display_name":"alkenes","score":0.8180000185966492},{"id":"https://openalex.org/keywords/rhodium-carbonyl-complexes","display_name":"rhodium carbonyl complexes","score":0.8600000143051147},{"id":"https://openalex.org/keywords/triphenylphosphine-ligands","display_name":"triphenylphosphine ligands","score":0.7929999828338623},{"id":"https://openalex.org/keywords/hydrogenolysis","display_name":"hydrogenolysis","score":0.8970000147819519},{"id":"https://openalex.org/keywords/carbon-monoxide-addition","display_name":"carbon monoxide addition","score":0.6389999985694885},{"id":"https://openalex.org/keywords/hydrogen-exchange","display_name":"hydrogen exchange","score":0.878000020980835},{"id":"https://openalex.org/keywords/active-catalytic-species","display_name":"catalytic active species","score":0.6499999761581421}],"concepts":[{"id":"https://openalex.org/C100805817","wikidata":"https://www.wikidata.org/wiki/Q899181","display_name":"Hydroformylation","level":4,"score":0.924185037612915},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8604847192764282},{"id":"https://openalex.org/C521398313","wikidata":"https://www.wikidata.org/wiki/Q1087","display_name":"Rhodium","level":3,"score":0.726830780506134},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7226141691207886},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6656720638275146},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.5183130502700806},{"id":"https://openalex.org/C126661725","wikidata":"https://www.wikidata.org/wiki/Q903420","display_name":"Isomerization","level":3,"score":0.5153219103813171},{"id":"https://openalex.org/C512735826","wikidata":"https://www.wikidata.org/wiki/Q2025","display_name":"Carbon monoxide","level":3,"score":0.49773481488227844},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.49531474709510803},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.47715944051742554},{"id":"https://openalex.org/C2779825165","wikidata":"https://www.wikidata.org/wiki/Q101497","display_name":"Aldehyde","level":3,"score":0.47632700204849243},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.35096365213394165}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/j19680003133","doi":"https://doi.org/10.1039/j19680003133","is_oa":false,"landing_page_url":"https://doi.org/10.1039/j19680003133","pdf_url":null,"source":{"id":"https://openalex.org/S4210168731","display_name":"Journal of the Chemical Society A Inorganic Physical Theoretical","issn_l":"0022-4944","issn":["0022-4944","2050-5582"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society A: Inorganic, Physical, Theoretical","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W71648628","https://openalex.org/W2115149095","https://openalex.org/W1988873896","https://openalex.org/W2013400322","https://openalex.org/W837035091","https://openalex.org/W4293059790","https://openalex.org/W2073061864","https://openalex.org/W2007547695","https://openalex.org/W2061829786"],"abstract_inverted_index":{"The":[0,49,84],"use":[1],"of":[2,4,6,34,54,76,120,148],"complexes":[3,56],"rhodium":[5],"the":[7,40,63,80,92,118,130],"type":[8],"trans-RhX(CO)(PR3)2,":[9],"(X":[10],"=":[11,14],"halogen,":[12],"R":[13],"aryl)":[15],"as":[16,106],"hydroformylation":[17,111,135],"catalysts":[18],"for":[19],"alkenes":[20,108,149],"is":[21,24,30,51,68,72,86,97,126],"studied.":[22],"It":[23],"shown":[25],"that":[26,39,62],"an":[27],"inhibition":[28],"period":[29],"removed":[31],"by":[32,74,89],"addition":[33,75],"hydrogen":[35],"halide":[36,41],"acceptors":[37],"and":[38,145],"complex":[42,82,95],"undergoes":[43],"hydrogenolysis":[44],"to":[45,79,122],"form":[46],"a":[47],"hydrido-species.":[48],"hydrido-species":[50],"only":[52],"one":[53],"several":[55],"in":[57,99,134],"equilibrium":[58],"but":[59],"it":[60],"appears":[61],"principal":[64],"active":[65],"catalytic":[66],"species":[67,71],"RhH(CO)2(PPh3)2.":[69],"This":[70],"formed":[73,88,125],"carbon":[77],"monoxide":[78],"monocarbonyl":[81],"RhH(CO)(PPh3)2.":[83],"latter":[85],"also":[87],"dissociation":[90],"when":[91],"stable":[93],"crystalline":[94],"RhH(CO)(PPh3)3":[96,105,151],"dissolved":[98],"benzene":[100],"or":[101],"other":[102],"solvents.":[103],"With":[104],"catalyst,":[107],"undergo":[109],"rapid":[110],"even":[112],"at":[113,140],"25\u00b0/1":[114],"atm.;":[115],"with":[116,150],"alk-1-enes":[117],"ratio":[119],"straight-":[121],"branched-chain":[123],"aldehyde":[124],"considerably":[127],"higher":[128],"than":[129],"ratios":[131],"normally":[132],"found":[133],"reactions,":[136],"being":[137],"ca.":[138],"20":[139],"25\u00b0.":[141],"Hydrogen":[142],"atom":[143],"exchange":[144],"isomerisation":[146],"reactions":[147],"are":[152],"described.":[153]},"counts_by_year":[{"year":2026,"cited_by_count":15},{"year":2025,"cited_by_count":22},{"year":2024,"cited_by_count":25},{"year":2023,"cited_by_count":19},{"year":2022,"cited_by_count":24},{"year":2021,"cited_by_count":28},{"year":2020,"cited_by_count":15},{"year":2019,"cited_by_count":20},{"year":2018,"cited_by_count":20},{"year":2017,"cited_by_count":22},{"year":2016,"cited_by_count":15},{"year":2015,"cited_by_count":19},{"year":2014,"cited_by_count":26},{"year":2013,"cited_by_count":27},{"year":2012,"cited_by_count":11}],"updated_date":"2026-11-14T11:04:58.165337","created_date":"2016-06-24T00:00:00"}