{"id":"https://openalex.org/W2005684248","doi":"https://doi.org/10.1021/ja981803d","title":"Self-Assembly of a Novel Organometallic\u2212Inorganic Block Copolymer in Solution and the Solid State: Nonintrusive Observation of Novel Wormlike Poly(ferrocenyldimethylsilane)-b-Poly(dimethylsiloxane) Micelles","display_name":"Self-Assembly of a Novel Organometallic\u2212Inorganic Block Copolymer in Solution and the Solid State: Nonintrusive Observation of Novel Wormlike Poly(ferrocenyldimethylsilane)-b-Poly(dimethylsiloxane) Micelles","publication_year":1998,"publication_date":"1998-09-01","ids":{"openalex":"https://openalex.org/W2005684248","doi":"https://doi.org/10.1021/ja981803d","mag":"2005684248"},"language":"en","primary_location":{"id":"doi:10.1021/ja981803d","doi":"https://doi.org/10.1021/ja981803d","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja981803d","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5051928388","display_name":"Jason A. Massey","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Jason Massey","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada","institution_ids":["https://openalex.org/I185261750"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5034074210","display_name":"K. Nicole Power","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"K. Nicole Power","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada","institution_ids":["https://openalex.org/I185261750"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076582889","display_name":"Ian Manners A","orcid":"https://orcid.org/0000-0002-3794-967X","observed_orcids":["https://orcid.org/0000-0002-3794-967X"]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Ian Manners","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada","institution_ids":["https://openalex.org/I185261750"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5026093276","display_name":"Mitchell A. Winnik","orcid":"https://orcid.org/0000-0002-2673-2141","observed_orcids":["https://orcid.org/0000-0002-2673-2141"]},"institutions":[{"id":"https://openalex.org/I185261750","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087","country_code":"CA","type":"education","lineage":["https://openalex.org/I185261750"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Mitchell A. Winnik","raw_affiliation_strings":["Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, M5S 3H6, Canada","institution_ids":["https://openalex.org/I185261750"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I185261750"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":11.5053,"has_fulltext":false,"cited_by_count":333,"citation_normalized_percentile":{"value":0.9924123,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":98,"max":100},"biblio":{"volume":"120","issue":"37","first_page":"9533","last_page":"9540"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.6894999742507935,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.6894999742507935,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.3061999976634979,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10721","display_name":"Surfactants and Colloidal Systems","score":0.001500000013038516,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/wormlike-micelles","display_name":"wormlike micelles","score":0.8050000071525574},{"id":"https://openalex.org/keywords/rod-like-micelles","display_name":"rod-like micelles","score":0.7409999966621399},{"id":"https://openalex.org/keywords/self-assembly","display_name":"self-assembly","score":0.7360000014305115},{"id":"https://openalex.org/keywords/aggregation-number","display_name":"aggregation number","score":0.8550000190734863},{"id":"https://openalex.org/keywords/ferrocene","display_name":"ferrocene","score":0.5360000133514404},{"id":"https://openalex.org/keywords/polydimethylsiloxane","display_name":"polydimethylsiloxane","score":0.6330000162124634}],"concepts":[{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.7885515093803406},{"id":"https://openalex.org/C11268172","wikidata":"https://www.wikidata.org/wiki/Q421110","display_name":"Micelle","level":3,"score":0.7380684614181519},{"id":"https://openalex.org/C14631669","wikidata":"https://www.wikidata.org/wiki/Q896108","display_name":"Dynamic light scattering","level":3,"score":0.6936959028244019},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6844980120658875},{"id":"https://openalex.org/C2777077568","wikidata":"https://www.wikidata.org/wiki/Q150440","display_name":"Hexane","level":2,"score":0.6648049354553223},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.6541572213172913},{"id":"https://openalex.org/C207374878","wikidata":"https://www.wikidata.org/wiki/Q3274587","display_name":"Hydrodynamic radius","level":4,"score":0.6371985673904419},{"id":"https://openalex.org/C63179538","wikidata":"https://www.wikidata.org/wiki/Q854422","display_name":"Gel permeation chromatography","level":3,"score":0.5974420309066772},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5611424446105957},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.5595114827156067},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5412108898162842},{"id":"https://openalex.org/C146088050","wikidata":"https://www.wikidata.org/wiki/Q744818","display_name":"Transmission electron microscopy","level":2,"score":0.5092729330062866},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.49196502566337585},{"id":"https://openalex.org/C45206210","wikidata":"https://www.wikidata.org/wiki/Q2415817","display_name":"Nanoscopic scale","level":2,"score":0.4318263530731201},{"id":"https://openalex.org/C26856880","wikidata":"https://www.wikidata.org/wiki/Q910150","display_name":"Self-assembly","level":2,"score":0.41008615493774414},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.3572271764278412},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.33641964197158813},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.23587381839752197},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.20948782563209534},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.15528401732444763},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja981803d","doi":"https://doi.org/10.1021/ja981803d","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja981803d","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W26722278","https://openalex.org/W1484399839","https://openalex.org/W1521736965","https://openalex.org/W1965459878","https://openalex.org/W1970438751","https://openalex.org/W1971306914","https://openalex.org/W1974513171","https://openalex.org/W1987710529","https://openalex.org/W2007377791","https://openalex.org/W2029774108","https://openalex.org/W2033297392","https://openalex.org/W2034228483","https://openalex.org/W2035931697","https://openalex.org/W2046501755","https://openalex.org/W2052388369","https://openalex.org/W2054057514","https://openalex.org/W2060615558","https://openalex.org/W2067379505","https://openalex.org/W2070074471","https://openalex.org/W2072609181","https://openalex.org/W2075666690","https://openalex.org/W2079946964","https://openalex.org/W2080731876","https://openalex.org/W2084558115","https://openalex.org/W2085984461","https://openalex.org/W2088915729","https://openalex.org/W2090103831","https://openalex.org/W2119282772","https://openalex.org/W2144015215","https://openalex.org/W2150634556","https://openalex.org/W2172949807","https://openalex.org/W2503576964","https://openalex.org/W2567056973","https://openalex.org/W2907273550"],"related_works":["https://openalex.org/W2012024672","https://openalex.org/W2038916577","https://openalex.org/W1997606591","https://openalex.org/W2083221204","https://openalex.org/W3020045995","https://openalex.org/W2008460460","https://openalex.org/W2752956525","https://openalex.org/W2528451823","https://openalex.org/W2170632878","https://openalex.org/W2087741708"],"abstract_inverted_index":{"The":[0,86,137],"novel":[1],"organometallic\u2212inorganic":[2],"diblock":[3],"copolymer,":[4],"poly(ferrocenyldimethylsilane)-":[5],"b":[6,9],"-poly(dimethylsiloxane)":[7],"(PFS-":[8],"-PDMS)":[10],"(block":[11],"ratio":[12],"=":[13,18,33],"1.0:6.0)":[14],"(":[15],"M":[16,28,31],"n":[17,32],"35":[19],"100":[20],"g/mol":[21],"with":[22,73,161],"a":[23,81,174],"narrow":[24],"molecular":[25],"weight":[26],"distribution":[27],"w":[29],"/":[30],"1.10":[34],"based":[35],"upon":[36],"gel":[37],"permeation":[38],"chromatography":[39],"in":[40,49,80,93,106,131,152],"THF":[41],"using":[42],"polystyrene":[43],"standards)":[44],"forms":[45,89],"long":[46],"rodlike":[47,183],"micelles":[48,124],"hexane":[50,100,132,153],"solution.":[51],"After":[52],"the":[53,74,94,102,107,123,156,187],"solvent":[54],"was":[55],"evaporated,":[56],"transmission":[57],"electron":[58],"microscopy":[59,64],"(TEM)":[60],"and":[61,96,111,116,177],"atomic":[62],"force":[63],"(AFM)":[65],"showed":[66],"that":[67,122],"individual":[68],"cylindrical":[69],"micellar":[70,184],"structures":[71,185],"form":[72],"iron-rich,":[75],"organometallic":[76],"PFS":[77,169],"core":[78],"encased":[79],"sheath":[82],"(corona)":[83],"of":[84,144,158,165],"PDMS.":[85],"block":[87],"copolymer":[88],"hexagonally":[90],"packed":[91],"cylinders":[92,103,160],"bulk,":[95],"exposure":[97],"to":[98,104,120,155,173,189],"warm":[99],"causes":[101],"disperse":[105],"solvent.":[108],"Both":[109],"static":[110],"dynamic":[112],"light":[113],"scattering":[114],"(SLS":[115],"DLS)":[117],"were":[118],"used":[119],"establish":[121],"are":[125,129],"flexible":[126],"rods":[127],"which":[128],"stable":[130],"even":[133],"at":[134],"80":[135],"\u00b0C.":[136],"as-prepared":[138],"sample":[139],"possessed":[140],"an":[141,162,180],"aggregation":[142,163],"number":[143,164],"ca.":[145,166],"2000":[146],"polymer":[147],"molecules.":[148],"Ultrasonication":[149],"(60":[150],"W)":[151],"led":[154],"generation":[157],"short":[159],"700.":[167],"Since":[168],"can":[170],"be":[171],"oxidized":[172],"semiconductive":[175],"state":[176],"PDMS":[178],"is":[179],"insulator,":[181],"these":[182],"have":[186],"potential":[188],"function":[190],"as":[191],"nanoscale":[192],"self-insulated":[193],"wires.":[194]},"counts_by_year":[{"year":2026,"cited_by_count":11},{"year":2025,"cited_by_count":12},{"year":2024,"cited_by_count":9},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":14},{"year":2021,"cited_by_count":7},{"year":2020,"cited_by_count":12},{"year":2019,"cited_by_count":11},{"year":2018,"cited_by_count":8},{"year":2017,"cited_by_count":6},{"year":2016,"cited_by_count":11},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":9},{"year":2013,"cited_by_count":12},{"year":2012,"cited_by_count":13}],"updated_date":"2026-10-17T09:40:24.721904","created_date":"2025-10-10T00:00:00"}