{"id":"https://openalex.org/W2005275709","doi":"https://doi.org/10.1021/ma971265+","title":"Microstructure Development and Crystallization of Poly(ethylene oxide) and Melt-Miscible PEO Blends","display_name":"Microstructure Development and Crystallization of Poly(ethylene oxide) and Melt-Miscible PEO Blends","publication_year":1998,"publication_date":"1998-02-18","ids":{"openalex":"https://openalex.org/W2005275709","doi":"https://doi.org/10.1021/ma971265+","mag":"2005275709"},"language":"en","primary_location":{"id":"doi:10.1021/ma971265+","doi":"https://doi.org/10.1021/ma971265+","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma971265+","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5067719206","display_name":"Sapna Talibuddin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I130769515","display_name":"Pennsylvania State University","ror":"https://ror.org/04p491231","country_code":"US","type":"education","lineage":["https://openalex.org/I130769515"]},{"id":"https://openalex.org/I1332737386","display_name":"General Electric (United States)","ror":"https://ror.org/013msgt25","country_code":"US","type":"company","lineage":["https://openalex.org/I1332737386"]},{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Sapna Talibuddin","raw_affiliation_strings":["Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","General Electric","Pennsylvania State University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","institution_ids":["https://openalex.org/I59553526"]},{"raw_affiliation_string":"Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","institution_ids":["https://openalex.org/I130769515"]},{"raw_affiliation_string":"General Electric","institution_ids":["https://openalex.org/I1332737386"]},{"raw_affiliation_string":"Pennsylvania State University","institution_ids":["https://openalex.org/I130769515"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5045292525","display_name":"James P. Runt","orcid":"https://orcid.org/0000-0002-8630-1239","observed_orcids":["https://orcid.org/0000-0002-8630-1239"]},"institutions":[{"id":"https://openalex.org/I130769515","display_name":"Pennsylvania State University","ror":"https://ror.org/04p491231","country_code":"US","type":"education","lineage":["https://openalex.org/I130769515"]},{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James Runt","raw_affiliation_strings":["Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","Materials Science and Engineering"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","institution_ids":["https://openalex.org/I59553526"]},{"raw_affiliation_string":"Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","institution_ids":["https://openalex.org/I130769515"]},{"raw_affiliation_string":"Materials Science and Engineering","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5038495086","display_name":"Lizhi Liu","orcid":"https://orcid.org/0000-0003-0199-6308","observed_orcids":["https://orcid.org/0000-0003-0199-6308"]},"institutions":[{"id":"https://openalex.org/I130769515","display_name":"Pennsylvania State University","ror":"https://ror.org/04p491231","country_code":"US","type":"education","lineage":["https://openalex.org/I130769515"]},{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Li-Zhi Liu","raw_affiliation_strings":["Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","Stony Brook University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","institution_ids":["https://openalex.org/I59553526"]},{"raw_affiliation_string":"Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","institution_ids":["https://openalex.org/I130769515"]},{"raw_affiliation_string":"Stony Brook University","institution_ids":["https://openalex.org/I59553526"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5000613784","display_name":"Benjamin Chu","orcid":"https://orcid.org/0000-0003-2775-2336","observed_orcids":["https://orcid.org/0000-0003-2775-2336"]},"institutions":[{"id":"https://openalex.org/I130769515","display_name":"Pennsylvania State University","ror":"https://ror.org/04p491231","country_code":"US","type":"education","lineage":["https://openalex.org/I130769515"]},{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Benjamin Chu","raw_affiliation_strings":["Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","Stony Brook University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The State University of New York at Stony Brook, Stony Brook, New York 11794-3400","institution_ids":["https://openalex.org/I59553526"]},{"raw_affiliation_string":"Department of Materials Science & Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802","institution_ids":["https://openalex.org/I130769515"]},{"raw_affiliation_string":"Stony Brook University","institution_ids":["https://openalex.org/I59553526"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.6418,"has_fulltext":false,"cited_by_count":37,"citation_normalized_percentile":{"value":0.88414491,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"31","issue":"5","first_page":"1627","last_page":"1634"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/poly-ethylene-oxide","display_name":"poly(ethylene oxide)","score":1.0},{"id":"https://openalex.org/keywords/melt-miscibility","display_name":"melt miscibility","score":0.921999990940094},{"id":"https://openalex.org/keywords/crystallization-kinetics","display_name":"crystallization kinetics","score":0.8169999718666077},{"id":"https://openalex.org/keywords/lamellar-microstructure","display_name":"lamellar microstructure","score":0.7480000257492065},{"id":"https://openalex.org/keywords/avrami-exponent","display_name":"Avrami exponent","score":0.7080000042915344},{"id":"https://openalex.org/keywords/time-resolved-small-angle-x-ray-scattering","display_name":"time-resolved small-angle X-ray scattering","score":0.8740000128746033},{"id":"https://openalex.org/keywords/crystallinity-evolution","display_name":"crystallinity evolution","score":0.6290000081062317},{"id":"https://openalex.org/keywords/polymer-blends","display_name":"polymer blends","score":0.4390000104904175}],"concepts":[{"id":"https://openalex.org/C46275449","wikidata":"https://www.wikidata.org/wiki/Q2458815","display_name":"Crystallinity","level":2,"score":0.9312518835067749},{"id":"https://openalex.org/C131888329","wikidata":"https://www.wikidata.org/wiki/Q3027679","display_name":"Small-angle X-ray scattering","level":3,"score":0.8280149698257446},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7571282386779785},{"id":"https://openalex.org/C203036418","wikidata":"https://www.wikidata.org/wiki/Q284256","display_name":"Crystallization","level":2,"score":0.7409294843673706},{"id":"https://openalex.org/C77851909","wikidata":"https://www.wikidata.org/wiki/Q6481705","display_name":"Lamellar structure","level":2,"score":0.6736375689506531},{"id":"https://openalex.org/C87976508","wikidata":"https://www.wikidata.org/wiki/Q1498213","display_name":"Microstructure","level":2,"score":0.5496472120285034},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.5483511090278625},{"id":"https://openalex.org/C110530677","wikidata":"https://www.wikidata.org/wiki/Q1789148","display_name":"Crystallization of polymers","level":3,"score":0.412009060382843},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.40116238594055176},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3437865376472473},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.19937708973884583},{"id":"https://openalex.org/C191486275","wikidata":"https://www.wikidata.org/wiki/Q210028","display_name":"Scattering","level":2,"score":0.14184120297431946},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.07233625650405884},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ma971265+","doi":"https://doi.org/10.1021/ma971265+","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma971265+","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":18,"referenced_works":["https://openalex.org/W1711766935","https://openalex.org/W1970649752","https://openalex.org/W1979352415","https://openalex.org/W1981853521","https://openalex.org/W2029953331","https://openalex.org/W2035717509","https://openalex.org/W2036531280","https://openalex.org/W2047516890","https://openalex.org/W2052039657","https://openalex.org/W2064197559","https://openalex.org/W2069181257","https://openalex.org/W2085971675","https://openalex.org/W2086867638","https://openalex.org/W2150151546","https://openalex.org/W4237286363","https://openalex.org/W4238964692","https://openalex.org/W4241304487","https://openalex.org/W4251221484"],"related_works":["https://openalex.org/W2092210111","https://openalex.org/W1995264401","https://openalex.org/W2101902002","https://openalex.org/W2014885749","https://openalex.org/W2075840085","https://openalex.org/W2182791396","https://openalex.org/W2015175556","https://openalex.org/W2324359483","https://openalex.org/W2024349156","https://openalex.org/W3184815676"],"abstract_inverted_index":{"Time-resolved":[0],"(TR)":[1],"small-angle":[2],"X-ray":[3],"(SAXS)":[4],"experiments":[5],"were":[6],"conducted":[7],"to":[8,81,100,134,148,182],"monitor":[9],"the":[10,36,40,44,49,52,83,101,110,114,117,125,128,150,154,163,195],"development":[11],"of":[12,39,43,51,67,86,116,127,153,189],"microstructure":[13],"and":[14,19,120,194],"crystallinity":[15,112],"in":[16,98],"neat":[17,171,192],"PEO":[18,26,172,193],"a":[20,167,187],"representative":[21],"composition":[22],"from":[23,48,58],"four,":[24],"melt-miscible":[25],"blends.":[27,198],"Although":[28],"crystal":[29,68],"thickening":[30,69],"was":[31,79,95,179],"not":[32,158],"observed":[33],"directly":[34],"during":[35,89],"time":[37,190],"scale":[38],"experiments,":[41],"comparison":[42],"microstructural":[45],"parameters":[46,136],"obtained":[47],"analysis":[50],"TRSAXS":[53,151],"data":[54,152],"with":[55,203],"those":[56,204],"determined":[57],"static":[59],"SAXS":[60,118],"(for":[61],"well-crystallized":[62],"samples)":[63],"indicated":[64],"different":[65],"rates":[66],"for":[70,109,137,170,191],"rapidly":[71],"vs":[72],"slowly":[73],"crystallizing":[74],"systems.":[75],"An":[76],"Avrami-like":[77],"expression":[78],"used":[80,146,181],"track":[82],"kinetic":[84],"evolution":[85],"experimental":[87],"invariants":[88],"crystallization.":[90],"A":[91],"generalized":[92],"four-parameter":[93,164],"model":[94,131,178],"proposed":[96],"which,":[97],"addition":[99],"two":[102],"\u201cAvrami\u201d":[103],"exponents,":[104],"included":[105],"factors":[106],"that":[107],"account":[108],"nonzero":[111],"at":[113,124,174],"start":[115],"run":[119],"finite":[121],"lamellar":[122],"stacks":[123],"end":[126],"run.":[129],"The":[130,141,177],"is":[132],"reduced":[133],"three":[135],"zero":[138],"initial":[139,160],"crystallinity.":[140],"three-parameter":[142],"version":[143],"could":[144],"be":[145],"successfully":[147],"fit":[149,169],"blends":[155],"(which":[156],"do":[157],"exhibit":[159],"crystallinity),":[161],"while":[162],"approach":[165],"offered":[166],"better":[168],"crystallized":[173],"45":[175],"\u00b0C.":[176],"further":[180],"estimate":[183],"bulk":[184],"crystallinities":[185],"as":[186],"function":[188],"strongly":[196],"interacting":[197],"These":[199],"values":[200],"agree":[201],"favorably":[202],"measured":[205],"using":[206],"DSC.":[207]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":3},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}