{"id":"https://openalex.org/W2005173303","doi":"https://doi.org/10.1021/ja801074m","title":"Electron Transport by Molecular Motion of redox-DNA Strands: Unexpectedly Slow Rotational Dynamics of 20-mer ds-DNA Chains End-Grafted onto Surfaces via C6 Linkers","display_name":"Electron Transport by Molecular Motion of redox-DNA Strands: Unexpectedly Slow Rotational Dynamics of 20-mer ds-DNA Chains End-Grafted onto Surfaces via C6 Linkers","publication_year":2008,"publication_date":"2008-07-01","ids":{"openalex":"https://openalex.org/W2005173303","doi":"https://doi.org/10.1021/ja801074m","mag":"2005173303","pmid":"https://pubmed.ncbi.nlm.nih.gov/18593158"},"language":"en","primary_location":{"id":"doi:10.1021/ja801074m","doi":"https://doi.org/10.1021/ja801074m","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja801074m","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111634426","display_name":"Agn\u00e8s Anne","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210131283","display_name":"Laboratoire d'Electrochimie Mol\u00e9culaire","ror":"https://ror.org/03atapr58","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I204730241","https://openalex.org/I4210128300","https://openalex.org/I4210131283"]},{"id":"https://openalex.org/I4387154366","display_name":"Universit\u00e9 Paris Diderot","ror":"https://ror.org/02n7qrg46","country_code":"FR","type":"education","lineage":["https://openalex.org/I204730241","https://openalex.org/I4387154366"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Agn\u00e8s Anne","raw_affiliation_strings":["Laboratoire d\u2019Electrochimie Mol\u00e9culaire, Unit\u00e9 Mixte de Recherche Universit\u00e9 - CNRS No. 7591, Universit\u00e9 de Paris 7 - Denis Diderot, 2 place Jussieu, 75251 Paris Cedex 5, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire d\u2019Electrochimie Mol\u00e9culaire, Unit\u00e9 Mixte de Recherche Universit\u00e9 - CNRS No. 7591, Universit\u00e9 de Paris 7 - Denis Diderot, 2 place Jussieu, 75251 Paris Cedex 5, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210131283","https://openalex.org/I4387154366"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5069416951","display_name":"Christophe Demaille","orcid":"https://orcid.org/0000-0002-6393-6522","observed_orcids":["https://orcid.org/0000-0002-6393-6522"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210131283","display_name":"Laboratoire d'Electrochimie Mol\u00e9culaire","ror":"https://ror.org/03atapr58","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I204730241","https://openalex.org/I4210128300","https://openalex.org/I4210131283"]},{"id":"https://openalex.org/I4387154366","display_name":"Universit\u00e9 Paris Diderot","ror":"https://ror.org/02n7qrg46","country_code":"FR","type":"education","lineage":["https://openalex.org/I204730241","https://openalex.org/I4387154366"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Christophe Demaille","raw_affiliation_strings":["Laboratoire d\u2019Electrochimie Mol\u00e9culaire, Unit\u00e9 Mixte de Recherche Universit\u00e9 - CNRS No. 7591, Universit\u00e9 de Paris 7 - Denis Diderot, 2 place Jussieu, 75251 Paris Cedex 5, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire d\u2019Electrochimie Mol\u00e9culaire, Unit\u00e9 Mixte de Recherche Universit\u00e9 - CNRS No. 7591, Universit\u00e9 de Paris 7 - Denis Diderot, 2 place Jussieu, 75251 Paris Cedex 5, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210131283","https://openalex.org/I4387154366"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.3818,"has_fulltext":false,"cited_by_count":100,"citation_normalized_percentile":{"value":0.88930596,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"130","issue":"30","first_page":"9812","last_page":"9823"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10207","display_name":"Advanced biosensing and bioanalysis techniques","score":0.7734000086784363,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T10207","display_name":"Advanced biosensing and bioanalysis techniques","score":0.7734000086784363,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.20649999380111694,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10432","display_name":"DNA and Nucleic Acid Chemistry","score":0.0035000001080334187,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rotational-diffusion","display_name":"rotational diffusion","score":0.5260000228881836},{"id":"https://openalex.org/keywords/dna-conduction","display_name":"DNA conduction","score":0.5090000033378601},{"id":"https://openalex.org/keywords/single-stranded-dna","display_name":"single-stranded DNA","score":0.597000002861023},{"id":"https://openalex.org/keywords/nucleic-acid-hybridization","display_name":"nucleic acid hybridization","score":0.5799999833106995},{"id":"https://openalex.org/keywords/mismatch-tolerance","display_name":"mismatch tolerance","score":0.4620000123977661},{"id":"https://openalex.org/keywords/molecular-electronics","display_name":"molecular electronics","score":0.3269999921321869}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8600294589996338},{"id":"https://openalex.org/C2776294167","wikidata":"https://www.wikidata.org/wiki/Q4127028","display_name":"Rotational diffusion","level":3,"score":0.6172592043876648},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.5447843670845032},{"id":"https://openalex.org/C59593255","wikidata":"https://www.wikidata.org/wiki/Q901663","display_name":"Molecular dynamics","level":2,"score":0.5236943960189819},{"id":"https://openalex.org/C552990157","wikidata":"https://www.wikidata.org/wiki/Q7430","display_name":"DNA","level":2,"score":0.5219823122024536},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4925714135169983},{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.4806429445743561},{"id":"https://openalex.org/C129312508","wikidata":"https://www.wikidata.org/wiki/Q133686","display_name":"Oligonucleotide","level":3,"score":0.4499437212944031},{"id":"https://openalex.org/C24840226","wikidata":"https://www.wikidata.org/wiki/Q211016","display_name":"Electron transport chain","level":2,"score":0.4398500323295593},{"id":"https://openalex.org/C191961535","wikidata":"https://www.wikidata.org/wiki/Q2360205","display_name":"A-DNA","level":3,"score":0.43510112166404724},{"id":"https://openalex.org/C147120987","wikidata":"https://www.wikidata.org/wiki/Q2225","display_name":"Electron","level":2,"score":0.4159667491912842},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.39682623744010925},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.3565324544906616},{"id":"https://openalex.org/C12554922","wikidata":"https://www.wikidata.org/wiki/Q7100","display_name":"Biophysics","level":1,"score":0.35430240631103516},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.29501187801361084},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.16931703686714172},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.1662510335445404},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.15826809406280518},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.08912605047225952},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0793389081954956},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D000075163","descriptor_name":"Metallocenes","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D004247","descriptor_name":"DNA","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D004563","descriptor_name":"Electrochemistry","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":false},{"descriptor_ui":"D004566","descriptor_name":"Electrodes","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D004583","descriptor_name":"Electrons","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D005296","descriptor_name":"Ferrous Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D006046","descriptor_name":"Gold","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D009690","descriptor_name":"Nucleic Acid Conformation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D009693","descriptor_name":"Nucleic Acid Hybridization","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D009841","descriptor_name":"Oligonucleotides","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013816","descriptor_name":"Thermodynamics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/ja801074m","doi":"https://doi.org/10.1021/ja801074m","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja801074m","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:18593158","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/18593158","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":53,"referenced_works":["https://openalex.org/W1497012787","https://openalex.org/W1963952334","https://openalex.org/W1965890431","https://openalex.org/W1969408680","https://openalex.org/W1975771552","https://openalex.org/W1979513165","https://openalex.org/W1981686658","https://openalex.org/W1983713544","https://openalex.org/W1989311276","https://openalex.org/W1992236667","https://openalex.org/W1994284144","https://openalex.org/W2006141915","https://openalex.org/W2006636051","https://openalex.org/W2006766146","https://openalex.org/W2007189314","https://openalex.org/W2009572926","https://openalex.org/W2011214154","https://openalex.org/W2012182308","https://openalex.org/W2018982396","https://openalex.org/W2019386043","https://openalex.org/W2024080812","https://openalex.org/W2030396602","https://openalex.org/W2030500229","https://openalex.org/W2033901968","https://openalex.org/W2035868441","https://openalex.org/W2036625650","https://openalex.org/W2037124447","https://openalex.org/W2039325272","https://openalex.org/W2040831565","https://openalex.org/W2041002283","https://openalex.org/W2045017111","https://openalex.org/W2053014859","https://openalex.org/W2065402445","https://openalex.org/W2067473443","https://openalex.org/W2068697781","https://openalex.org/W2081702356","https://openalex.org/W2083346465","https://openalex.org/W2087760402","https://openalex.org/W2088315741","https://openalex.org/W2088728408","https://openalex.org/W2093041725","https://openalex.org/W2123606186","https://openalex.org/W2124675518","https://openalex.org/W2135718797","https://openalex.org/W2135995702","https://openalex.org/W2141429657","https://openalex.org/W2141948890","https://openalex.org/W2149681483","https://openalex.org/W2152835519","https://openalex.org/W2167440571","https://openalex.org/W2167560273","https://openalex.org/W2312732204","https://openalex.org/W4256635452"],"related_works":["https://openalex.org/W2083346465","https://openalex.org/W4323645578","https://openalex.org/W7164716126","https://openalex.org/W2065824330","https://openalex.org/W2067473443","https://openalex.org/W2069181905","https://openalex.org/W2048554480","https://openalex.org/W2319473397","https://openalex.org/W3135870069","https://openalex.org/W2117501044"],"abstract_inverted_index":{"The":[0,127,179],"dynamics":[1,41,110,180],"of":[2,8,42,77,92,101,111,120,136,144,154,159,181,192,199,226],"electron":[3,165,220],"transport":[4,205,221],"within":[5],"molecular":[6],"layers":[7,30,50],"3'-ferrocenylated":[9],"20-mer":[10],"oligonucleotide,":[11],"5'-thiol":[12],"end-grafted":[13],"onto":[14],"gold":[15],"electrode":[16,169],"surfaces":[17],"via":[18],"a":[19,54,67,150,193,237],"six-carbon":[20],"(C6)":[21],"linker,":[22],"is":[23,64,72,105,132,170,184,211,230],"studied":[24,217],"by":[25,66,206,222],"cyclic":[26,56],"voltammetry.":[27],"Single-stranded":[28],"Fc-DNA":[29],"are":[31],"observed":[32],"to":[33,53,74,115,149,173,186,189,232],"behave":[34],"as":[35,96],"diffusionless":[36],"systems":[37,216],"reflecting":[38],"the":[39,43,48,61,78,90,93,102,108,112,155,160,164,168,175,190,197,200,215,227],"rapid":[40],"ssDNA":[44],"strand.":[45],"Following":[46],"hybridization,":[47],"Fc-dsDNA-C6":[49,113],"give":[51],"rise":[52],"characteristic":[55],"voltammetry":[57],"behavior":[58],"evidencing":[59],"that":[60,203],"Fc":[62,94,161],"head":[63,95,162],"animated":[65],"purely":[68],"diffusional":[69],"motion,":[70],"which":[71],"ascribed":[73],"free":[75,142,223],"rotation":[76,143],"rigid":[79],"DNA":[80,103,242],"duplex":[81],"around":[82],"its":[83],"C6":[84],"anchoring":[85,156],"linker.":[86],"A":[87],"model,":[88],"describing":[89],"motion":[91,100,225],"resulting":[97],"from":[98],"hinge":[99,224],"duplex,":[104],"developed":[106],"allowing":[107],"motional":[109],"chains":[114],"be":[116,187,233],"quantified":[117],"in":[118,146,196],"terms":[119],"an":[121],"apparent":[122,176],"rotational":[123],"diffusion":[124],"coefficient,":[125],"Dr.":[126],"value":[128],"found":[129,185],"for":[130,141,163,214],"Dr":[131],"approximately":[133],"3-4":[134],"orders":[135],"magnitude":[137],"slower":[138],"than":[139],"expected":[140],"dsDNA":[145,177,207,228],"solution,":[147],"pointing":[148],"drastic":[151],"motion-slowing":[152],"role":[153],"surface.":[157],"Accessibility":[158],"transfer":[166],"at":[167],"also":[171],"shown":[172,231],"modulate":[174],"dynamics.":[178],"Fc-dsDNA-C":[182],"6":[183],"insensitive":[188],"presence":[191],"single":[194],"mismatch":[195],"middle":[198],"strand,":[201],"confirming":[202],"charge":[204],"conduction":[208],"(DNA":[209],"CT)":[210],"not":[212],"present":[213],"here.":[218],"However,":[219],"chain":[229],"fast":[234],"enough":[235],"to,":[236],"priori,":[238],"compete":[239],"favorably":[240],"with":[241],"CT.":[243]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":6},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":8},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":6},{"year":2018,"cited_by_count":8},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":10},{"year":2012,"cited_by_count":10}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2016-06-24T00:00:00"}
