{"id":"https://openalex.org/W2005159076","doi":"https://doi.org/10.1021/ic700363k","title":"Reactivity Studies on FeIII\u2212(O22-)\u2212CuII Compounds: Influence of the Ligand Architecture and Copper Ligand Denticity","display_name":"Reactivity Studies on FeIII\u2212(O22-)\u2212CuII Compounds: Influence of the Ligand Architecture and Copper Ligand Denticity","publication_year":2007,"publication_date":"2007-07-06","ids":{"openalex":"https://openalex.org/W2005159076","doi":"https://doi.org/10.1021/ic700363k","mag":"2005159076","pmid":"https://pubmed.ncbi.nlm.nih.gov/17616124"},"language":"en","primary_location":{"id":"doi:10.1021/ic700363k","doi":"https://doi.org/10.1021/ic700363k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic700363k","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5039658770","display_name":"Eduardo E. Chuf\u00e1n","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]},{"id":"https://openalex.org/I165690674","display_name":"Oregon Health & Science University","ror":"https://ror.org/009avj582","country_code":"US","type":"education","lineage":["https://openalex.org/I165690674"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Eduardo E. Chuf\u00e1n","raw_affiliation_strings":["Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5074283016","display_name":"Biplab Mondal","orcid":"https://orcid.org/0000-0002-0594-6749","observed_orcids":["https://orcid.org/0000-0002-0594-6749","https://orcid.org/0009-0007-8968-0514"]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]},{"id":"https://openalex.org/I165690674","display_name":"Oregon Health & Science University","ror":"https://ror.org/009avj582","country_code":"US","type":"education","lineage":["https://openalex.org/I165690674"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Biplab Mondal","raw_affiliation_strings":["Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075196778","display_name":"Thirumanavelan Gandhi","orcid":"https://orcid.org/0000-0002-0461-5155","observed_orcids":["https://orcid.org/0000-0002-0461-5155"]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]},{"id":"https://openalex.org/I165690674","display_name":"Oregon Health & Science University","ror":"https://ror.org/009avj582","country_code":"US","type":"education","lineage":["https://openalex.org/I165690674"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thirumanavelan Gandhi","raw_affiliation_strings":["Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102798932","display_name":"Eunsuk Kim","orcid":"https://orcid.org/0000-0001-8803-0666","observed_orcids":["https://orcid.org/0000-0001-8803-0666"]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]},{"id":"https://openalex.org/I165690674","display_name":"Oregon Health & Science University","ror":"https://ror.org/009avj582","country_code":"US","type":"education","lineage":["https://openalex.org/I165690674"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Eunsuk Kim","raw_affiliation_strings":["Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5085573856","display_name":"Nick D. Rubie","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]},{"id":"https://openalex.org/I165690674","display_name":"Oregon Health & Science University","ror":"https://ror.org/009avj582","country_code":"US","type":"education","lineage":["https://openalex.org/I165690674"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nick D. Rubie","raw_affiliation_strings":["Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079246484","display_name":"Pierre Mo\u00ebnne\u2010Loccoz","orcid":"https://orcid.org/0000-0002-7684-7617","observed_orcids":["https://orcid.org/0000-0002-7684-7617"]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]},{"id":"https://openalex.org/I165690674","display_name":"Oregon Health & Science University","ror":"https://ror.org/009avj582","country_code":"US","type":"education","lineage":["https://openalex.org/I165690674"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Pierre Mo\u00ebnne-Loccoz","raw_affiliation_strings":["Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","Center for Coastal Margins"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"]},{"raw_affiliation_string":"Center for Coastal Margins","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5084521304","display_name":"Kenneth D. Karlin","orcid":"https://orcid.org/0000-0002-5675-7040","observed_orcids":["https://orcid.org/0000-0002-5675-7040"]},"institutions":[{"id":"https://openalex.org/I145311948","display_name":"Johns Hopkins University","ror":"https://ror.org/00za53h95","country_code":"US","type":"education","lineage":["https://openalex.org/I145311948"]},{"id":"https://openalex.org/I165690674","display_name":"Oregon Health & Science University","ror":"https://ror.org/009avj582","country_code":"US","type":"education","lineage":["https://openalex.org/I165690674"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Kenneth D. Karlin","raw_affiliation_strings":["Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Johns Hopkins University, Baltimore, Maryland, Maryland 21218, and Department of Environmental & Biomolecular Systems, OGI School of Science & Engineering, Oregon Health & Science University, Beaverton, Oregon 97006","institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5084521304"],"corresponding_institution_ids":["https://openalex.org/I145311948","https://openalex.org/I165690674"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.1912,"has_fulltext":false,"cited_by_count":36,"citation_normalized_percentile":{"value":0.87232521,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"46","issue":"16","first_page":"6382","last_page":"6394"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ligand-architecture","display_name":"ligand architecture","score":0.7940000295639038},{"id":"https://openalex.org/keywords/co-displacement","display_name":"CO displacement","score":0.48100000619888306},{"id":"https://openalex.org/keywords/triphenylphosphine","display_name":"triphenylphosphine","score":0.8199999928474426},{"id":"https://openalex.org/keywords/cobaltocene-reduction","display_name":"cobaltocene reduction","score":0.7929999828338623},{"id":"https://openalex.org/keywords/dioxygen-reduction","display_name":"dioxygen reduction","score":0.531000018119812}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9370346069335938},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.7814467549324036},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7113513946533203},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.6383904814720154},{"id":"https://openalex.org/C178516000","wikidata":"https://www.wikidata.org/wiki/Q3023362","display_name":"Denticity","level":3,"score":0.6030272245407104},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.42341798543930054},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.17646971344947815},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.07841980457305908},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.05916625261306763},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D000143","descriptor_name":"Acids","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D002248","descriptor_name":"Carbon Monoxide","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D003300","descriptor_name":"Copper","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D006418","descriptor_name":"Heme","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D007501","descriptor_name":"Iron","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008024","descriptor_name":"Ligands","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010100","descriptor_name":"Oxygen","qualifier_ui":"Q000378","qualifier_name":"metabolism","is_major_topic":false},{"descriptor_ui":"D010100","descriptor_name":"Oxygen","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013056","descriptor_name":"Spectrophotometry, Ultraviolet","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":false},{"descriptor_ui":"D013059","descriptor_name":"Spectrum Analysis, Raman","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":false},{"descriptor_ui":"D015392","descriptor_name":"Chemistry, Inorganic","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1021/ic700363k","doi":"https://doi.org/10.1021/ic700363k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic700363k","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:17616124","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/17616124","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2513652571","display_name":null,"funder_award_id":"GM-60353","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G3874315476","display_name":"Heme/Copper and Heme/Nonheme Iron O(2) and NO Reactivity","funder_award_id":"R01GM060353","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G39538172","display_name":null,"funder_award_id":"GM34468","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G4342709353","display_name":"PORPHYRINS AND QUINONES AS ENZYME COFACTORS","funder_award_id":"5r01gm034468-15","funder_id":"https://openalex.org/F4320332161","funder_display_name":"National Institutes of Health"}],"funders":[{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W1591010220","https://openalex.org/W1966698815","https://openalex.org/W1967453468","https://openalex.org/W1972170675","https://openalex.org/W1976843504","https://openalex.org/W1977306014","https://openalex.org/W1980645628","https://openalex.org/W1981261075","https://openalex.org/W1984184890","https://openalex.org/W1987853611","https://openalex.org/W1988178548","https://openalex.org/W1989649804","https://openalex.org/W1989891505","https://openalex.org/W1993427153","https://openalex.org/W1996834975","https://openalex.org/W2003172417","https://openalex.org/W2007471212","https://openalex.org/W2012736781","https://openalex.org/W2018174874","https://openalex.org/W2022177609","https://openalex.org/W2022925545","https://openalex.org/W2025258396","https://openalex.org/W2026812720","https://openalex.org/W2028122330","https://openalex.org/W2029451266","https://openalex.org/W2039657636","https://openalex.org/W2042846086","https://openalex.org/W2048414598","https://openalex.org/W2049418897","https://openalex.org/W2050448132","https://openalex.org/W2052983624","https://openalex.org/W2060897601","https://openalex.org/W2063074480","https://openalex.org/W2065646888","https://openalex.org/W2069017764","https://openalex.org/W2070512512","https://openalex.org/W2071894609","https://openalex.org/W2079108392","https://openalex.org/W2092284751","https://openalex.org/W2097002933","https://openalex.org/W2132934971","https://openalex.org/W2138360835","https://openalex.org/W2140753535","https://openalex.org/W2145062831","https://openalex.org/W2953198030","https://openalex.org/W3093236069","https://openalex.org/W3139016704","https://openalex.org/W3174864180","https://openalex.org/W4237644676","https://openalex.org/W4245595995"],"related_works":["https://openalex.org/W2054509724","https://openalex.org/W1970206530","https://openalex.org/W2163856839","https://openalex.org/W2049662343","https://openalex.org/W2066507516","https://openalex.org/W1967453468","https://openalex.org/W2982447624","https://openalex.org/W2095158429","https://openalex.org/W2072600453","https://openalex.org/W1985965569"],"abstract_inverted_index":{"Heme-Cu/O2":[0],"adducts":[1],"are":[2,53,278],"of":[3,8,22,31,164,171,180,198,207,224,267],"interest":[4],"in":[5,14,38,55,215],"the":[6,9,29,69,75,86,99,111,130,177,181,195,199,204,210,218,250,257],"elucidation":[7],"fundamental":[10],"metal-O2":[11],"chemistry":[12,30,277],"occurring":[13],"heme-Cu":[15],"enzymes":[16],"which":[17],"effect":[18],"reductive":[19],"O-O":[20,275],"cleavage":[21,276],"dioxygen":[23],"to":[24,81,85,105,116,169,217],"water.":[25],"In":[26,65,88],"this":[27],"report,":[28],"four":[32],"heme-peroxo-copper":[33,222],"[FeIII-(O22-)-CuII]+":[34],"complexes":[35],"(1-4),":[36],"varying":[37],"their":[39,48,56],"ligand":[40,71,113,132,183,241],"architecture,":[41],"copper-ligand":[42],"denticity,":[43],"or":[44],"both":[45,106],"and":[46,50,63,67,74,83,91,98,120,127,147,166,173,243,246,252,273],"thus":[47],"structures":[49],"physical":[51,253],"properties":[52,254],"compared":[54,168],"reactivity":[57,258],"toward":[58,159],"CO,":[59,155],"PPh3,":[60,146],"acids,":[61],"cobaltocene,":[62],"phenols.":[64],"1":[66,149,165],"2,":[68],"copper(II)":[70,96],"is":[72,78,102],"N4-tetradentate,":[73],"peroxo":[76,100,112],"unit":[77,101],"bound":[79,103],"side-on":[80,104],"iron(III)":[82],"end-on":[84],"copper(II).":[87],"contrast,":[89],"3":[90,126,172],"4":[92,128,174],"contain":[93],"a":[94],"N3-tridentate":[95],"ligand,":[97],"metal":[107],"ions.":[108],"CO":[109],"\"displaces\"":[110],"from":[114,133],"2-4":[115],"form":[117],"reduced":[118],"CO-FeII":[119],"CO-CuI":[121],"species.":[122,139],"PPh3":[123,153],"reacts":[124,150],"with":[125,145,152,176,190,233],"displacing":[129],"peroxide":[131,200],"copper,":[134],"forming":[135],"(porphyrinate)FeIII-superoxide":[136],"plus":[137],"CuI-PPh3":[138],"Complex":[140],"2":[141,167],"does":[142],"not":[143,248],"react":[144,189],"surprisingly,":[148],"neither":[151],"nor":[154],"exhibiting":[156],"remarkable":[157],"stability":[158],"these":[160],"reagents.":[161],"The":[162,235],"behavior":[163],"that":[170],"correlates":[175],"different":[178,225],"denticity":[179],"copper":[182],"(tetra":[184],"vs":[185],"tridentate).":[186],"Complexes":[187],"1-4":[188,208],"HCl":[191],"releasing":[192],"H2O2,":[193],"demonstrating":[194],"basic":[196],"character":[197],"ligand.":[201],"Cobaltocene":[202],"causes":[203],"two-electron":[205],"reduction":[206],"giving":[209],"corresponding":[211],"micro-oxo":[212],"[FeIII-(O2-)-CuII]+":[213],"complexes,":[214,270],"contrast":[216],"findings":[219],"for":[220,260,264],"other":[221],"species":[223],"design.":[226],"With":[227],"t-butyl-substituted":[228],"phenols,":[229],"no":[230],"reaction":[231],"occurs":[232],"1-4.":[234],"results":[236],"described":[237],"here":[238],"emphasize":[239],"how":[240],"design":[242],"variations":[244],"influence":[245],"control":[247],"only":[249],"structure":[251],"but":[255],"also":[256],"patterns":[259],"heme-Cu/O2":[261],"adducts.":[262],"Implications":[263],"future":[265],"investigations":[266],"protonated":[268],"heme/Cu-peroxo":[269],"low-spin":[271],"analogues,":[272],"ultimately":[274],"discussed.":[279]},"counts_by_year":[{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":2},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}