{"id":"https://openalex.org/W2004662972","doi":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","title":"A.C. dielectric and TSC studies of constrained amorphous motions in flexible polymers including poly(oxymethylene) and miscible blends","display_name":"A.C. dielectric and TSC studies of constrained amorphous motions in flexible polymers including poly(oxymethylene) and miscible blends","publication_year":1997,"publication_date":"1997-09-30","ids":{"openalex":"https://openalex.org/W2004662972","doi":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","mag":"2004662972"},"language":"en","primary_location":{"id":"doi:10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","doi":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","pdf_url":null,"source":{"id":"https://openalex.org/S175770247","display_name":"Journal of Polymer Science Part B Polymer Physics","issn_l":"0887-6266","issn":["0887-6266","1099-0488"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","poland-20"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part B: Polymer Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5020283090","display_name":"Bryan B. Sauer","orcid":"https://orcid.org/0000-0002-7220-274X","observed_orcids":["https://orcid.org/0000-0002-7220-274X"]},"institutions":[{"id":"https://openalex.org/I1316910977","display_name":"DuPont (United States)","ror":"https://ror.org/03g3m1w62","country_code":"US","type":"company","lineage":["https://openalex.org/I1316910977"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Bryan B. Sauer","raw_affiliation_strings":["E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356","institution_ids":["https://openalex.org/I1316910977"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110148046","display_name":"Peter Avakian","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1316910977","display_name":"DuPont (United States)","ror":"https://ror.org/03g3m1w62","country_code":"US","type":"company","lineage":["https://openalex.org/I1316910977"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Peter Avakian","raw_affiliation_strings":["E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356","institution_ids":["https://openalex.org/I1316910977"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089900869","display_name":"Edmund A. Flexman","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1316910977","display_name":"DuPont (United States)","ror":"https://ror.org/03g3m1w62","country_code":"US","type":"company","lineage":["https://openalex.org/I1316910977"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Edmund A. Flexman","raw_affiliation_strings":["E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356","institution_ids":["https://openalex.org/I1316910977"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5047933282","display_name":"Mimi Y. Keating","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1316910977","display_name":"DuPont (United States)","ror":"https://ror.org/03g3m1w62","country_code":"US","type":"company","lineage":["https://openalex.org/I1316910977"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mimi Keating","raw_affiliation_strings":["E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356","institution_ids":["https://openalex.org/I1316910977"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5031207407","display_name":"Benjamin S. Hsiao","orcid":"https://orcid.org/0000-0002-3180-1826","observed_orcids":["https://orcid.org/0000-0002-3180-1826"]},"institutions":[{"id":"https://openalex.org/I1316910977","display_name":"DuPont (United States)","ror":"https://ror.org/03g3m1w62","country_code":"US","type":"company","lineage":["https://openalex.org/I1316910977"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Benjamin S. Hsiao","raw_affiliation_strings":["E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"E. I. du Pont de Nemours and Company, Inc., Central Research and Development, Experimental Station, P.O. Box 80356, Wilmington, Delaware 19880-0356","institution_ids":["https://openalex.org/I1316910977"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5102314997","display_name":"Ravi Verma","orcid":"https://orcid.org/0000-0003-4918-9564","observed_orcids":["https://orcid.org/0000-0003-4918-9564"]},"institutions":[{"id":"https://openalex.org/I122411786","display_name":"California Institute of Technology","ror":"https://ror.org/05dxps055","country_code":"US","type":"education","lineage":["https://openalex.org/I122411786"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ravi K. Verma","raw_affiliation_strings":["Chemical Engineering Dept., California Technical Inst., Pasadena, California 91125"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemical Engineering Dept., California Technical Inst., Pasadena, California 91125","institution_ids":["https://openalex.org/I122411786"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5020283090"],"corresponding_institution_ids":["https://openalex.org/I1316910977"],"apc_list":{"value":3200,"currency":"USD","value_usd":3200},"apc_paid":null,"fwci":1.9022,"has_fulltext":false,"cited_by_count":35,"citation_normalized_percentile":{"value":0.84054384,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"35","issue":"13","first_page":"2121","last_page":"2132"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10474","display_name":"Material Dynamics and Properties","score":0.548799991607666,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10474","display_name":"Material Dynamics and Properties","score":0.548799991607666,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.4456000030040741,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11379","display_name":"Rheology and Fluid Dynamics Studies","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polyoxymethylene","display_name":"polyoxymethylene","score":0.996999979019165},{"id":"https://openalex.org/keywords/poly-vinyl-phenol","display_name":"poly(vinyl phenol)","score":0.7910000085830688},{"id":"https://openalex.org/keywords/miscible-polymer-blends","display_name":"miscible polymer blends","score":0.8880000114440918},{"id":"https://openalex.org/keywords/amorphous-polymer-blends","display_name":"amorphous polymer blends","score":0.6290000081062317},{"id":"https://openalex.org/keywords/glass-transition","display_name":"glass transition","score":0.800000011920929},{"id":"https://openalex.org/keywords/activation-energy","display_name":"activation energy","score":0.49900001287460327},{"id":"https://openalex.org/keywords/semi-crystalline-polymers","display_name":"semicrystalline polymers","score":0.8389999866485596}],"concepts":[{"id":"https://openalex.org/C122865956","wikidata":"https://www.wikidata.org/wiki/Q825643","display_name":"Glass transition","level":3,"score":0.8590512275695801},{"id":"https://openalex.org/C56052488","wikidata":"https://www.wikidata.org/wiki/Q103382","display_name":"Amorphous solid","level":2,"score":0.7632344961166382},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6759738922119141},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.638798713684082},{"id":"https://openalex.org/C175804951","wikidata":"https://www.wikidata.org/wiki/Q3268188","display_name":"Diluent","level":2,"score":0.6164529323577881},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5911692380905151},{"id":"https://openalex.org/C46275449","wikidata":"https://www.wikidata.org/wiki/Q2458815","display_name":"Crystallinity","level":2,"score":0.5687503218650818},{"id":"https://openalex.org/C2777566558","wikidata":"https://www.wikidata.org/wiki/Q28917","display_name":"Styrene","level":4,"score":0.5227601528167725},{"id":"https://openalex.org/C133386390","wikidata":"https://www.wikidata.org/wiki/Q184996","display_name":"Dielectric","level":2,"score":0.5095930099487305},{"id":"https://openalex.org/C187404810","wikidata":"https://www.wikidata.org/wiki/Q733193","display_name":"Polymer blend","level":4,"score":0.5024421215057373},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.43908628821372986},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.2853422164916992},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.224427729845047},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.19515657424926758},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.12337759137153625},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","doi":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.0.co;2-6","pdf_url":null,"source":{"id":"https://openalex.org/S175770247","display_name":"Journal of Polymer Science Part B Polymer Physics","issn_l":"0887-6266","issn":["0887-6266","1099-0488"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","poland-20"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part B: Polymer Physics","raw_type":"journal-article"},{"id":"doi:10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.3.co;2-c","doi":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.3.co;2-c","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1099-0488(19970930)35:13<2121::aid-polb12>3.3.co;2-c","pdf_url":null,"source":{"id":"https://openalex.org/S175770247","display_name":"Journal of Polymer Science Part B Polymer Physics","issn_l":"0887-6266","issn":["0887-6266","1099-0488"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","poland-20"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part B: Polymer Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W1981806174","https://openalex.org/W1989091046","https://openalex.org/W2064384717","https://openalex.org/W2391225046","https://openalex.org/W2134222936","https://openalex.org/W2053376542","https://openalex.org/W1975077793","https://openalex.org/W54743726","https://openalex.org/W2023806557","https://openalex.org/W4244883284"],"abstract_inverted_index":{"Poly(OxyMethylene)":[0],"(POM)":[1],"and":[2,12,59,94,98,101,112,168],"its":[3,99],"miscible":[4],"blends":[5,18,136,141],"were":[6],"studied":[7],"by":[8],"multifrequency":[9],"A.C.":[10],"dielectric":[11],"thermally":[13],"stimulated":[14],"currents":[15],"(TSC).":[16],"The":[17,42,83,147],"contained":[19],"small":[20],"amounts":[21],"of":[22,44,122,124,145,149,158,164],"either":[23],"poly(vinyl":[24],"phenol),":[25],"which":[26],"is":[27,55,65,73,132,154],"a":[28,35,66,143],"high":[29,113],"glass":[30,57],"transition":[31,48,64,72,109],"(Tg)":[32],"diluent,":[33],"or":[34],"styrene-co-hydroxy":[36],"styrene":[37],"oligomeric":[38],"low":[39,111],"Tg":[40],"diluent.":[41],"variation":[43],"the":[45,56,61,70,107,120,125,128,135,169],"10\u00b0C":[46],"\u201c\u03b2\u201d":[47],"with":[49,160,175],"blend":[50],"composition":[51],"proves":[52],"that":[53,60,134],"it":[54,131],"transition,":[58],"\u221270\u00b0C":[62],"\u201c\u03b3\u201d":[63],"local":[67],"motion.":[68],"Dielectrically":[69],"\u03b2":[71],"very":[74],"weak":[75],"in":[76,80,96,156,171],"pure":[77],"POM":[78,97,172],"even":[79],"fast-quenched":[81],"samples.":[82],"TSC":[84],"thermal":[85],"sampling":[86],"method":[87],"also":[88],"detected":[89],"two":[90],"cooperative":[91],"transitions,":[92],"\u03b3":[93,108],"\u03b2,":[95],"blends,":[100],"was":[102],"used":[103],"to":[104],"directly":[105],"resolve":[106],"into":[110],"activation":[114],"energy":[115],"components.":[116],"If":[117],"one":[118],"considers":[119],"contribution":[121],"exclusion":[123],"diluents":[126],"from":[127],"crystal":[129],"lamellae,":[130],"shown":[133],"behave":[137],"like":[138],"typical":[139],"amorphous":[140,152],"as":[142],"function":[144],"concentration.":[146],"effect":[148],"crystals":[150],"on":[151],"motions":[153],"examined":[155],"light":[157],"comparison":[159],"van":[161],"Krevelen's37":[162],"predictions":[163],"an":[165],"\u201camorphous\u201d":[166],"Tg,":[167],"transitions":[170],"are":[173],"contrasted":[174],"those":[176],"for":[177],"other":[178],"semicrystalline":[179],"polymers.":[180],"\u00a9":[181],"1997":[182,196],"John":[183],"Wiley":[184],"&":[185],"Sons,":[186],"Inc.":[187],"J":[188],"Polym":[189,192],"Sci":[190],"B:":[191],"Phys":[193],"35:":[194],"2121\u20132132,":[195]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2014,"cited_by_count":4},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}