{"id":"https://openalex.org/W2003236450","doi":"https://doi.org/10.1107/s0108270196015910","title":"Tricarbonyl(trifluoromethyl)(triphenylphosphine)cobalt","display_name":"Tricarbonyl(trifluoromethyl)(triphenylphosphine)cobalt","publication_year":1997,"publication_date":"1997-05-15","ids":{"openalex":"https://openalex.org/W2003236450","doi":"https://doi.org/10.1107/s0108270196015910","mag":"2003236450"},"language":"en","primary_location":{"id":"doi:10.1107/s0108270196015910","doi":"https://doi.org/10.1107/s0108270196015910","is_oa":false,"landing_page_url":"https://doi.org/10.1107/s0108270196015910","pdf_url":null,"source":{"id":"https://openalex.org/S149116045","display_name":"Acta Crystallographica Section C Crystal Structure Communications","issn_l":"0108-2701","issn":["0108-2701","1600-5759"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section C Crystal Structure Communications","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111724006","display_name":"D.F. Mullica","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"D. F. Mullica","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110170126","display_name":"Eric L. Sappenfield","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"E. L. Sappenfield","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022958451","display_name":"Stephen L. Gipson","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"S. L. Gipson","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5055203729","display_name":"C.C. Wilkinson","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"C. C. Wilkinson","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3760,"currency":"USD","value_usd":3760},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":{"value":0.10720545,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":94},"biblio":{"volume":"53","issue":"5","first_page":"572","last_page":"574"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9785000085830688,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9785000085830688,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.012500000186264515,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.00430000014603138,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/trifluoromethyl-ligands","display_name":"trifluoromethyl ligands","score":0.8980000019073486},{"id":"https://openalex.org/keywords/triphenylphosphine","display_name":"triphenylphosphine","score":0.9179999828338623},{"id":"https://openalex.org/keywords/trigonal-bipyramidal-coordination","display_name":"trigonal bipyramidal coordination","score":0.9020000100135803},{"id":"https://openalex.org/keywords/staggered-conformation","display_name":"staggered conformation","score":0.7559999823570251},{"id":"https://openalex.org/keywords/alkylcobalt-complexes","display_name":"alkylcobalt complexes","score":0.7940000295639038},{"id":"https://openalex.org/keywords/coordination-geometry","display_name":"coordination geometry","score":0.48100000619888306},{"id":"https://openalex.org/keywords/bond-lengths","display_name":"bond lengths","score":0.7760000228881836}],"concepts":[{"id":"https://openalex.org/C2776442012","wikidata":"https://www.wikidata.org/wiki/Q2302144","display_name":"Trifluoromethyl","level":3,"score":0.9429583549499512},{"id":"https://openalex.org/C2777247709","wikidata":"https://www.wikidata.org/wiki/Q115493","display_name":"Triphenylphosphine","level":3,"score":0.8715704679489136},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7177655696868896},{"id":"https://openalex.org/C111592845","wikidata":"https://www.wikidata.org/wiki/Q2867924","display_name":"Trigonal bipyramidal molecular geometry","level":3,"score":0.6026449799537659},{"id":"https://openalex.org/C515602321","wikidata":"https://www.wikidata.org/wiki/Q740","display_name":"Cobalt","level":2,"score":0.5163775682449341},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4795896112918854},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3730261027812958},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3558669090270996},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.26869305968284607},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.1164136528968811},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0891847312450409},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.07686412334442139},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1107/s0108270196015910","doi":"https://doi.org/10.1107/s0108270196015910","is_oa":false,"landing_page_url":"https://doi.org/10.1107/s0108270196015910","pdf_url":null,"source":{"id":"https://openalex.org/S149116045","display_name":"Acta Crystallographica Section C Crystal Structure Communications","issn_l":"0108-2701","issn":["0108-2701","1600-5759"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section C Crystal Structure Communications","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W969962426","https://openalex.org/W2108513743","https://openalex.org/W2044678283","https://openalex.org/W1991625833","https://openalex.org/W1977137861","https://openalex.org/W2054977583","https://openalex.org/W2055258390","https://openalex.org/W2059251729","https://openalex.org/W2018186321","https://openalex.org/W1992084393"],"abstract_inverted_index":{"The":[0,20,49],"title":[1,53],"compound,":[2],"[Co(CF3)(C18H15P)(CO)3],":[3],"has":[4],"a":[5,37],"trigonal":[6],"bipyramidal":[7],"geometry":[8],"with":[9],"the":[10,16,25,30,42,46,52],"trifluoromethyl":[11,31],"and":[12,32],"trifluorophosphine":[13],"ligands":[14,23,34,44],"occupying":[15],"trans":[17],"axial":[18],"positions.":[19,28],"three":[21],"carbonyl":[22,43],"occupy":[24],"planar":[26],"equatorial":[27,47],"Both":[29],"triphenylphosphine":[33],"are":[35],"in":[36,45],"staggered":[38],"conformation":[39],"relative":[40],"to":[41,57],"plane.":[48],"structure":[50],"of":[51],"compound":[54],"is":[55],"similar":[56],"other":[58],"alkylcobalt":[59],"tricarbonyl":[60],"triphenylphosphines.":[61],"Important":[62],"bond":[63],"distances":[64],"include:":[65],"Co\u2014CF3":[66],"=":[67,71,76,80],"1.953":[68],"(6),":[69],"Co\u2014P1":[70],"2.235":[72],"(1);":[73],"Co\u2014CO":[74],"(mean)":[75,79],"1.752;":[77],"P1\u2014C":[78],"1.822":[81],"\u00c5.":[82]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2015,"cited_by_count":1}],"updated_date":"2026-07-31T08:31:51.225901","created_date":"2016-06-24T00:00:00"}