{"id":"https://openalex.org/W2003225095","doi":"https://doi.org/10.1039/c3ra22710c","title":"A mixed-valence Mn6 cluster exhibiting self-assembled vesicular structure and catecholase-like activity in solution state","display_name":"A mixed-valence Mn6 cluster exhibiting self-assembled vesicular structure and catecholase-like activity in solution state","publication_year":2013,"publication_date":"2013-01-01","ids":{"openalex":"https://openalex.org/W2003225095","doi":"https://doi.org/10.1039/c3ra22710c","mag":"2003225095"},"language":"en","primary_location":{"id":"doi:10.1039/c3ra22710c","doi":"https://doi.org/10.1039/c3ra22710c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3ra22710c","pdf_url":null,"source":{"id":"https://openalex.org/S2481244646","display_name":"RSC Advances","issn_l":"2046-2069","issn":["2046-2069"],"is_oa":false,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"RSC Advances","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5024697476","display_name":"Piya Seth","orcid":"https://orcid.org/0009-0005-9021-5471","observed_orcids":["https://orcid.org/0009-0005-9021-5471"]},"institutions":[{"id":"https://openalex.org/I106542073","display_name":"University of Calcutta","ror":"https://ror.org/01e7v7w47","country_code":"IN","type":"education","lineage":["https://openalex.org/I106542073"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Piya Seth","raw_affiliation_strings":["Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata-700 009, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata-700 009, India","institution_ids":["https://openalex.org/I106542073"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5017963965","display_name":"Ashutosh Ghosh","orcid":"https://orcid.org/0000-0003-2026-7565","observed_orcids":["https://orcid.org/0000-0003-2026-7565"]},"institutions":[{"id":"https://openalex.org/I106542073","display_name":"University of Calcutta","ror":"https://ror.org/01e7v7w47","country_code":"IN","type":"education","lineage":["https://openalex.org/I106542073"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Ashutosh Ghosh","raw_affiliation_strings":["Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata-700 009, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata-700 009, India","institution_ids":["https://openalex.org/I106542073"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5017963965"],"corresponding_institution_ids":["https://openalex.org/I106542073"],"apc_list":{"value":850,"currency":"GBP","value_usd":1042},"apc_paid":null,"fwci":0.2778,"has_fulltext":false,"cited_by_count":15,"citation_normalized_percentile":{"value":0.49307586,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"3","issue":"11","first_page":"3717","last_page":"3717"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.22349999845027924,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.22349999845027924,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11286","display_name":"Polyoxometalates: Synthesis and Applications","score":0.20170000195503235,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.1898999959230423,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/self-assembled-vesicles","display_name":"self-assembled vesicles","score":0.7429999709129333},{"id":"https://openalex.org/keywords/catecholase-like-activity","display_name":"catecholase-like activity","score":0.9440000057220459},{"id":"https://openalex.org/keywords/benzoate-ligands","display_name":"benzoate ligands","score":0.7170000076293945},{"id":"https://openalex.org/keywords/hexamethylenetetramine","display_name":"hexamethylenetetramine","score":0.9800000190734863},{"id":"https://openalex.org/keywords/dye-encapsulation","display_name":"dye encapsulation","score":0.8889999985694885},{"id":"https://openalex.org/keywords/3-5-di-tert-butylcatechol","display_name":"3,5-di-tert-butylcatechol","score":0.9430000185966492},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5379999876022339}],"concepts":[{"id":"https://openalex.org/C168900304","wikidata":"https://www.wikidata.org/wiki/Q171407","display_name":"Valence (chemistry)","level":2,"score":0.7430450916290283},{"id":"https://openalex.org/C164866538","wikidata":"https://www.wikidata.org/wiki/Q367351","display_name":"Cluster (spacecraft)","level":2,"score":0.6928548812866211},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5391455292701721},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4504314064979553},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3389638066291809},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.33842208981513977},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.32168012857437134},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.16689446568489075},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.10539624094963074},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/c3ra22710c","doi":"https://doi.org/10.1039/c3ra22710c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3ra22710c","pdf_url":null,"source":{"id":"https://openalex.org/S2481244646","display_name":"RSC Advances","issn_l":"2046-2069","issn":["2046-2069"],"is_oa":false,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"RSC Advances","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":75,"referenced_works":["https://openalex.org/W279002246","https://openalex.org/W1548878303","https://openalex.org/W1967547035","https://openalex.org/W1967887562","https://openalex.org/W1969840554","https://openalex.org/W1973964427","https://openalex.org/W1975165348","https://openalex.org/W1976225712","https://openalex.org/W1978974747","https://openalex.org/W1982788111","https://openalex.org/W1985499860","https://openalex.org/W1985519967","https://openalex.org/W1986360500","https://openalex.org/W1989924241","https://openalex.org/W1990845410","https://openalex.org/W1993115645","https://openalex.org/W1996256024","https://openalex.org/W1999369612","https://openalex.org/W2002724434","https://openalex.org/W2002762653","https://openalex.org/W2002995703","https://openalex.org/W2005931721","https://openalex.org/W2007078348","https://openalex.org/W2007977956","https://openalex.org/W2010630242","https://openalex.org/W2011446825","https://openalex.org/W2015752004","https://openalex.org/W2024308710","https://openalex.org/W2025031859","https://openalex.org/W2027333770","https://openalex.org/W2028291957","https://openalex.org/W2028419368","https://openalex.org/W2028460275","https://openalex.org/W2031541386","https://openalex.org/W2032439653","https://openalex.org/W2034802211","https://openalex.org/W2036797574","https://openalex.org/W2038350496","https://openalex.org/W2043821944","https://openalex.org/W2049735818","https://openalex.org/W2050627023","https://openalex.org/W2056199152","https://openalex.org/W2057863409","https://openalex.org/W2059020082","https://openalex.org/W2063334178","https://openalex.org/W2063452671","https://openalex.org/W2067621687","https://openalex.org/W2073148907","https://openalex.org/W2073671615","https://openalex.org/W2075202907","https://openalex.org/W2079957384","https://openalex.org/W2080614262","https://openalex.org/W2080665513","https://openalex.org/W2082318268","https://openalex.org/W2087370039","https://openalex.org/W2089740902","https://openalex.org/W2092790192","https://openalex.org/W2094329914","https://openalex.org/W2095608520","https://openalex.org/W2102914624","https://openalex.org/W2104265498","https://openalex.org/W2105646634","https://openalex.org/W2120548400","https://openalex.org/W2121239001","https://openalex.org/W2124207597","https://openalex.org/W2146099614","https://openalex.org/W2147198209","https://openalex.org/W2149590872","https://openalex.org/W2157986221","https://openalex.org/W2160350074","https://openalex.org/W2161929578","https://openalex.org/W2166689829","https://openalex.org/W2169171157","https://openalex.org/W2329042284","https://openalex.org/W2335077682"],"related_works":["https://openalex.org/W6977212369","https://openalex.org/W2042907832","https://openalex.org/W3036553742","https://openalex.org/W2608282238","https://openalex.org/W2330139293","https://openalex.org/W4386946108","https://openalex.org/W2074186053","https://openalex.org/W2174748275","https://openalex.org/W2902972645","https://openalex.org/W6902110257"],"abstract_inverted_index":{"The":[0,21,83],"reaction":[1],"of":[2,46,80],"Mn(OBz)2\u00b74H2O":[3],"(OBz":[4],"=":[5,10],"benzoate)":[6],"with":[7,75,124],"hmt":[8,62],"(hmt":[9],"hexamethylenetetramine)":[11],"in":[12,26,77,85,130],"CH3CN":[13],"affords":[14],"a":[15,47],"mixed-valence":[16],"hexanuclear":[17],"complex":[18,22],"[MnIII2MnII4O2(hmt)4(OBz)10]":[19],"(1).":[20],"has":[23,88],"been":[24,89,111],"characterized":[25],"solid":[27],"state":[28,66,87],"by":[29,113],"elemental":[30],"analysis,":[31],"IR":[32],"spectroscopy":[33],"and":[34,59],"single-crystal":[35],"X-ray":[36],"diffraction":[37],"analysis.":[38],"X-Ray":[39],"crystal":[40],"structure":[41,74],"reveals":[42],"that":[43],"1":[44,69,118],"consists":[45],"[MnIII2MnII4O2]":[48],"core,":[49],"co-ordinated":[50],"to":[51,138],"ten":[52],"bridging":[53],"benzoates":[54],"(six":[55],"syn,-syn-\u03b71:\u03b71:\u03bc2,":[56],"four":[57,60],"\u03b71:\u03b72:\u03bc3)":[58],"terminal":[61],"groups.":[63],"In":[64],"solution":[65,86],"(acetonitrile":[67],"solvent)":[68],"spontaneously":[70],"forms":[71],"self-assembled":[72,101],"vesicular":[73,102],"diameter":[76],"the":[78,128,133],"range":[79],"100\u2013150":[81],"nm.":[82],"morphology":[84],"studied":[90],"through":[91],"various":[92],"microscopic":[93,115],"techniques":[94],"like":[95],"SEM,":[96],"TEM,":[97],"AFM":[98],"etc.":[99],"These":[100],"structures":[103],"can":[104],"encapsulate":[105],"organic":[106],"dye":[107],"molecules,":[108],"which":[109],"have":[110],"confirmed":[112],"confocal":[114],"imaging.":[116],"Complex":[117],"also":[119],"exhibits":[120],"substantial":[121],"catecholase-like":[122],"activity":[123],"3,5-di-tert-butylcatechol":[125],"(3,5-DTBC)":[126],"as":[127],"substrate":[129],"acetonitrile":[131],"solvent;":[132],"Kcat":[134],"value":[135],"is":[136],"determined":[137],"be":[139],"2337.9":[140],"h\u22121.":[141]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2015,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}