{"id":"https://openalex.org/W2002803229","doi":"https://doi.org/10.1039/dt9730001095","title":"Complex formation with heptane-3,5-dione. Stabilities of some bivalent metal chelate complexes in aqueous dioxan (50%)","display_name":"Complex formation with heptane-3,5-dione. Stabilities of some bivalent metal chelate complexes in aqueous dioxan (50%)","publication_year":1973,"publication_date":"1973-01-01","ids":{"openalex":"https://openalex.org/W2002803229","doi":"https://doi.org/10.1039/dt9730001095","mag":"2002803229"},"language":"en","primary_location":{"id":"doi:10.1039/dt9730001095","doi":"https://doi.org/10.1039/dt9730001095","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9730001095","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5042521301","display_name":"John L. Ault","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"John L. Ault","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022153306","display_name":"Hugo J. Harries","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Hugo J. Harries","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5002026660","display_name":"John R. Burgess","orcid":"https://orcid.org/0000-0003-4748-9571","observed_orcids":["https://orcid.org/0000-0003-4748-9571"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"John Burgess","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.5348,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":{"value":0.59056405,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":"10","first_page":"1095","last_page":"1095"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.5659000277519226,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.5659000277519226,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11936","display_name":"Chemical and Physical Properties in Aqueous Solutions","score":0.3596000075340271,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.0203000009059906,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cobalt-ii-complexes","display_name":"cobalt(II) complexes","score":0.8320000171661377},{"id":"https://openalex.org/keywords/cu-ii-complexes","display_name":"copper(II) complexes","score":0.9459999799728394},{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/mn-ii-complexes","display_name":"manganese(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/magnesium-ii-complexes","display_name":"magnesium(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/stability-constants","display_name":"stability constants","score":0.8370000123977661},{"id":"https://openalex.org/keywords/acid-dissociation-constants","display_name":"acid dissociation constants","score":0.9589999914169312},{"id":"https://openalex.org/keywords/protonation-enthalpy","display_name":"protonation enthalpy","score":0.843999981880188}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8074065446853638},{"id":"https://openalex.org/C2777854178","wikidata":"https://www.wikidata.org/wiki/Q150668","display_name":"Heptane","level":2,"score":0.7838718295097351},{"id":"https://openalex.org/C197404232","wikidata":"https://www.wikidata.org/wiki/Q319827","display_name":"Chelation","level":2,"score":0.7722394466400146},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.6518188118934631},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.6448606848716736},{"id":"https://openalex.org/C515602321","wikidata":"https://www.wikidata.org/wiki/Q740","display_name":"Cobalt","level":2,"score":0.5996268391609192},{"id":"https://openalex.org/C168191866","wikidata":"https://www.wikidata.org/wiki/Q4551818","display_name":"Stability constants of complexes","level":3,"score":0.5994267463684082},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.5297905802726746},{"id":"https://openalex.org/C528890316","wikidata":"https://www.wikidata.org/wiki/Q731","display_name":"Manganese","level":2,"score":0.5123721361160278},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5121755599975586},{"id":"https://openalex.org/C74998103","wikidata":"https://www.wikidata.org/wiki/Q898254","display_name":"Dissociation constant","level":3,"score":0.5016977787017822},{"id":"https://openalex.org/C543218039","wikidata":"https://www.wikidata.org/wiki/Q660","display_name":"Magnesium","level":2,"score":0.49686554074287415},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.47891151905059814},{"id":"https://openalex.org/C504270822","wikidata":"https://www.wikidata.org/wiki/Q744","display_name":"Nickel","level":2,"score":0.46758484840393066},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4441722631454468},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.3296610116958618},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17633852362632751},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.11010384559631348},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.08570918440818787},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/dt9730001095","doi":"https://doi.org/10.1039/dt9730001095","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9730001095","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2950962658","https://openalex.org/W1967870454","https://openalex.org/W4293279361","https://openalex.org/W2951544720","https://openalex.org/W1514486936","https://openalex.org/W2293842914","https://openalex.org/W1964846365","https://openalex.org/W411185988","https://openalex.org/W2318562399","https://openalex.org/W2049218087"],"abstract_inverted_index":{"The":[0],"acid":[1],"dissociation":[2],"constant":[3],"of":[4,11,35,40,49,53],"heptane-3,5-dione":[5,50],"together":[6],"with":[7,15],"the":[8,26,36],"stability":[9],"constants":[10,48],"its":[12],"chelate":[13,51],"complex":[14],"cobalt(II),":[16],"have":[17,44,59],"been":[18,45,60],"determined":[19],"in":[20],"aqueous":[21],"dioxan":[22],"(50%":[23],"v/v)":[24],"over":[25],"temperature":[27],"range":[28],"5\u201345":[29],"\u00b0C.":[30,64],"From":[31],"these":[32],"results,":[33],"values":[34],"enthalpy":[37],"and":[38,42,57],"entropy":[39],"protonation":[41],"chelation":[43],"calculated.":[46],"Stability":[47],"complexes":[52],"copper(II),":[54],"nickel(II),":[55],"manganese(II)":[56],"magnesium(II)":[58],"measured":[61],"at":[62],"25":[63]},"counts_by_year":[],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-06-24T00:00:00"}