{"id":"https://openalex.org/W2002185258","doi":"https://doi.org/10.1080/10426500307930","title":"Novel Stereoselective Phase Transfer Catalytic Synthesis and Some Applications of ( E )-2-Chlorovinylthioarenes and Hetarenes","display_name":"Novel Stereoselective Phase Transfer Catalytic Synthesis and Some Applications of ( E )-2-Chlorovinylthioarenes and Hetarenes","publication_year":2003,"publication_date":"2003-03-01","ids":{"openalex":"https://openalex.org/W2002185258","doi":"https://doi.org/10.1080/10426500307930","mag":"2002185258"},"language":"en","primary_location":{"id":"doi:10.1080/10426500307930","doi":"https://doi.org/10.1080/10426500307930","is_oa":false,"landing_page_url":"https://doi.org/10.1080/10426500307930","pdf_url":null,"source":{"id":"https://openalex.org/S70121411","display_name":"Phosphorus, sulfur, and silicon and the related elements","issn_l":"1026-7719","issn":["1026-7719","1042-6507","1563-5325"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Phosphorus, Sulfur, and Silicon and the Related Elements","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111761184","display_name":"\u041a\u0438\u0440\u0430 \u0420\u0443\u0431\u0438\u043d\u0430","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210102248","display_name":"Latvijas Organisk\u0101s Sint\u0113zes Instit\u016bts","ror":"https://ror.org/01a92vw29","country_code":"LV","type":"facility","lineage":["https://openalex.org/I4210102248","https://openalex.org/I70055295"]}],"countries":["LV"],"is_corresponding":false,"raw_author_name":"Kira Rubina","raw_affiliation_strings":["a  Latvian Institute of Organic Synthesis , Riga,  Latvia","Latvian Institute of Organic Synthesis , Riga, Latvia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Latvian Institute of Organic Synthesis , Riga,  Latvia","institution_ids":["https://openalex.org/I4210102248"]},{"raw_affiliation_string":"Latvian Institute of Organic Synthesis , Riga, Latvia","institution_ids":["https://openalex.org/I4210102248"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5024109176","display_name":"Edgars Abele","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210102248","display_name":"Latvijas Organisk\u0101s Sint\u0113zes Instit\u016bts","ror":"https://ror.org/01a92vw29","country_code":"LV","type":"facility","lineage":["https://openalex.org/I4210102248","https://openalex.org/I70055295"]}],"countries":["LV"],"is_corresponding":false,"raw_author_name":"Edgars \u0100bele","raw_affiliation_strings":["a  Latvian Institute of Organic Synthesis , Riga,  Latvia","Latvian Institute of Organic Synthesis , Riga, Latvia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Latvian Institute of Organic Synthesis , Riga,  Latvia","institution_ids":["https://openalex.org/I4210102248"]},{"raw_affiliation_string":"Latvian Institute of Organic Synthesis , Riga, Latvia","institution_ids":["https://openalex.org/I4210102248"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113621609","display_name":"Juris Popelis","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210102248","display_name":"Latvijas Organisk\u0101s Sint\u0113zes Instit\u016bts","ror":"https://ror.org/01a92vw29","country_code":"LV","type":"facility","lineage":["https://openalex.org/I4210102248","https://openalex.org/I70055295"]}],"countries":["LV"],"is_corresponding":false,"raw_author_name":"Juris Popelis","raw_affiliation_strings":["a  Latvian Institute of Organic Synthesis , Riga,  Latvia","Latvian Institute of Organic Synthesis , Riga, Latvia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Latvian Institute of Organic Synthesis , Riga,  Latvia","institution_ids":["https://openalex.org/I4210102248"]},{"raw_affiliation_string":"Latvian Institute of Organic Synthesis , Riga, Latvia","institution_ids":["https://openalex.org/I4210102248"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5054053185","display_name":"Solveiga Gr\u0131\u0304nberga","orcid":"https://orcid.org/0000-0002-7009-4220","observed_orcids":["https://orcid.org/0000-0002-7009-4220"]},"institutions":[{"id":"https://openalex.org/I4210102248","display_name":"Latvijas Organisk\u0101s Sint\u0113zes Instit\u016bts","ror":"https://ror.org/01a92vw29","country_code":"LV","type":"facility","lineage":["https://openalex.org/I4210102248","https://openalex.org/I70055295"]}],"countries":["LV"],"is_corresponding":false,"raw_author_name":"Solveiga Grinberga","raw_affiliation_strings":["a  Latvian Institute of Organic Synthesis , Riga,  Latvia","Latvian Institute of Organic Synthesis , Riga, Latvia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Latvian Institute of Organic Synthesis , Riga,  Latvia","institution_ids":["https://openalex.org/I4210102248"]},{"raw_affiliation_string":"Latvian Institute of Organic Synthesis , Riga, Latvia","institution_ids":["https://openalex.org/I4210102248"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006813438","display_name":"Pavel Arsenyan","orcid":"https://orcid.org/0000-0001-5875-2799","observed_orcids":["https://orcid.org/0000-0001-5875-2799"]},"institutions":[{"id":"https://openalex.org/I4210102248","display_name":"Latvijas Organisk\u0101s Sint\u0113zes Instit\u016bts","ror":"https://ror.org/01a92vw29","country_code":"LV","type":"facility","lineage":["https://openalex.org/I4210102248","https://openalex.org/I70055295"]}],"countries":["LV"],"is_corresponding":false,"raw_author_name":"Pavel Arsenyan","raw_affiliation_strings":["a  Latvian Institute of Organic Synthesis , Riga,  Latvia","Latvian Institute of Organic Synthesis , Riga, Latvia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Latvian Institute of Organic Synthesis , Riga,  Latvia","institution_ids":["https://openalex.org/I4210102248"]},{"raw_affiliation_string":"Latvian Institute of Organic Synthesis , Riga, Latvia","institution_ids":["https://openalex.org/I4210102248"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5022348550","display_name":"Edmunds Lukevics","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210102248","display_name":"Latvijas Organisk\u0101s Sint\u0113zes Instit\u016bts","ror":"https://ror.org/01a92vw29","country_code":"LV","type":"facility","lineage":["https://openalex.org/I4210102248","https://openalex.org/I70055295"]}],"countries":["LV"],"is_corresponding":false,"raw_author_name":"Edmunds Lukevics","raw_affiliation_strings":["a  Latvian Institute of Organic Synthesis , Riga,  Latvia","Latvian Institute of Organic Synthesis , Riga, Latvia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Latvian Institute of Organic Synthesis , Riga,  Latvia","institution_ids":["https://openalex.org/I4210102248"]},{"raw_affiliation_string":"Latvian Institute of Organic Synthesis , Riga, Latvia","institution_ids":["https://openalex.org/I4210102248"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I4210102248"],"apc_list":null,"apc_paid":null,"fwci":0.6711,"has_fulltext":false,"cited_by_count":4,"citation_normalized_percentile":{"value":0.61883231,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"178","issue":"3","first_page":"521","last_page":"529"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.8490999937057495,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.8490999937057495,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.06120000034570694,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13304","display_name":"Synthesis and Reactivity of Sulfur-Containing Compounds","score":0.05220000073313713,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hetarenes","display_name":"hetarenes","score":0.8429999947547913},{"id":"https://openalex.org/keywords/phase-transfer-catalysis","display_name":"phase-transfer catalysis","score":0.8889999985694885},{"id":"https://openalex.org/keywords/stereoselective-synthesis","display_name":"stereoselective synthesis","score":0.9789999723434448},{"id":"https://openalex.org/keywords/thiols","display_name":"thiols","score":0.7049999833106995},{"id":"https://openalex.org/keywords/1-1-2-trichloroethane","display_name":"1,1,2-trichloroethane","score":0.9959999918937683},{"id":"https://openalex.org/keywords/18-crown-6","display_name":"18-crown-6","score":0.9480000138282776},{"id":"https://openalex.org/keywords/solid-base-catalysis","display_name":"solid base catalysis","score":0.5659999847412109},{"id":"https://openalex.org/keywords/heck-reaction","display_name":"Heck reaction","score":0.8970000147819519},{"id":"https://openalex.org/keywords/stille-coupling","display_name":"Stille coupling","score":0.9369999766349792}],"concepts":[{"id":"https://openalex.org/C145255805","wikidata":"https://www.wikidata.org/wiki/Q899861","display_name":"Stille reaction","level":3,"score":0.7688877582550049},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6605163216590881},{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.6515756845474243},{"id":"https://openalex.org/C181647583","wikidata":"https://www.wikidata.org/wiki/Q903429","display_name":"Stereoselectivity","level":3,"score":0.622218132019043},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.543218731880188},{"id":"https://openalex.org/C2776469878","wikidata":"https://www.wikidata.org/wiki/Q2026994","display_name":"Solid-phase synthesis","level":3,"score":0.5287686586380005},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.49886345863342285},{"id":"https://openalex.org/C2778930939","wikidata":"https://www.wikidata.org/wiki/Q900822","display_name":"Phase-transfer catalyst","level":3,"score":0.46351730823516846},{"id":"https://openalex.org/C2779896714","wikidata":"https://www.wikidata.org/wiki/Q208366","display_name":"Xylene","level":3,"score":0.43575215339660645},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4082530438899994},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.34600138664245605},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0465112030506134},{"id":"https://openalex.org/C2779281246","wikidata":"https://www.wikidata.org/wiki/Q172847","display_name":"Peptide","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/10426500307930","doi":"https://doi.org/10.1080/10426500307930","is_oa":false,"landing_page_url":"https://doi.org/10.1080/10426500307930","pdf_url":null,"source":{"id":"https://openalex.org/S70121411","display_name":"Phosphorus, sulfur, and silicon and the related elements","issn_l":"1026-7719","issn":["1026-7719","1042-6507","1563-5325"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Phosphorus, Sulfur, and Silicon and the Related Elements","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W1965555472","https://openalex.org/W1973308886","https://openalex.org/W1975229302","https://openalex.org/W1979809543","https://openalex.org/W2012367748","https://openalex.org/W2028472989","https://openalex.org/W2102469963","https://openalex.org/W4233172592","https://openalex.org/W4245799071","https://openalex.org/W4285719527"],"related_works":["https://openalex.org/W3093995804","https://openalex.org/W2611085310","https://openalex.org/W2044431296","https://openalex.org/W2751139349","https://openalex.org/W1987131422","https://openalex.org/W3013607147","https://openalex.org/W2001359436","https://openalex.org/W2124659842","https://openalex.org/W2604635879","https://openalex.org/W2169378469"],"abstract_inverted_index":{"A":[0],"novel":[1],"two-step":[2],"method":[3],"for":[4],"the":[5,18,52],"preparation":[6],"of":[7,47],"(":[8,36,48],"E":[9,37,49],")-2-chlorovinylthioarenes":[10,38,50],"(or":[11],"hetarenes)":[12],"from":[13],"thiols":[14],"and":[15,30,54],"1,1,2-trichloroethane":[16],"in":[17,41,51],"phase":[19],"transfer":[20],"catalytic":[21],"systems":[22],"solid":[23,31],"K":[24],"2":[25],"CO":[26],"3":[27],"/solid":[28],"KI/18-crown-6/xylene":[29],"KOH/18-crown-6/toluene":[32],"has":[33,57],"been":[34,58],"developed.":[35],"were":[39],"isolated":[40],"yields":[42],"up":[43],"to":[44],"98%.":[45],"Utilization":[46],"Heck":[53],"Stille":[55],"reactions":[56],"shown.":[59]},"counts_by_year":[{"year":2013,"cited_by_count":1}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}