{"id":"https://openalex.org/W2002132963","doi":"https://doi.org/10.3184/146867809x413256","title":"Studies on the Substitution and Temperature Effects in the Insertion Reactions of Singlet State Aluminium Monohalides (1Alx) with Hydrogen Halides (Hx) (X = F, Cl, Br)","display_name":"Studies on the Substitution and Temperature Effects in the Insertion Reactions of Singlet State Aluminium Monohalides (1Alx) with Hydrogen Halides (Hx) (X = F, Cl, Br)","publication_year":2009,"publication_date":"2009-03-01","ids":{"openalex":"https://openalex.org/W2002132963","doi":"https://doi.org/10.3184/146867809x413256","mag":"2002132963"},"language":"en","primary_location":{"id":"doi:10.3184/146867809x413256","doi":"https://doi.org/10.3184/146867809x413256","is_oa":false,"landing_page_url":"https://doi.org/10.3184/146867809x413256","pdf_url":null,"source":{"id":"https://openalex.org/S121492938","display_name":"Progress in Reaction Kinetics and Mechanism","issn_l":"0079-6743","issn":["0079-6743","1468-6783","1471-406X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-20","russia-white-list-4"],"host_organization":"https://openalex.org/P4310320017","host_organization_name":"SAGE Publishing","host_organization_lineage":["https://openalex.org/P4310320017"],"host_organization_lineage_names":["SAGE Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Progress in Reaction Kinetics and Mechanism","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5056668080","display_name":"Ping Yin","orcid":"https://orcid.org/0000-0001-8348-7069","observed_orcids":["https://orcid.org/0000-0001-8348-7069"]},"institutions":[{"id":"https://openalex.org/I182707071","display_name":"Ludong University","ror":"https://ror.org/028h95t32","country_code":"CN","type":"education","lineage":["https://openalex.org/I182707071"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Ping Yin","raw_affiliation_strings":["School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","institution_ids":["https://openalex.org/I182707071"]},{"raw_affiliation_string":"School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China","institution_ids":["https://openalex.org/I182707071"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5024492997","display_name":"Yanbin Xu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I182707071","display_name":"Ludong University","ror":"https://ror.org/028h95t32","country_code":"CN","type":"education","lineage":["https://openalex.org/I182707071"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yanbin Xu Jiang Zhang","raw_affiliation_strings":["School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","institution_ids":["https://openalex.org/I182707071"]},{"raw_affiliation_string":"School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China","institution_ids":["https://openalex.org/I182707071"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111621891","display_name":"Qiang Xu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I182707071","display_name":"Ludong University","ror":"https://ror.org/028h95t32","country_code":"CN","type":"education","lineage":["https://openalex.org/I182707071"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Qiang Xu","raw_affiliation_strings":["School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","institution_ids":["https://openalex.org/I182707071"]},{"raw_affiliation_string":"School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China","institution_ids":["https://openalex.org/I182707071"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101643043","display_name":"Wei Jiang","orcid":"https://orcid.org/0009-0001-4463-238X","observed_orcids":["https://orcid.org/0009-0001-4463-238X"]},"institutions":[{"id":"https://openalex.org/I182707071","display_name":"Ludong University","ror":"https://ror.org/028h95t32","country_code":"CN","type":"education","lineage":["https://openalex.org/I182707071"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Wei Jiang","raw_affiliation_strings":["School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","institution_ids":["https://openalex.org/I182707071"]},{"raw_affiliation_string":"School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China","institution_ids":["https://openalex.org/I182707071"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100333459","display_name":"Lei Chen","orcid":"https://orcid.org/0000-0002-2935-6276","observed_orcids":["https://orcid.org/0000-0002-2935-6276"]},"institutions":[{"id":"https://openalex.org/I182707071","display_name":"Ludong University","ror":"https://ror.org/028h95t32","country_code":"CN","type":"education","lineage":["https://openalex.org/I182707071"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Lei Chen","raw_affiliation_strings":["School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","institution_ids":["https://openalex.org/I182707071"]},{"raw_affiliation_string":"School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China","institution_ids":["https://openalex.org/I182707071"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5037767540","display_name":"Chongrong Bao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I182707071","display_name":"Ludong University","ror":"https://ror.org/028h95t32","country_code":"CN","type":"education","lineage":["https://openalex.org/I182707071"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chongrong Bao","raw_affiliation_strings":["School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Materials Science, Ludong University, Yantai 264025, P. R. China","institution_ids":["https://openalex.org/I182707071"]},{"raw_affiliation_string":"School of Chemistry & Materials Science Ludong University Yantai 264025 P. R. China","institution_ids":["https://openalex.org/I182707071"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5056668080"],"corresponding_institution_ids":["https://openalex.org/I182707071"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"34","issue":"1","first_page":"43","last_page":"53"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.3831000030040741,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13253","display_name":"Photolysis and Reactive Intermediates","score":0.3831000030040741,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.24320000410079956,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.12439999729394913,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/singlet-state","display_name":"singlet state","score":0.6499999761581421},{"id":"https://openalex.org/keywords/insertion-reactions","display_name":"insertion reactions","score":0.7950000166893005},{"id":"https://openalex.org/keywords/hydrogen-halides","display_name":"hydrogen halides","score":0.968999981880188},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.5580000281333923},{"id":"https://openalex.org/keywords/reaction-thermodynamics","display_name":"reaction thermodynamics","score":0.8109999895095825},{"id":"https://openalex.org/keywords/temperature-dependence","display_name":"temperature dependence","score":0.640999972820282},{"id":"https://openalex.org/keywords/equilibrium-constants","display_name":"equilibrium constants","score":0.5950000286102295},{"id":"https://openalex.org/keywords/rate-constants","display_name":"rate constants","score":0.8960000276565552},{"id":"https://openalex.org/keywords/substitution-effect","display_name":"substitution effect","score":0.5389999747276306}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.918236494064331},{"id":"https://openalex.org/C33062035","wikidata":"https://www.wikidata.org/wiki/Q3296863","display_name":"Singlet state","level":3,"score":0.710791826248169},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.6915254592895508},{"id":"https://openalex.org/C39353612","wikidata":"https://www.wikidata.org/wiki/Q5283759","display_name":"Atmospheric temperature range","level":2,"score":0.6298233270645142},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.6045398116111755},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.534950852394104},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.5312981605529785},{"id":"https://openalex.org/C10710636","wikidata":"https://www.wikidata.org/wiki/Q857809","display_name":"Equilibrium constant","level":2,"score":0.5035261511802673},{"id":"https://openalex.org/C513153333","wikidata":"https://www.wikidata.org/wiki/Q663","display_name":"Aluminium","level":2,"score":0.4959622323513031},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.33382129669189453},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.29587143659591675},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.27244043350219727},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.21796128153800964},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.15241068601608276},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.13594764471054077},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08481860160827637},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.3184/146867809x413256","doi":"https://doi.org/10.3184/146867809x413256","is_oa":false,"landing_page_url":"https://doi.org/10.3184/146867809x413256","pdf_url":null,"source":{"id":"https://openalex.org/S121492938","display_name":"Progress in Reaction Kinetics and Mechanism","issn_l":"0079-6743","issn":["0079-6743","1468-6783","1471-406X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-20","russia-white-list-4"],"host_organization":"https://openalex.org/P4310320017","host_organization_name":"SAGE Publishing","host_organization_lineage":["https://openalex.org/P4310320017"],"host_organization_lineage_names":["SAGE Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Progress in Reaction Kinetics and Mechanism","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W67138927","https://openalex.org/W193471426","https://openalex.org/W1964593622","https://openalex.org/W1972721710","https://openalex.org/W1974096827","https://openalex.org/W1990177460","https://openalex.org/W2011498725","https://openalex.org/W2026826676","https://openalex.org/W2031050363","https://openalex.org/W2041953939","https://openalex.org/W2043091187","https://openalex.org/W2053093646","https://openalex.org/W2060161048","https://openalex.org/W2065315542","https://openalex.org/W2071181824","https://openalex.org/W2083679052","https://openalex.org/W2949188563","https://openalex.org/W2950681754","https://openalex.org/W4237575096"],"related_works":["https://openalex.org/W2002317002","https://openalex.org/W6959697019","https://openalex.org/W2031050363","https://openalex.org/W2059198885","https://openalex.org/W2058298304","https://openalex.org/W2008649188","https://openalex.org/W2355430800","https://openalex.org/W2515015361","https://openalex.org/W3006280462","https://openalex.org/W1966511918"],"abstract_inverted_index":{"The":[0,100],"insertion":[1,98],"reactions":[2],"of":[3,62,70,119,125],"singlet":[4],"aluminium":[5],"monohalides":[6],"1(AlX)":[7],"(X":[8],"=":[9],"F,":[10],"Cl,":[11],"Br)":[12],"with":[13,49,77],"hydrogen":[14],"halides":[15],"(HX)":[16],"have":[17],"been":[18],"investigated":[19],"by":[20],"the":[21,25,50,57,67,80,88,115,123],"DFT/B3LYP":[22],"method":[23],"at":[24,131,138],"B3LYP/6-311":[26],"+":[27],"G(":[28],"d,":[29],"p)":[30],"level,":[31],"which":[32],"involve":[33],"three-membered":[34],"ring":[35],"transition":[36,46],"states":[37],"(TS).":[38],"In":[39],"addition,":[40],"general":[41],"statistical":[42],"thermodynamics":[43],"and":[44,59,108,128],"Eyring":[45],"state":[47],"theory":[48],"Wigner":[51],"correction":[52],"were":[53],"used":[54],"to":[55],"study":[56],"thermodynamic":[58],"kinetic":[60],"properties":[61],"these":[63,97],"reaction":[64,81,89],"channels":[65],"within":[66],"temperature":[68,117,133],"range":[69,118],"200-1200":[71,120],"K.":[72],"It":[73],"is":[74],"concluded":[75],"that":[76],"increasing":[78],"temperature,":[79],"equilibrium":[82],"constant":[83,91],"K":[84,127],"decreases":[85],"sharply,":[86],"while":[87,122],"rate":[90],"k":[92,130],"increases":[93],"gradually":[94],"for":[95],"all":[96],"reactions.":[99],"orders":[101],"are":[102,134],"K(F)":[103],">":[104,106,110,112],"K(Cl)":[105],"K(Br)":[107],"k(Br)":[109],"k(Cl)":[111],"k(F)":[113],"over":[114],"entire":[116],"K,":[121],"differences":[124],"lg":[126,129],"low":[132],"larger":[135],"than":[136],"those":[137],"high":[139],"temperature.":[140]},"counts_by_year":[{"year":2013,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}
