{"id":"https://openalex.org/W2002008532","doi":"https://doi.org/10.1021/ie980335d","title":"Homogeneous Catalytic Hydroformylation of 1-Octene in Supercritical Carbon Dioxide Using a Novel Rhodium Catalyst with Fluorinated Arylphosphine Ligands","display_name":"Homogeneous Catalytic Hydroformylation of 1-Octene in Supercritical Carbon Dioxide Using a Novel Rhodium Catalyst with Fluorinated Arylphosphine Ligands","publication_year":1998,"publication_date":"1998-09-17","ids":{"openalex":"https://openalex.org/W2002008532","doi":"https://doi.org/10.1021/ie980335d","mag":"2002008532"},"language":"en","primary_location":{"id":"doi:10.1021/ie980335d","doi":"https://doi.org/10.1021/ie980335d","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ie980335d","pdf_url":null,"source":{"id":"https://openalex.org/S202680183","display_name":"Industrial & Engineering Chemistry Research","issn_l":"0888-5885","issn":["0888-5885","1520-5045"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Industrial &amp; Engineering Chemistry Research","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5041884920","display_name":"Daniel R. Palo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Daniel R. Palo","raw_affiliation_strings":["Environmental Engineering Program, Department of Chemical Engineering, University of Connecticut, Storrs, Connecticut 06269"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Environmental Engineering Program, Department of Chemical Engineering, University of Connecticut, Storrs, Connecticut 06269","institution_ids":["https://openalex.org/I140172145"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5011049298","display_name":"Can Erkey","orcid":"https://orcid.org/0000-0001-6539-7748","observed_orcids":["https://orcid.org/0000-0001-6539-7748","https://orcid.org/0000-0002-2715-3299"]},"institutions":[{"id":"https://openalex.org/I140172145","display_name":"University of Connecticut","ror":"https://ror.org/02der9h97","country_code":"US","type":"education","lineage":["https://openalex.org/I140172145"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Can Erkey","raw_affiliation_strings":["Environmental Engineering Program, Department of Chemical Engineering, University of Connecticut, Storrs, Connecticut 06269"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Environmental Engineering Program, Department of Chemical Engineering, University of Connecticut, Storrs, Connecticut 06269","institution_ids":["https://openalex.org/I140172145"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5011049298"],"corresponding_institution_ids":["https://openalex.org/I140172145"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":7.2168,"has_fulltext":false,"cited_by_count":85,"citation_normalized_percentile":{"value":0.9835822,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"37","issue":"10","first_page":"4203","last_page":"4206"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.92330002784729,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.92330002784729,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.06840000301599503,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10402","display_name":"Phase Equilibria and Thermodynamics","score":0.002899999963119626,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydroformylation","display_name":"hydroformylation","score":0.8659999966621399},{"id":"https://openalex.org/keywords/1-octene","display_name":"1-octene","score":0.9449999928474426},{"id":"https://openalex.org/keywords/supercritical-carbon-dioxide","display_name":"supercritical carbon dioxide","score":0.9549999833106995},{"id":"https://openalex.org/keywords/rhodium-catalysts","display_name":"rhodium catalysts","score":0.9049999713897705},{"id":"https://openalex.org/keywords/homogeneous-catalysis","display_name":"homogeneous catalysis","score":0.8640000224113464},{"id":"https://openalex.org/keywords/catalyst-solubility","display_name":"catalyst solubility","score":0.7570000290870667},{"id":"https://openalex.org/keywords/aldehyde-selectivity","display_name":"aldehyde selectivity","score":0.7129999995231628},{"id":"https://openalex.org/keywords/catalyst-recycling","display_name":"catalyst recycling","score":0.7879999876022339},{"id":"https://openalex.org/keywords/triphenylphosphine-ligands","display_name":"triphenylphosphine ligands","score":0.7799999713897705}],"concepts":[{"id":"https://openalex.org/C100805817","wikidata":"https://www.wikidata.org/wiki/Q899181","display_name":"Hydroformylation","level":4,"score":0.9812456965446472},{"id":"https://openalex.org/C521398313","wikidata":"https://www.wikidata.org/wiki/Q1087","display_name":"Rhodium","level":3,"score":0.9116553068161011},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.8411955833435059},{"id":"https://openalex.org/C134458231","wikidata":"https://www.wikidata.org/wiki/Q332582","display_name":"Supercritical carbon dioxide","level":3,"score":0.7377122640609741},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.635666012763977},{"id":"https://openalex.org/C118419359","wikidata":"https://www.wikidata.org/wiki/Q682585","display_name":"Supercritical fluid","level":2,"score":0.6042447686195374},{"id":"https://openalex.org/C2779964599","wikidata":"https://www.wikidata.org/wiki/Q161664","display_name":"1-Octene","level":4,"score":0.5814065933227539},{"id":"https://openalex.org/C109474758","wikidata":"https://www.wikidata.org/wiki/Q1411716","display_name":"Homogeneous catalysis","level":3,"score":0.5064479112625122},{"id":"https://openalex.org/C2777247709","wikidata":"https://www.wikidata.org/wiki/Q115493","display_name":"Triphenylphosphine","level":3,"score":0.4765132963657379},{"id":"https://openalex.org/C126661725","wikidata":"https://www.wikidata.org/wiki/Q903420","display_name":"Isomerization","level":3,"score":0.4604618549346924},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.41353312134742737},{"id":"https://openalex.org/C2778597550","wikidata":"https://www.wikidata.org/wiki/Q151313","display_name":"Ethylene","level":3,"score":0.06715920567512512}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ie980335d","doi":"https://doi.org/10.1021/ie980335d","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ie980335d","pdf_url":null,"source":{"id":"https://openalex.org/S202680183","display_name":"Industrial & Engineering Chemistry Research","issn_l":"0888-5885","issn":["0888-5885","1520-5045"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Industrial &amp; Engineering Chemistry Research","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320332454","display_name":"American Chemical Society Petroleum Research Fund","ror":"https://ror.org/059dqb057"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W1497254558","https://openalex.org/W1597143728","https://openalex.org/W1965055736","https://openalex.org/W2002808786","https://openalex.org/W2005753110","https://openalex.org/W2019993814","https://openalex.org/W2035635234","https://openalex.org/W2045536445","https://openalex.org/W2064549353","https://openalex.org/W2068806331","https://openalex.org/W2071691471","https://openalex.org/W2084442872","https://openalex.org/W2085551927","https://openalex.org/W2085667513","https://openalex.org/W2092993934","https://openalex.org/W2096753085","https://openalex.org/W2131838436","https://openalex.org/W2952105976","https://openalex.org/W4251813169"],"related_works":["https://openalex.org/W1983892635","https://openalex.org/W1460558835","https://openalex.org/W1973090071","https://openalex.org/W2031107856","https://openalex.org/W2168226645","https://openalex.org/W51375331","https://openalex.org/W2043177607","https://openalex.org/W2007290157","https://openalex.org/W2116158137","https://openalex.org/W2046851246"],"abstract_inverted_index":{"A":[0],"novel":[1,56],"rhodium-based":[2],"catalyst":[3,57,87],"was":[4,58,70,88],"developed":[5],"for":[6],"homogeneous":[7],"hydroformylation":[8,51],"in":[9,29,91],"supercritical":[10,31],"carbon":[11],"dioxide.":[12],"The":[13,86],"catalyst,":[14],"trans":[15],"-RhCl(CO)(P(":[16],"p":[17],"-CF":[18],"3":[19,25],"C":[20],"6":[21],"H":[22],"4":[23],")":[24,26],"2,":[27],"has":[28],"the":[30,55],"fluid":[32],"reaction":[33],"mixture":[34],"moderate":[35],"solubility":[36],"(>5.5":[37],"mM),":[38],"2":[39],"orders":[40],"of":[41,52,68,77],"magnitude":[42],"greater":[43],"than":[44],"most":[45],"conventional":[46],"metal\u2212triphenylphosphine":[47],"catalysts.":[48],"Homogeneous":[49],"catalytic":[50],"1-octene":[53,69],"using":[54],"carried":[59],"out":[60],"at":[61],"343":[62],"K":[63],"and":[64,80,101],"272":[65],"atm.":[66],"Conversion":[67],"complete,":[71],"with":[72],"a":[73],"normal/branched":[74],"aldehyde":[75],"ratio":[76],"ca.":[78],"2.4":[79],"negligible":[81],"hydrogenation":[82],"or":[83],"isomerization":[84],"products.":[85],"also":[89],"recoverable":[90],"its":[92],"original":[93],"form,":[94],"as":[95],"confirmed":[96],"by":[97],"31":[98],"P":[99],"NMR":[100],"FTIR":[102],"spectroscopy.":[103]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":4},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}
