{"id":"https://openalex.org/W2000778411","doi":"https://doi.org/10.1135/cccc19861293","title":"Photochemical hydrolysis of some nitrophenyl acetates","display_name":"Photochemical hydrolysis of some nitrophenyl acetates","publication_year":1986,"publication_date":"1986-01-01","ids":{"openalex":"https://openalex.org/W2000778411","doi":"https://doi.org/10.1135/cccc19861293","mag":"2000778411"},"language":"en","primary_location":{"id":"doi:10.1135/cccc19861293","doi":"https://doi.org/10.1135/cccc19861293","is_oa":false,"landing_page_url":"https://doi.org/10.1135/cccc19861293","pdf_url":null,"source":{"id":"https://openalex.org/S162571691","display_name":"Collection of Czechoslovak Chemical Communications","issn_l":"0010-0765","issn":["0010-0765","1212-6950"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Collection of Czechoslovak Chemical Communications","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5008377738","display_name":"Petr Kuzmi\u010d","orcid":"https://orcid.org/0000-0001-5250-8381","observed_orcids":["https://orcid.org/0000-0001-5250-8381"]},"institutions":[{"id":"https://openalex.org/I4210145889","display_name":"Czech Academy of Sciences, Institute of Organic Chemistry and Biochemistry","ror":"https://ror.org/04nfjn472","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210145889"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Petr Kuzmi\u010d","raw_affiliation_strings":["Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague","institution_ids":["https://openalex.org/I4210145889"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006720348","display_name":"Libu\u0161e Pavl\u00ed\u010dkov\u00e1","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210145889","display_name":"Czech Academy of Sciences, Institute of Organic Chemistry and Biochemistry","ror":"https://ror.org/04nfjn472","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210145889"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Libu\u0161e Pavl\u00ed\u010dkov\u00e1","raw_affiliation_strings":["Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague","institution_ids":["https://openalex.org/I4210145889"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5006054870","display_name":"Milan Sou\u010dek","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210145889","display_name":"Czech Academy of Sciences, Institute of Organic Chemistry and Biochemistry","ror":"https://ror.org/04nfjn472","country_code":"CZ","type":"facility","lineage":["https://openalex.org/I202391551","https://openalex.org/I4210145889"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Milan Sou\u010dek","raw_affiliation_strings":["Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague","institution_ids":["https://openalex.org/I4210145889"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I4210145889"],"apc_list":{"value":3660,"currency":"USD","value_usd":3660},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.12319598,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"51","issue":"6","first_page":"1293","last_page":"1300"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.7660999894142151,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.7660999894142151,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.21060000360012054,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.011300000362098217,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/4-nitrophenyl-acetate","display_name":"4-nitrophenyl acetate","score":0.8460000157356262},{"id":"https://openalex.org/keywords/uv-photolysis","display_name":"UV photolysis","score":0.765999972820282},{"id":"https://openalex.org/keywords/quantum-yield","display_name":"quantum yield","score":0.6639999747276306},{"id":"https://openalex.org/keywords/phenol-formation","display_name":"phenol formation","score":0.6899999976158142},{"id":"https://openalex.org/keywords/triplet-state","display_name":"triplet state","score":0.7860000133514404},{"id":"https://openalex.org/keywords/excited-state-protonation","display_name":"excited-state protonation","score":0.8339999914169312},{"id":"https://openalex.org/keywords/acid-catalysis","display_name":"acid catalysis","score":0.6399999856948853},{"id":"https://openalex.org/keywords/18o-labeling","display_name":"18O labeling","score":0.7139999866485596},{"id":"https://openalex.org/keywords/ester-hydrolysis","display_name":"ester hydrolysis","score":0.8190000057220459}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9074835777282715},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.8228327631950378},{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.7563382387161255},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.7246385812759399},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.7032914161682129},{"id":"https://openalex.org/C2780639532","wikidata":"https://www.wikidata.org/wiki/Q7041427","display_name":"Nitro","level":3,"score":0.6511855125427246},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.6362257599830627},{"id":"https://openalex.org/C121745418","wikidata":"https://www.wikidata.org/wiki/Q585536","display_name":"Quenching (fluorescence)","level":3,"score":0.5765668749809265},{"id":"https://openalex.org/C2778689049","wikidata":"https://www.wikidata.org/wiki/Q898422","display_name":"Substituent","level":2,"score":0.5688319802284241},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.5424540638923645},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.4496026635169983},{"id":"https://openalex.org/C2777728882","wikidata":"https://www.wikidata.org/wiki/Q407142","display_name":"Phenols","level":2,"score":0.44773995876312256},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3723984360694885},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2193569540977478},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.1316603422164917},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.05694308876991272},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1135/cccc19861293","doi":"https://doi.org/10.1135/cccc19861293","is_oa":false,"landing_page_url":"https://doi.org/10.1135/cccc19861293","pdf_url":null,"source":{"id":"https://openalex.org/S162571691","display_name":"Collection of Czechoslovak Chemical Communications","issn_l":"0010-0765","issn":["0010-0765","1212-6950"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Collection of Czechoslovak Chemical Communications","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":1,"referenced_works":["https://openalex.org/W1497399712"],"related_works":["https://openalex.org/W2068785579","https://openalex.org/W2097425917","https://openalex.org/W1993465881","https://openalex.org/W4407320303","https://openalex.org/W2013447589","https://openalex.org/W1987128175","https://openalex.org/W1983873215","https://openalex.org/W2080984970","https://openalex.org/W2137536530","https://openalex.org/W2311364640"],"abstract_inverted_index":{"Nitro":[0],"substituent":[1],"exhibits":[2],"a":[3,75,136],"meta-activating":[4],"effect":[5],"on":[6],"the":[7,30,33,62,65,72,79,97,102,105,113,119,132,140],"course":[8],"of":[9,12,18,32,61,64,74,82,96,104,110,121,139],"photochemical":[10,53,99],"hydrolysis":[11,138],"phenyl":[13],"acetates":[14,23,46],"since":[15],"UV":[16],"photolysis":[17,120],"isomeric":[19],"4-":[20],"and":[21,40,44,57],"3-nitrophenyl":[22],"in":[24,51,89,124],"neutral":[25],"aqueous":[26],"solution":[27],"leads":[28],"to":[29],"formation":[31],"corresponding":[34],"phenols":[35],"with":[36,68,78],"quantum":[37],"yields":[38],"0.002":[39,56],"0.006,":[41],"respectively;":[42],"2-methoxy-4-nitro-":[43],"2-methoxy-5-nitrophenyl":[45,122],"showed":[47],"still":[48],"greater":[49],"difference":[50],"their":[52],"reactivity":[54],"(\u03a6r":[55],"0.129,":[58],"respectively).":[59],"Quenching":[60],"photohydrolysis":[63],"latter":[66],"compound":[67],"2,4-hexadienoic":[69],"acid":[70],"indicates":[71],"participation":[73],"triplet":[76],"state":[77],"effective":[80],"lifetime":[81],"0.15":[83],"\u03bcs.":[84],"The":[85],"photoreaction":[86,133],"is":[87,101,127],"accelerated":[88],"acidic":[90],"media":[91],"which":[92,126],"means":[93],"that":[94,131],"one":[95],"early":[98],"steps":[100],"protonation":[103],"excited":[106],"state.":[107],"No":[108],"incorporation":[109],"18O":[111],"into":[112],"product":[114],"molecule":[115],"was":[116],"observed":[117],"after":[118],"acetate":[123],"H218O,":[125],"an":[128],"unambiguous":[129],"evidence":[130],"proceeds":[134],"as":[135],"light-induced":[137],"ester":[141],"bond.":[142]},"counts_by_year":[],"updated_date":"2026-11-01T11:40:01.658920","created_date":"2016-06-24T00:00:00"}