{"id":"https://openalex.org/W2000506171","doi":"https://doi.org/10.1021/jp030091x","title":"Model Catalyst Studies on Vanadia Particles Deposited onto a Thin-Film Alumina Support. 2. Interaction with Carbon Monoxide","display_name":"Model Catalyst Studies on Vanadia Particles Deposited onto a Thin-Film Alumina Support. 2. Interaction with Carbon Monoxide","publication_year":2003,"publication_date":"2003-07-22","ids":{"openalex":"https://openalex.org/W2000506171","doi":"https://doi.org/10.1021/jp030091x","mag":"2000506171"},"language":"en","primary_location":{"id":"doi:10.1021/jp030091x","doi":"https://doi.org/10.1021/jp030091x","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp030091x","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5020337181","display_name":"Norbert Magg","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Norbert Magg","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany","institution_ids":["https://openalex.org/I2800875726"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000053341","display_name":"Javier B. Giorgi","orcid":"https://orcid.org/0000-0001-9120-5594","observed_orcids":["https://orcid.org/0000-0001-9120-5594"]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Javier B. Giorgi","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany","institution_ids":["https://openalex.org/I2800875726"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5060252411","display_name":"Ayman Hammoudeh","orcid":"https://orcid.org/0000-0003-0037-2157","observed_orcids":["https://orcid.org/0000-0003-0037-2157"]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Ayman Hammoudeh","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany","institution_ids":["https://openalex.org/I2800875726"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075626502","display_name":"Thomas A. Schroeder","orcid":"https://orcid.org/0000-0002-7547-3828","observed_orcids":["https://orcid.org/0000-0002-7547-3828"]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Thomas Schroeder","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany","institution_ids":["https://openalex.org/I2800875726"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111571400","display_name":"Marcus B\u00e4umer","orcid":"https://orcid.org/0000-0002-8620-1764","observed_orcids":["https://orcid.org/0000-0002-8620-1764"]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Marcus B\u00e4umer","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany","institution_ids":["https://openalex.org/I2800875726"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5072703741","display_name":"Hans\u2010Joachim Freund","orcid":"https://orcid.org/0000-0001-5188-852X","observed_orcids":["https://orcid.org/0000-0001-5188-852X"]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Hans-Joachim Freund","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany","institution_ids":["https://openalex.org/I2800875726"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5072703741"],"corresponding_institution_ids":["https://openalex.org/I2800875726"],"apc_list":null,"apc_paid":null,"fwci":1.5501,"has_fulltext":false,"cited_by_count":24,"citation_normalized_percentile":{"value":0.80668085,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":96},"biblio":{"volume":"107","issue":"34","first_page":"9003","last_page":"9010"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.8955000042915344,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":0.8955000042915344,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11825","display_name":"Catalysis and Oxidation Reactions","score":0.1014999970793724,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10495","display_name":"Catalysts for Methane Reforming","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alumina-support","display_name":"alumina support","score":0.8550000190734863},{"id":"https://openalex.org/keywords/co-adsorption","display_name":"CO adsorption","score":0.7820000052452087},{"id":"https://openalex.org/keywords/co-oxidation","display_name":"CO oxidation","score":0.7509999871253967},{"id":"https://openalex.org/keywords/particle-size-effects","display_name":"particle size effects","score":0.6460000276565552},{"id":"https://openalex.org/keywords/co2-formation","display_name":"CO2 formation","score":0.5460000038146973},{"id":"https://openalex.org/keywords/defect-sites","display_name":"defect sites","score":0.671999990940094},{"id":"https://openalex.org/keywords/model-catalysts","display_name":"model catalysts","score":0.5099999904632568}],"concepts":[{"id":"https://openalex.org/C512735826","wikidata":"https://www.wikidata.org/wiki/Q2025","display_name":"Carbon monoxide","level":3,"score":0.6865354776382446},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.6322456002235413},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6306480169296265},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.6116044521331787},{"id":"https://openalex.org/C155916967","wikidata":"https://www.wikidata.org/wiki/Q2402805","display_name":"Thermal desorption spectroscopy","level":4,"score":0.5460202693939209},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.4916446805000305},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.47825801372528076},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.4642788767814636},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4578721225261688},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.45420145988464355},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.447584331035614},{"id":"https://openalex.org/C540031477","wikidata":"https://www.wikidata.org/wiki/Q629","display_name":"Oxygen","level":2,"score":0.4474058151245117},{"id":"https://openalex.org/C7070889","wikidata":"https://www.wikidata.org/wiki/Q902488","display_name":"Monolayer","level":2,"score":0.42713814973831177},{"id":"https://openalex.org/C33790079","wikidata":"https://www.wikidata.org/wiki/Q899417","display_name":"Chemisorption","level":3,"score":0.41684070229530334},{"id":"https://openalex.org/C2780289051","wikidata":"https://www.wikidata.org/wiki/Q7023815","display_name":"Nial","level":4,"score":0.4109647274017334},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.33319082856178284},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3036912977695465},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2819368541240692},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.19706571102142334},{"id":"https://openalex.org/C2780026712","wikidata":"https://www.wikidata.org/wiki/Q37756","display_name":"Alloy","level":2,"score":0.09992605447769165},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.07208731770515442},{"id":"https://openalex.org/C27501479","wikidata":"https://www.wikidata.org/wiki/Q428069","display_name":"Intermetallic","level":3,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/jp030091x","doi":"https://doi.org/10.1021/jp030091x","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp030091x","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},{"id":"pmh:oai:edoc.mpg.de:175446","doi":null,"is_oa":false,"landing_page_url":"http://edoc.mpg.de/175446","pdf_url":null,"source":{"id":"https://openalex.org/S4406922265","display_name":"Max Planck Institute for Plasma Physics","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"The Journal of Physical Chemistry B, v.107, 9003-9010 (2003)","raw_type":"Article"},{"id":"pmh:oai:escidoc.org:escidoc:740341","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/11858/00-001M-0000-0011-1272-5","pdf_url":null,"source":{"id":"https://openalex.org/S7407052962","display_name":"Max Planck Digital Library","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210088280","host_organization_name":"Max Planck Digital Library","host_organization_lineage":["https://openalex.org/I4210088280"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:pure.mpg.de:item_740341","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/11858/00-001M-0000-0011-1272-5","pdf_url":null,"source":{"id":"https://openalex.org/S4306400654","display_name":"MPG.PuRe (Max Planck Society)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I149899117","host_organization_name":"Max Planck Society","host_organization_lineage":["https://openalex.org/I149899117"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":31,"referenced_works":["https://openalex.org/W357396208","https://openalex.org/W1970783218","https://openalex.org/W1974985690","https://openalex.org/W1977856852","https://openalex.org/W1983852360","https://openalex.org/W1990023090","https://openalex.org/W1992351902","https://openalex.org/W1995548022","https://openalex.org/W1995587181","https://openalex.org/W1997223842","https://openalex.org/W2009106052","https://openalex.org/W2010154632","https://openalex.org/W2023335220","https://openalex.org/W2026344482","https://openalex.org/W2027178781","https://openalex.org/W2032534333","https://openalex.org/W2047154014","https://openalex.org/W2048782932","https://openalex.org/W2049409970","https://openalex.org/W2052023009","https://openalex.org/W2055728662","https://openalex.org/W2060615858","https://openalex.org/W2064026454","https://openalex.org/W2074247571","https://openalex.org/W2083527345","https://openalex.org/W2088813666","https://openalex.org/W2090264787","https://openalex.org/W2091728027","https://openalex.org/W2142412171","https://openalex.org/W2156102260","https://openalex.org/W2782933432"],"related_works":["https://openalex.org/W1992351902","https://openalex.org/W2116001005","https://openalex.org/W2007934285","https://openalex.org/W2151738942","https://openalex.org/W2126074017","https://openalex.org/W2081037267","https://openalex.org/W1602868730","https://openalex.org/W2134336935","https://openalex.org/W2093937894","https://openalex.org/W2154947348"],"abstract_inverted_index":{"The":[0,38],"interaction":[1],"of":[2,41,75,101,140,145,151,160,180,197,220],"CO":[3,62,85,146,161,168,183,187],"molecules":[4],"with":[5,92,119,124],"a":[6,35,68,73,142,175,190,195],"model":[7,43,153],"catalyst":[8],"system":[9,44],"formed":[10],"by":[11,49,194],"alumina-supported":[12],"vanadia":[13,76,81],"particles":[14,133,170],"was":[15,32],"studied":[16],"utilizing":[17],"infrared":[18],"(IR)":[19],"spectroscopy.":[20,59],"A":[21,178],"thin,":[22],"well-ordered":[23],"alumina":[24],"film":[25],"grown":[26],"on":[27],"the":[28,99,102,129,149,167,181,204,212,218,221],"NiAl(110)":[29],"alloy":[30],"surface":[31,100],"used":[33],"as":[34,72],"support":[36],"oxide.":[37],"structural":[39],"characterization":[40],"this":[42,135],"has":[45],"been":[46],"performed":[47],"previously":[48],"applying":[50],"scanning":[51],"tunneling":[52],"microscopy,":[53],"X-ray":[54],"photoelectron":[55],"spectroscopy,":[56],"and":[57],"IR":[58],"Exposure":[60],"to":[61,116,171,186,201,210],"at":[63,98,128],"90":[64],"K":[65],"results":[66],"in":[67,134],"complex":[69],"adsorption":[70],"behavior":[71],"function":[74],"particle":[77],"size.":[78],"At":[79,104],"high":[80],"coverages,":[82,106],"only":[83,157],"one":[84],"species":[86,110,213],"can":[87],"be":[88,117,211],"detected":[89],"that":[90,214],"interacts":[91],"vanadyl":[93,205],"groups":[94],"(V":[95],"O)":[96],"present":[97],"particles.":[103],"lower":[105],"however,":[107],"three":[108],"further":[109],"were":[111],"observed.":[112],"Their":[113],"existence":[114],"seems":[115],"correlated":[118],"either":[120],"defect":[121],"sites":[122,126],"or":[123],"special":[125],"provided":[127],"vanadia\u2212alumina":[130],"interface.":[131],"Furthermore,":[132],"coverage":[136],"regime":[137],"are":[138],"capable":[139],"adsorbing":[141],"maximum":[143],"amount":[144],"molecules.":[147],"Regarding":[148],"reactivity":[150],"our":[152,202],"system,":[154],"we":[155],"found":[156],"molecular":[158],"desorption":[159],"upon":[162],"thermal":[163],"treatment.":[164],"However,":[165],"exposing":[166],"covered":[169],"low-energy":[172],"electrons":[173],"renders":[174],"reaction":[176],"possible.":[177],"portion":[179],"adsorbed":[182],"gets":[184],"oxidized":[185],"2":[188],"via":[189],"redox":[191],"mechanism,":[192],"i.e.,":[193],"transfer":[196],"lattice":[198],"oxygen.":[199],"According":[200],"experiments,":[203],"oxygen":[206],"does":[207],"not":[208],"seem":[209],"is":[215],"consumed":[216],"during":[217],"course":[219],"reaction.":[222]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}