{"id":"https://openalex.org/W2000487015","doi":"https://doi.org/10.1002/app.1977.070210207","title":"The absorption of direct dyes by crosslinked cellulose. II. Rate of dyeing and diffusivity","display_name":"The absorption of direct dyes by crosslinked cellulose. II. Rate of dyeing and diffusivity","publication_year":1977,"publication_date":"1977-02-01","ids":{"openalex":"https://openalex.org/W2000487015","doi":"https://doi.org/10.1002/app.1977.070210207","mag":"2000487015"},"language":"en","primary_location":{"id":"doi:10.1002/app.1977.070210207","doi":"https://doi.org/10.1002/app.1977.070210207","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.1977.070210207","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5085005932","display_name":"E. Chianakwalam Ibe","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"E. Chianakwalam Ibe","raw_affiliation_strings":["Fibers and Polymers Laboratory, Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fibers and Polymers Laboratory, Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5059006663","display_name":"Emery I. Valko","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Emery I. Valko","raw_affiliation_strings":["Deceased June 20, 1975","Fibers and Polymers Laboratory, Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Deceased June 20, 1975","institution_ids":[]},{"raw_affiliation_string":"Fibers and Polymers Laboratory, Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139","institution_ids":["https://openalex.org/I63966007"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I63966007"],"apc_list":{"value":4140,"currency":"USD","value_usd":4140},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.42352205,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"21","issue":"2","first_page":"385","last_page":"400"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11511","display_name":"Dyeing and Modifying Textile Fibers","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/2215","display_name":"Building and Construction"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11511","display_name":"Dyeing and Modifying Textile Fibers","score":0.9789999723434448,"subfield":{"id":"https://openalex.org/subfields/2215","display_name":"Building and Construction"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10610","display_name":"Advanced Cellulose Research Studies","score":0.017999999225139618,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13604","display_name":"Adsorption, diffusion, and thermodynamic properties of materials","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/direct-dyes","display_name":"direct dyes","score":0.9390000104904175},{"id":"https://openalex.org/keywords/crosslinked-cellulose","display_name":"crosslinked cellulose","score":0.9710000157356262},{"id":"https://openalex.org/keywords/cellophane","display_name":"cellophane","score":0.9380000233650208},{"id":"https://openalex.org/keywords/dyeing-rate","display_name":"dyeing rate","score":0.871999979019165},{"id":"https://openalex.org/keywords/dye-diffusion","display_name":"dye diffusion","score":0.7630000114440918},{"id":"https://openalex.org/keywords/diffusion-coefficient","display_name":"diffusion coefficient","score":0.6200000047683716},{"id":"https://openalex.org/keywords/crosslink-density","display_name":"crosslink density","score":0.7910000085830688},{"id":"https://openalex.org/keywords/pore-model","display_name":"pore model","score":0.9940000176429749},{"id":"https://openalex.org/keywords/free-volume","display_name":"free volume","score":0.6909999847412109},{"id":"https://openalex.org/keywords/tortuosity","display_name":"tortuosity","score":0.7300000190734863}],"concepts":[{"id":"https://openalex.org/C2778485729","wikidata":"https://www.wikidata.org/wiki/Q1164991","display_name":"Dyeing","level":2,"score":0.8994694948196411},{"id":"https://openalex.org/C37668627","wikidata":"https://www.wikidata.org/wiki/Q3381809","display_name":"Thermal diffusivity","level":2,"score":0.6566543579101562},{"id":"https://openalex.org/C2778431162","wikidata":"https://www.wikidata.org/wiki/Q193841","display_name":"Cellophane","level":2,"score":0.6541520357131958},{"id":"https://openalex.org/C2779251873","wikidata":"https://www.wikidata.org/wiki/Q80294","display_name":"Cellulose","level":2,"score":0.6233766078948975},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6201854348182678},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5979270935058594},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.5466578006744385},{"id":"https://openalex.org/C2778540859","wikidata":"https://www.wikidata.org/wiki/Q152234","display_name":"Swelling","level":2,"score":0.5158292651176453},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.496991902589798},{"id":"https://openalex.org/C125287762","wikidata":"https://www.wikidata.org/wiki/Q1758948","display_name":"Absorption (acoustics)","level":2,"score":0.4817781150341034},{"id":"https://openalex.org/C206175624","wikidata":"https://www.wikidata.org/wiki/Q595731","display_name":"Branching (polymer chemistry)","level":2,"score":0.4516462981700897},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.3831622302532196},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.24847382307052612},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/app.1977.070210207","doi":"https://doi.org/10.1002/app.1977.070210207","is_oa":false,"landing_page_url":"https://doi.org/10.1002/app.1977.070210207","pdf_url":null,"source":{"id":"https://openalex.org/S200764475","display_name":"Journal of Applied Polymer Science","issn_l":"0021-8995","issn":["0021-8995","1097-4628"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Applied Polymer Science","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":11,"referenced_works":["https://openalex.org/W1975107771","https://openalex.org/W1986533775","https://openalex.org/W1990687663","https://openalex.org/W2004806064","https://openalex.org/W2015315167","https://openalex.org/W2033409065","https://openalex.org/W2039688646","https://openalex.org/W2081322206","https://openalex.org/W2142567869","https://openalex.org/W2611774657","https://openalex.org/W4211033041"],"related_works":["https://openalex.org/W2393868882","https://openalex.org/W2096421131","https://openalex.org/W2360814995","https://openalex.org/W2188073556","https://openalex.org/W1997310609","https://openalex.org/W2358582777","https://openalex.org/W2382523356","https://openalex.org/W2376574940","https://openalex.org/W1997984795","https://openalex.org/W2347423521"],"abstract_inverted_index":{"Abstract":[0],"The":[1,105,121,139,164,189],"effect":[2,157],"of":[3,12,14,44,51,60,81,91,94,99,108,126,142,158,211],"crosslinking":[4,36,52,159,174,200],"in":[5,77,86,111,130,215],"the":[6,10,35,42,58,74,78,82,89,92,100,109,112,118,127,131,136,145,149,156,161,176,183,187,202,207,212,216],"dry":[7],"state":[8],"on":[9,160],"rate":[11,43,93,119],"dyeing":[13,45,95],"cellophane":[15],"with":[16],"two":[17,140],"direct":[18],"dyes,":[19],"Chrysophenine":[20],"G":[21],"and":[22,31,148,180,185,209],"Chlorazol":[23],"Sky":[24],"Blue":[25],"FF,":[26],"has":[27],"been":[28],"studied.":[29],"Dimethylolethyleneurea":[30],"bis(hydroxyethyl)":[32],"sulfone":[33],"were":[34,115,133,152],"agents.":[37],"It":[38,70],"was":[39,46,65,71],"found":[40],"that":[41,73,98,173,199],"reduced":[47,66],"at":[48,63,102],"high":[49],"degree":[50],"by":[53,67,171,197,205],"more":[54],"than":[55,97],"90%,":[56],"whereas":[57],"amount":[59],"dye":[61,128],"absorbed":[62],"equilibrium":[64],"only":[68],"40%.":[69],"concluded":[72],"major":[75],"factor":[76],"practical":[79],"undyeability":[80],"crosslinked":[83],"cellulose":[84,113,213,217],"fibers":[85],"commerce":[87],"is":[88],"reduction":[90],"rather":[96],"absorption":[101],"final":[103],"equilibrium.":[104],"average":[106,177],"diffusivities":[107],"dyes":[110],"film":[114],"calculated":[116],"from":[117,135],"data.":[120],"diffusion":[122,162],"coefficients":[123],"as":[124],"functions":[125],"concentration":[129,210],"films":[132],"estimated":[134],"diffusivity":[137],"values.":[138],"models":[141],"swollen":[143],"cellulose,":[144],"pore":[146,165,178],"model":[147,166,191],"gel":[150,190],"model,":[151],"applied":[153],"to":[154],"explain":[155],"coefficients.":[163],"offers":[167,192],"a":[168],"satisfactory":[169,195],"explanation":[170,196],"assuming":[172,198],"reduces":[175,201],"diameter":[179],"therefore":[181],"increases":[182],"drag":[184],"also":[186],"tortuosity.":[188],"an":[193],"equally":[194],"free":[203],"volume":[204],"increasing":[206],"rigidity":[208],"chains":[214],"gel.":[218]},"counts_by_year":[],"updated_date":"2026-09-23T05:00:35.095934","created_date":"2025-10-10T00:00:00"}