{"id":"https://openalex.org/W2000375726","doi":"https://doi.org/10.1021/ic9513604","title":"Structural and Functional Models for the Dinuclear Copper Active Site in Catechol Oxidases: Syntheses, X-ray Crystal Structures, Magnetic and Spectral Properties, and X-ray Absorption Spectroscopic Studies in Solid State and in Solution","display_name":"Structural and Functional Models for the Dinuclear Copper Active Site in Catechol Oxidases: Syntheses, X-ray Crystal Structures, Magnetic and Spectral Properties, and X-ray Absorption Spectroscopic Studies in Solid State and in Solution","publication_year":1996,"publication_date":"1996-01-01","ids":{"openalex":"https://openalex.org/W2000375726","doi":"https://doi.org/10.1021/ic9513604","mag":"2000375726","pmid":"https://pubmed.ncbi.nlm.nih.gov/11666546"},"language":"en","primary_location":{"id":"doi:10.1021/ic9513604","doi":"https://doi.org/10.1021/ic9513604","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic9513604","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5002758835","display_name":"Frank Zippel","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22465464","display_name":"University of M\u00fcnster","ror":"https://ror.org/00pd74e08","country_code":"DE","type":"education","lineage":["https://openalex.org/I22465464"]},{"id":"https://openalex.org/I2801876189","display_name":"Deutsches Elektronen-Synchrotron DESY","ror":"https://ror.org/01js2sh04","country_code":"DE","type":"facility","lineage":["https://openalex.org/I1305996414","https://openalex.org/I2801876189"]},{"id":"https://openalex.org/I31512782","display_name":"Technische Universit\u00e4t Darmstadt","ror":"https://ror.org/05n911h24","country_code":"DE","type":"education","lineage":["https://openalex.org/I31512782"]},{"id":"https://openalex.org/I4210138560","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/03mstc592","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560"]},{"id":"https://openalex.org/I4210153543","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/050589e39","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Frank Zippel","raw_affiliation_strings":["Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany","institution_ids":["https://openalex.org/I22465464","https://openalex.org/I2801876189","https://openalex.org/I31512782","https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043089688","display_name":"Friedhelm Ahlers","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22465464","display_name":"University of M\u00fcnster","ror":"https://ror.org/00pd74e08","country_code":"DE","type":"education","lineage":["https://openalex.org/I22465464"]},{"id":"https://openalex.org/I2801876189","display_name":"Deutsches Elektronen-Synchrotron DESY","ror":"https://ror.org/01js2sh04","country_code":"DE","type":"facility","lineage":["https://openalex.org/I1305996414","https://openalex.org/I2801876189"]},{"id":"https://openalex.org/I31512782","display_name":"Technische Universit\u00e4t Darmstadt","ror":"https://ror.org/05n911h24","country_code":"DE","type":"education","lineage":["https://openalex.org/I31512782"]},{"id":"https://openalex.org/I4210138560","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/03mstc592","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560"]},{"id":"https://openalex.org/I4210153543","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/050589e39","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Friedhelm Ahlers","raw_affiliation_strings":["Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany","institution_ids":["https://openalex.org/I22465464","https://openalex.org/I2801876189","https://openalex.org/I31512782","https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112638169","display_name":"R\u00fcdiger Werner","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22465464","display_name":"University of M\u00fcnster","ror":"https://ror.org/00pd74e08","country_code":"DE","type":"education","lineage":["https://openalex.org/I22465464"]},{"id":"https://openalex.org/I2801876189","display_name":"Deutsches Elektronen-Synchrotron DESY","ror":"https://ror.org/01js2sh04","country_code":"DE","type":"facility","lineage":["https://openalex.org/I1305996414","https://openalex.org/I2801876189"]},{"id":"https://openalex.org/I31512782","display_name":"Technische Universit\u00e4t Darmstadt","ror":"https://ror.org/05n911h24","country_code":"DE","type":"education","lineage":["https://openalex.org/I31512782"]},{"id":"https://openalex.org/I4210138560","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/03mstc592","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560"]},{"id":"https://openalex.org/I4210153543","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/050589e39","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"R\u00fcdiger Werner","raw_affiliation_strings":["Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany","institution_ids":["https://openalex.org/I22465464","https://openalex.org/I2801876189","https://openalex.org/I31512782","https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003092243","display_name":"W. Haase","orcid":"https://orcid.org/0000-0002-3276-3614","observed_orcids":["https://orcid.org/0000-0002-3276-3614"]},"institutions":[{"id":"https://openalex.org/I22465464","display_name":"University of M\u00fcnster","ror":"https://ror.org/00pd74e08","country_code":"DE","type":"education","lineage":["https://openalex.org/I22465464"]},{"id":"https://openalex.org/I2801876189","display_name":"Deutsches Elektronen-Synchrotron DESY","ror":"https://ror.org/01js2sh04","country_code":"DE","type":"facility","lineage":["https://openalex.org/I1305996414","https://openalex.org/I2801876189"]},{"id":"https://openalex.org/I31512782","display_name":"Technische Universit\u00e4t Darmstadt","ror":"https://ror.org/05n911h24","country_code":"DE","type":"education","lineage":["https://openalex.org/I31512782"]},{"id":"https://openalex.org/I4210138560","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/03mstc592","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560"]},{"id":"https://openalex.org/I4210153543","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/050589e39","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Wolfgang Haase","raw_affiliation_strings":["Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany","institution_ids":["https://openalex.org/I22465464","https://openalex.org/I2801876189","https://openalex.org/I31512782","https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110048458","display_name":"Hans\u2010Friedrich Nolting","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22465464","display_name":"University of M\u00fcnster","ror":"https://ror.org/00pd74e08","country_code":"DE","type":"education","lineage":["https://openalex.org/I22465464"]},{"id":"https://openalex.org/I2801876189","display_name":"Deutsches Elektronen-Synchrotron DESY","ror":"https://ror.org/01js2sh04","country_code":"DE","type":"facility","lineage":["https://openalex.org/I1305996414","https://openalex.org/I2801876189"]},{"id":"https://openalex.org/I31512782","display_name":"Technische Universit\u00e4t Darmstadt","ror":"https://ror.org/05n911h24","country_code":"DE","type":"education","lineage":["https://openalex.org/I31512782"]},{"id":"https://openalex.org/I4210138560","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/03mstc592","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560"]},{"id":"https://openalex.org/I4210153543","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/050589e39","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Hans-Friedrich Nolting","raw_affiliation_strings":["Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany","institution_ids":["https://openalex.org/I22465464","https://openalex.org/I2801876189","https://openalex.org/I31512782","https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5023155028","display_name":"Bernt Krebs","orcid":"https://orcid.org/0000-0002-7412-3463","observed_orcids":["https://orcid.org/0000-0002-7412-3463"]},"institutions":[{"id":"https://openalex.org/I22465464","display_name":"University of M\u00fcnster","ror":"https://ror.org/00pd74e08","country_code":"DE","type":"education","lineage":["https://openalex.org/I22465464"]},{"id":"https://openalex.org/I2801876189","display_name":"Deutsches Elektronen-Synchrotron DESY","ror":"https://ror.org/01js2sh04","country_code":"DE","type":"facility","lineage":["https://openalex.org/I1305996414","https://openalex.org/I2801876189"]},{"id":"https://openalex.org/I31512782","display_name":"Technische Universit\u00e4t Darmstadt","ror":"https://ror.org/05n911h24","country_code":"DE","type":"education","lineage":["https://openalex.org/I31512782"]},{"id":"https://openalex.org/I4210138560","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/03mstc592","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560"]},{"id":"https://openalex.org/I4210153543","display_name":"European Molecular Biology Laboratory","ror":"https://ror.org/050589e39","country_code":"DE","type":"government","lineage":["https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Bernt Krebs","raw_affiliation_strings":["Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Anorganisch-Chemisches Institut der Universit\u00e4t M\u00fcnster, Wilhelm-Klemm-Strasse 8, 48149 M\u00fcnster, Germany, Institut f\u00fcr Physikalische Chemie der Technischen Hochschule Darmstadt, 64287 Darmstadt, Germany, and European Molecular Biology Laboratory, Hamburg Outstation c/o DESY, Notkestrasse 85, 22603 Hamburg, Germany","institution_ids":["https://openalex.org/I22465464","https://openalex.org/I2801876189","https://openalex.org/I31512782","https://openalex.org/I4210138560","https://openalex.org/I4210153543"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":5,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.3436,"has_fulltext":false,"cited_by_count":198,"citation_normalized_percentile":{"value":0.95154409,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":100},"biblio":{"volume":"35","issue":"11","first_page":"3409","last_page":"3419"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.003000000026077032,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11162","display_name":"Enzyme Structure and Function","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/catechol-oxidase","display_name":"catechol oxidase","score":0.9160000085830688},{"id":"https://openalex.org/keywords/dinuclear-copper-complex","display_name":"dinuclear copper complex","score":0.8159999847412109},{"id":"https://openalex.org/keywords/copper-active-sites","display_name":"copper active sites","score":0.578000009059906},{"id":"https://openalex.org/keywords/benzimidazole-ligands","display_name":"benzimidazole ligands","score":0.9190000295639038},{"id":"https://openalex.org/keywords/antiferromagnetic-coupling","display_name":"antiferromagnetic coupling","score":0.828000009059906},{"id":"https://openalex.org/keywords/exafs","display_name":"EXAFS","score":0.7990000247955322},{"id":"https://openalex.org/keywords/xanes","display_name":"XANES","score":0.984000027179718},{"id":"https://openalex.org/keywords/multiple-scattering-calculations","display_name":"multiple scattering calculations","score":0.6439999938011169},{"id":"https://openalex.org/keywords/solution-structure","display_name":"solution structure","score":0.42899999022483826},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6890000104904175},{"id":"https://openalex.org/keywords/magnetic-susceptibility","display_name":"magnetic susceptibility","score":0.5889999866485596},{"id":"https://openalex.org/keywords/uv-vis-titration","display_name":"UV-vis titration","score":0.6890000104904175},{"id":"https://openalex.org/keywords/copper-i-complexes","display_name":"copper(I) complexes","score":0.33399999141693115},{"id":"https://openalex.org/keywords/copper-i-copper-ii-redox","display_name":"copper(I)/copper(II) redox","score":0.5149999856948853}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9258546829223633},{"id":"https://openalex.org/C42228675","wikidata":"https://www.wikidata.org/wiki/Q376927","display_name":"Triclinic crystal system","level":3,"score":0.8412506580352783},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.7736877202987671},{"id":"https://openalex.org/C37243968","wikidata":"https://www.wikidata.org/wiki/Q648961","display_name":"Orthorhombic crystal system","level":3,"score":0.7353267669677734},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.6610526442527771},{"id":"https://openalex.org/C107861141","wikidata":"https://www.wikidata.org/wiki/Q908783","display_name":"Extended X-ray absorption fine structure","level":3,"score":0.47801005840301514},{"id":"https://openalex.org/C110715899","wikidata":"https://www.wikidata.org/wiki/Q3570341","display_name":"XANES","level":3,"score":0.45197200775146484},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.42657190561294556},{"id":"https://openalex.org/C62284982","wikidata":"https://www.wikidata.org/wiki/Q903103","display_name":"X-ray absorption spectroscopy","level":3,"score":0.4195174276828766},{"id":"https://openalex.org/C119824511","wikidata":"https://www.wikidata.org/wiki/Q13553575","display_name":"Absorption spectroscopy","level":2,"score":0.4138803482055664},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.35981085896492004},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.20143860578536987},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/ic9513604","doi":"https://doi.org/10.1021/ic9513604","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic9513604","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:11666546","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11666546","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:bib-pubdb1.desy.de:330292","doi":null,"is_oa":false,"landing_page_url":"https://bib-pubdb1.desy.de/record/330292","pdf_url":null,"source":{"id":"https://openalex.org/S4306401365","display_name":"Desy publication database (The Deutsches Elektronen-Synchrotron)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I2801876189","host_organization_name":"Deutsches Elektronen-Synchrotron DESY","host_organization_lineage":["https://openalex.org/I2801876189"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry 35(11), 3409 - 3419 (1996). doi:10.1021/ic9513604","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:tubiblio.ulb.tu-darmstadt.de:4368","doi":null,"is_oa":false,"landing_page_url":"http://tubiblio.ulb.tu-darmstadt.de/4368/","pdf_url":null,"source":{"id":"https://openalex.org/S4377196390","display_name":"TUbilio (Technical University of Darmstadt)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I31512782","host_organization_name":"Technische Universit\u00e4t Darmstadt","host_organization_lineage":["https://openalex.org/I31512782"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Artikel"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":39,"referenced_works":["https://openalex.org/W46942708","https://openalex.org/W1486881477","https://openalex.org/W1516910637","https://openalex.org/W1577234663","https://openalex.org/W1595269757","https://openalex.org/W1966440289","https://openalex.org/W1982295085","https://openalex.org/W1983909512","https://openalex.org/W1991677766","https://openalex.org/W1996613966","https://openalex.org/W2004962085","https://openalex.org/W2008176901","https://openalex.org/W2013535141","https://openalex.org/W2013862228","https://openalex.org/W2017305448","https://openalex.org/W2029365184","https://openalex.org/W2029675104","https://openalex.org/W2032334111","https://openalex.org/W2047665573","https://openalex.org/W2049024956","https://openalex.org/W2050076483","https://openalex.org/W2062122963","https://openalex.org/W2062151814","https://openalex.org/W2065612276","https://openalex.org/W2073262960","https://openalex.org/W2073938110","https://openalex.org/W2079658152","https://openalex.org/W2080251860","https://openalex.org/W2082490798","https://openalex.org/W2085119395","https://openalex.org/W2089154907","https://openalex.org/W2120104062","https://openalex.org/W2157147573","https://openalex.org/W2160707575","https://openalex.org/W2478789085","https://openalex.org/W2484864061","https://openalex.org/W3139411305","https://openalex.org/W3154467809","https://openalex.org/W4247183660"],"related_works":["https://openalex.org/W167285432","https://openalex.org/W1995963000","https://openalex.org/W7099895069","https://openalex.org/W2005598379","https://openalex.org/W1972254901","https://openalex.org/W1977925490","https://openalex.org/W2331731218","https://openalex.org/W2023809317","https://openalex.org/W1984455831","https://openalex.org/W2015553869"],"abstract_inverted_index":{"Two":[0],"novel":[1],"tridentate":[2],"dinucleating":[3],"ligands":[4,45],"containing":[5],"benzimidazole":[6],"were":[7,21,171],"prepared,":[8],"1,3-bis(2-benzimidazolyl)-2-propanol":[9],"(Hbbp,":[10],"1)":[11],"and":[12,28,35,91,126,140,169,177,231],"1,5-bis(2-benzimidazolyl)-3-pentanol":[13],"(Hbbpen,":[14],"2).":[15],"Their":[16],"complexing":[17],"properties":[18],"toward":[19],"copper":[20],"studied":[22,228],"in":[23,51,98,133,164,173,178,201,208],"order":[24,156],"to":[25,157,215,219,241],"obtain":[26],"structural":[27],"functional":[29],"models":[30],"for":[31],"catechol":[32],"oxidases.":[33],"Syntheses":[34],"crystal":[36],"structures":[37,160],"of":[38,152,161,182,239,247],"dinuclear":[39],"Cu(II)":[40,150,240],"complexes":[41,163,196],"derived":[42],"from":[43],"these":[44,183],"are":[46],"reported.":[47],"[Cu(2)bbp(2)](ClO(4))(2).2MeOH,":[48],"3,":[49],"crystallizes":[50,97],"the":[52,58,99,105,134,149,159,162,174,195,198,202,220,237,248],"triclinic":[53],"space":[54,101],"group":[55,102],"P&onemacr;":[56],"with":[57,104,190],"following":[59,106],"unit":[60,107],"cell":[61,108],"parameters:":[62,109],"a":[63,110,245],"=":[64,68,72,76,80,84,88,93,111,115,119,123,128],"7.702(3)":[65],"\u00c5,":[66,70,74,113,117,121],"b":[67,114],"10.973(6)":[69],"c":[71,118],"12.396(6)":[73],"alpha":[75],"100.59(4)":[77],"degrees,":[78,82,86],"beta":[79],"99.02(4)":[81],"gamma":[83],"98.90(4)":[85],"V":[87,122],"998.7(8)":[89],"\u00c5(3),":[90,125],"Z":[92,127],"1.":[94],"[Cu(2)bbpen(2)](ClO(4))(2).3MeOH,":[95],"4,":[96],"orthorhombic":[100],"Pccn,":[103],"17.478(9)":[112],"18.795(8)":[116],"13.888(6)":[120],"4562.2(4)":[124],"4.":[129],"Magnetic":[130],"susceptibility":[131],"measurements":[132,235],"temperature":[135],"ranges":[136],"4.6-459":[137],"K":[138,142],"(3)":[139],"4.6-425":[141],"(4)":[143],"indicate":[144],"an":[145],"antiferromagnetic":[146],"coupling":[147],"between":[148],"centers":[151],"both":[153],"complexes.":[154],"In":[155],"determine":[158],"solution,":[165],"XAS":[166,230],"spectra":[167],"(EXAFS":[168],"XANES)":[170],"recorded":[172],"solid":[175],"state":[176,204],"solution.":[179,210],"The":[180],"interpretation":[181],"data,":[184],"including":[185],"multiple":[186],"scattering":[187],"calculations,":[188],"together":[189],"UV-vis":[191,232],"titrations,":[192],"shows":[193],"that":[194],"have":[197],"same":[199],"structure":[200],"crystalline":[203],"as":[205,207],"well":[206],"methanolic":[209],"Complex":[211],"4":[212],"is":[213],"able":[214],"oxidize":[216],"3,5-di-tert-butylcatechol":[217],"(3,5-DTBC)":[218],"quinone":[221],"(catecholase":[222],"activity).":[223],"This":[224],"reaction":[225],"was":[226],"also":[227],"by":[229,244],"spectroscopy.":[233],"These":[234],"reveal":[236],"reduction":[238],"Cu(I)":[242],"accompanied":[243],"decrease":[246],"coordination":[249],"number.":[250]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":5},{"year":2022,"cited_by_count":10},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":8},{"year":2019,"cited_by_count":7},{"year":2018,"cited_by_count":8},{"year":2017,"cited_by_count":10},{"year":2016,"cited_by_count":14},{"year":2015,"cited_by_count":7},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":11}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}