{"id":"https://openalex.org/W1998413847","doi":"https://doi.org/10.1021/ic971517n","title":"Laser Flash Photolysis Studies of Nitritomanganese(III) Tetraphenylporphyrin. Reactions of O2, NO, and Pyridine with Manganese(II) Tetraphenylporphyrin","display_name":"Laser Flash Photolysis Studies of Nitritomanganese(III) Tetraphenylporphyrin. Reactions of O2, NO, and Pyridine with Manganese(II) Tetraphenylporphyrin","publication_year":1998,"publication_date":"1998-04-30","ids":{"openalex":"https://openalex.org/W1998413847","doi":"https://doi.org/10.1021/ic971517n","mag":"1998413847"},"language":"en","primary_location":{"id":"doi:10.1021/ic971517n","doi":"https://doi.org/10.1021/ic971517n","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic971517n","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5017610382","display_name":"Mikio Hoshino","orcid":"https://orcid.org/0000-0002-9526-3473","observed_orcids":["https://orcid.org/0000-0002-9526-3473"]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]},{"id":"https://openalex.org/I4210110652","display_name":"RIKEN","ror":"https://ror.org/01sjwvz98","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4210110652"]}],"countries":["JP","US"],"is_corresponding":true,"raw_author_name":"Mikio Hoshino","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106","The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]},{"raw_affiliation_string":"The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan","institution_ids":["https://openalex.org/I4210110652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103423146","display_name":"Yutaka Nagashima","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]},{"id":"https://openalex.org/I4210110652","display_name":"RIKEN","ror":"https://ror.org/01sjwvz98","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4210110652"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Yutaka Nagashima","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106","The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]},{"raw_affiliation_string":"The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan","institution_ids":["https://openalex.org/I4210110652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110334536","display_name":"Hiroshi Seki","orcid":"https://orcid.org/0000-0002-1769-2627","observed_orcids":["https://orcid.org/0000-0002-1769-2627"]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]},{"id":"https://openalex.org/I4210110652","display_name":"RIKEN","ror":"https://ror.org/01sjwvz98","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4210110652"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Hiroshi Seki","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106","The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]},{"raw_affiliation_string":"The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan","institution_ids":["https://openalex.org/I4210110652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082374088","display_name":"Malcolm A. De Leo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]},{"id":"https://openalex.org/I4210110652","display_name":"RIKEN","ror":"https://ror.org/01sjwvz98","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4210110652"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Malcolm De Leo","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106","The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]},{"raw_affiliation_string":"The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan","institution_ids":["https://openalex.org/I4210110652"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5057717570","display_name":"Peter C. Ford","orcid":"https://orcid.org/0000-0002-5509-9912","observed_orcids":["https://orcid.org/0000-0002-5509-9912"]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]},{"id":"https://openalex.org/I4210110652","display_name":"RIKEN","ror":"https://ror.org/01sjwvz98","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4210110652"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Peter C. Ford","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106","The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]},{"raw_affiliation_string":"The Institute of Physical and Chemical Research, Wako, Saitama 351-01, Japan","institution_ids":["https://openalex.org/I4210110652"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5017610382"],"corresponding_institution_ids":["https://openalex.org/I154570441","https://openalex.org/I4210110652"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.3514,"has_fulltext":false,"cited_by_count":35,"citation_normalized_percentile":{"value":0.8742437,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"37","issue":"10","first_page":"2464","last_page":"2469"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.007400000002235174,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10957","display_name":"Photodynamic Therapy Research Studies","score":0.0052999998442828655,"subfield":{"id":"https://openalex.org/subfields/1306","display_name":"Cancer Research"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dioxygen-adducts","display_name":"dioxygen adducts","score":0.8209999799728394},{"id":"https://openalex.org/keywords/nitric-oxide-addition","display_name":"nitric oxide addition","score":0.6980000138282776},{"id":"https://openalex.org/keywords/pyridine-addition","display_name":"pyridine addition","score":0.8460000157356262},{"id":"https://openalex.org/keywords/association-kinetics","display_name":"association kinetics","score":0.49799999594688416},{"id":"https://openalex.org/keywords/recombination-kinetics","display_name":"recombination kinetics","score":0.5740000009536743},{"id":"https://openalex.org/keywords/quantum-yield","display_name":"quantum yield","score":0.7369999885559082},{"id":"https://openalex.org/keywords/metalloporphyrins","display_name":"metalloporphyrins","score":0.9290000200271606}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9582473039627075},{"id":"https://openalex.org/C2778401137","wikidata":"https://www.wikidata.org/wiki/Q3985292","display_name":"Tetraphenylporphyrin","level":3,"score":0.9234137535095215},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.7860614061355591},{"id":"https://openalex.org/C13472781","wikidata":"https://www.wikidata.org/wiki/Q5457567","display_name":"Flash photolysis","level":4,"score":0.768841028213501},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.7384823560714722},{"id":"https://openalex.org/C171001562","wikidata":"https://www.wikidata.org/wiki/Q2856048","display_name":"Quantum yield","level":3,"score":0.7109782099723816},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6527153849601746},{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.6409067511558533},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.5438923835754395},{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.503107488155365},{"id":"https://openalex.org/C10710636","wikidata":"https://www.wikidata.org/wiki/Q857809","display_name":"Equilibrium constant","level":2,"score":0.48809826374053955},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.46868517994880676},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.45799002051353455},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4307924211025238},{"id":"https://openalex.org/C2779480358","wikidata":"https://www.wikidata.org/wiki/Q422926","display_name":"Porphyrin","level":2,"score":0.2410564124584198},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.23451602458953857},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.21934959292411804},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.17738476395606995},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0995950698852539},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.08820381760597229},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ic971517n","doi":"https://doi.org/10.1021/ic971517n","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic971517n","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":38,"referenced_works":["https://openalex.org/W260213315","https://openalex.org/W1533259206","https://openalex.org/W1966285171","https://openalex.org/W1970895529","https://openalex.org/W1972536511","https://openalex.org/W1975084486","https://openalex.org/W1981539151","https://openalex.org/W1989857545","https://openalex.org/W1990948583","https://openalex.org/W1994031154","https://openalex.org/W1999667625","https://openalex.org/W2000820246","https://openalex.org/W2020739743","https://openalex.org/W2026922316","https://openalex.org/W2046815937","https://openalex.org/W2047374212","https://openalex.org/W2051095660","https://openalex.org/W2052238937","https://openalex.org/W2053854423","https://openalex.org/W2054859046","https://openalex.org/W2057775581","https://openalex.org/W2058167301","https://openalex.org/W2071427630","https://openalex.org/W2071965775","https://openalex.org/W2072255186","https://openalex.org/W2073356400","https://openalex.org/W2074595405","https://openalex.org/W2074827335","https://openalex.org/W2075640085","https://openalex.org/W2081639194","https://openalex.org/W2084033107","https://openalex.org/W2087097168","https://openalex.org/W2137408606","https://openalex.org/W2951713955","https://openalex.org/W2952740967","https://openalex.org/W2992066550","https://openalex.org/W3195002527","https://openalex.org/W4298424044"],"related_works":["https://openalex.org/W2025283388","https://openalex.org/W1979931746","https://openalex.org/W2072606154","https://openalex.org/W2125319353","https://openalex.org/W2491041800","https://openalex.org/W1980484586","https://openalex.org/W2078494563","https://openalex.org/W1996929487","https://openalex.org/W2032906955","https://openalex.org/W2073613267"],"abstract_inverted_index":{"Laser":[0],"photolysis":[1,58,85],"of":[2,34,69,86,123,177,244,287,305],"nitritomanganese(III)":[3],"tetraphenylporphyrin,":[4,16],"Mn":[5,17,35,79,87,124,140,229,237,256,266,288],"III":[6,88],"TPP(ONO)":[7,89],"(":[8,20,155],"1":[9,70,93,113,116,192,195,227,251,254,279,282],"),":[10,22,171,218],"in":[11,135,301],"degassed":[12],"toluene":[13],"gives":[14],"manganese(II)":[15],"II":[18,36,80,125,141,230,238,257,267,289],"TPP":[19,37,81,126,142,231,258,290],"2":[21,25,98,153,164,170,212,217,224,298],"plus":[23],"NO":[24,97,261,297],".":[26,117,228,255,283],"The":[27,118,158,284],"quantum":[28,63],"yield,":[29],"\u03a6,":[30],"for":[31,65,120,172],"the":[32,41,62,66,121,149,173,206,270],"formation":[33,174],"is":[38,71,219],"dependent":[39],"on":[40],"excitation":[42],"wavelength:":[43],"\u03a6":[44,51],"=":[45,52],"0.045":[46],"at":[47,54,179],"355":[48],"nm":[49],"and":[50,131,166,175,196,205,296],"0.0064":[53],"532":[55],"nm.":[56],"Continuous":[57],"studies":[59],"reveal":[60],"that":[61],"yield":[64,148,263],"net":[67],"photodecomposition":[68],"much":[72],"smaller":[73],"(10":[74],"-":[75,112,115,191,194,202,226,250,253,278,281],"4":[76,200],").":[77,157],"Thus,":[78],"produced":[82],"by":[83,94],"laser":[84],"mostly":[90],"returns":[91],"to":[92,100,147,184,235,262],"recombination":[95],"with":[96,103,127,145,233,240,260,269,291,303],"according":[99],"second-order":[101],"kinetics":[102,119],"a":[104,241],"rate":[105,159,242,271],"constant":[106,243,272],"2.2":[107],"\u00d7":[108,187,198,222,246,274],"10":[109,188,199,223,247,275],"9":[110],"M":[111,190,225,249,277],"s":[114,193,201,252,280],"reactions":[122,286],"O":[128,294],"2,":[129,295],"NO,":[130,292],"pyridine":[132,234],"were":[133,182],"investigated":[134],"detail.":[136],"In":[137],"aerated":[138],"toluene,":[139],"reversibly":[143],"reacts":[144,232,259],"oxygen":[146],"dioxygen":[150],"adduct,":[151],"MnTPP(O":[152],")":[154,165],"3":[156,178],"constants,":[160],"k":[161,167,209,214],"f":[162,210],"(O":[163,169,211,216],"b":[168,215],"dissociation":[176],"300":[180],"K":[181],"determined":[183],"be":[185],"1.93":[186],"7":[189],"9.0":[197],"1,":[203],"respectively,":[204],"equilibrium":[207],"constant,":[208],")/":[213],"therefore":[220],"2.1":[221],"give":[236],"TPP(Py)":[239],"9.5":[245],"8":[248,276],"nitrosylmanganese":[264],"porphyrin,":[265],"TPP(NO),":[268],"5.3":[273],"association":[285],"pyridine,":[293],"are":[299],"discussed":[300],"comparison":[302],"those":[304],"other":[306],"metalloporphyrins.":[307]},"counts_by_year":[{"year":2025,"cited_by_count":3},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-09-25T08:18:29.962427","created_date":"2016-06-24T00:00:00"}