{"id":"https://openalex.org/W1998349130","doi":"https://doi.org/10.1021/ja9716463","title":"Transition Metal Coordinated Al(X)L 2 and Ga(X)L 2 Fragments","display_name":"Transition Metal Coordinated Al(X)L 2 and Ga(X)L 2 Fragments","publication_year":1998,"publication_date":"1998-02-01","ids":{"openalex":"https://openalex.org/W1998349130","doi":"https://doi.org/10.1021/ja9716463","mag":"1998349130"},"language":"en","primary_location":{"id":"doi:10.1021/ja9716463","doi":"https://doi.org/10.1021/ja9716463","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja9716463","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5037112345","display_name":"Roland A. Fischer","orcid":"https://orcid.org/0000-0002-7532-5286","observed_orcids":["https://orcid.org/0000-0002-7532-5286"]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Roland A. Fischer","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103414700","display_name":"Markus M. Schulte","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Markus M. Schulte","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103543732","display_name":"Jurij Wei\u00df","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Jurij Weiss","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5031782154","display_name":"L\u00e1szl\u00f3 Zsolnai","orcid":"https://orcid.org/0000-0002-0213-7778","observed_orcids":["https://orcid.org/0000-0002-0213-7778"]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Laszlo Zsolnai","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037663207","display_name":"Albrecht Jacobi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Albrecht Jacobi","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070157134","display_name":"Gottfried H\u00fcttner","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Gottfried Huttner","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033413160","display_name":"Gernot Frenking","orcid":"https://orcid.org/0000-0003-1689-1197","observed_orcids":["https://orcid.org/0000-0003-1689-1197"]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Gernot Frenking","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023078855","display_name":"Christian Boehme","orcid":"https://orcid.org/0000-0002-4289-0465","observed_orcids":["https://orcid.org/0000-0002-4289-0465"]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Christian Boehme","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5070490233","display_name":"Sergei F. Vyboishchikov","orcid":"https://orcid.org/0000-0003-1338-3437","observed_orcids":["https://orcid.org/0000-0003-1338-3437"]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]},{"id":"https://openalex.org/I223822909","display_name":"Heidelberg University","ror":"https://ror.org/038t36y30","country_code":"DE","type":"education","lineage":["https://openalex.org/I223822909"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Sergei F. Vyboishchikov","raw_affiliation_strings":["Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Ruprecht-Karls-Universti\u00e4t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany, and Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany","institution_ids":["https://openalex.org/I161103922","https://openalex.org/I223822909"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":6.5625,"has_fulltext":false,"cited_by_count":123,"citation_normalized_percentile":{"value":0.97955916,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"120","issue":"6","first_page":"1237","last_page":"1248"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.8744999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.8744999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.0608999989926815,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.02879999950528145,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/transition-metal-carbonyl-complexes","display_name":"transition metal carbonyl complexes","score":0.7670000195503235},{"id":"https://openalex.org/keywords/salt-elimination","display_name":"salt elimination","score":0.5249999761581421},{"id":"https://openalex.org/keywords/tmeda","display_name":"TMEDA","score":0.6690000295639038},{"id":"https://openalex.org/keywords/dme","display_name":"DME","score":0.5989999771118164},{"id":"https://openalex.org/keywords/hydride-complexes","display_name":"hydride complexes","score":0.6370000243186951},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5220000147819519}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9149523973464966},{"id":"https://openalex.org/C61276311","wikidata":"https://www.wikidata.org/wiki/Q624543","display_name":"Monoclinic crystal system","level":3,"score":0.816266655921936},{"id":"https://openalex.org/C2780400988","wikidata":"https://www.wikidata.org/wiki/Q421748","display_name":"Dichloromethane","level":3,"score":0.6438390016555786},{"id":"https://openalex.org/C27501479","wikidata":"https://www.wikidata.org/wiki/Q428069","display_name":"Intermetallic","level":3,"score":0.5925754308700562},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5524777173995972},{"id":"https://openalex.org/C106773901","wikidata":"https://www.wikidata.org/wiki/Q19588","display_name":"Transition metal","level":3,"score":0.5370762348175049},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.522944986820221},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.5195006132125854},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.5182092785835266},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.5045114755630493},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4851682782173157},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.460714191198349},{"id":"https://openalex.org/C50515024","wikidata":"https://www.wikidata.org/wiki/Q826582","display_name":"X-ray crystallography","level":3,"score":0.4362563490867615},{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.42872992157936096},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.4107969105243683},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3581017851829529},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.1630708873271942},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.12596675753593445},{"id":"https://openalex.org/C207114421","wikidata":"https://www.wikidata.org/wiki/Q133900","display_name":"Diffraction","level":2,"score":0.1215396523475647},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10788565874099731},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C2780026712","wikidata":"https://www.wikidata.org/wiki/Q37756","display_name":"Alloy","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja9716463","doi":"https://doi.org/10.1021/ja9716463","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja9716463","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":58,"referenced_works":["https://openalex.org/W1496067501","https://openalex.org/W1969763382","https://openalex.org/W1970356673","https://openalex.org/W1981447362","https://openalex.org/W1985002544","https://openalex.org/W1985133664","https://openalex.org/W1992077520","https://openalex.org/W1995439572","https://openalex.org/W1998108769","https://openalex.org/W1999142883","https://openalex.org/W1999602299","https://openalex.org/W2002692436","https://openalex.org/W2008237841","https://openalex.org/W2009629380","https://openalex.org/W2016418604","https://openalex.org/W2018588247","https://openalex.org/W2021238902","https://openalex.org/W2023246165","https://openalex.org/W2023468663","https://openalex.org/W2023552536","https://openalex.org/W2024842922","https://openalex.org/W2025984865","https://openalex.org/W2031312607","https://openalex.org/W2032627250","https://openalex.org/W2043327592","https://openalex.org/W2044940178","https://openalex.org/W2045597839","https://openalex.org/W2050781823","https://openalex.org/W2053617442","https://openalex.org/W2054149576","https://openalex.org/W2055089192","https://openalex.org/W2069148985","https://openalex.org/W2070739820","https://openalex.org/W2074216327","https://openalex.org/W2075662351","https://openalex.org/W2077120194","https://openalex.org/W2080377884","https://openalex.org/W2080539095","https://openalex.org/W2085980720","https://openalex.org/W2087594971","https://openalex.org/W2092310236","https://openalex.org/W2094642658","https://openalex.org/W2108691746","https://openalex.org/W2126301969","https://openalex.org/W2146055388","https://openalex.org/W2147303166","https://openalex.org/W2150637521","https://openalex.org/W2154555670","https://openalex.org/W2912800609","https://openalex.org/W2949178550","https://openalex.org/W2950179917","https://openalex.org/W2952967852","https://openalex.org/W3004675267","https://openalex.org/W3137755515","https://openalex.org/W3138745558","https://openalex.org/W4255798156","https://openalex.org/W4285719527","https://openalex.org/W4388166534"],"related_works":["https://openalex.org/W1986746612","https://openalex.org/W1990888235","https://openalex.org/W2090931395","https://openalex.org/W2042779489","https://openalex.org/W2334728045","https://openalex.org/W2065819334","https://openalex.org/W2053285687","https://openalex.org/W1562157048","https://openalex.org/W2160634841","https://openalex.org/W2001612875"],"abstract_inverted_index":{"Carbonylmetalate":[0],"dianions":[1],"react":[2],"in":[3,275,351],"thf":[4,133],"with":[5,71,89,438,450],"the":[6,34,58,91,101,177,194,218,276,352,389,395,464],"group":[7,279,355],"13":[8],"chlorides":[9],"X":[10,21,120,152],"m":[11,15,28,40,44],"ECl":[12],"3":[13,401,416],"-":[14,43,46],"(":[16,136,163,247,253,260,313,343,378,405,454,470],"E":[17,406],"=":[18,22,29,48,54,111,117,121,127,148,153,160,201,286,290,294,298,302,305,311,316,320,324,328,332,335,341,346,358,362,366,370,376,381,407,474],"Al,":[19,409],"Ga;":[20],"Cl,":[23,122,154],"Me,":[24,123,202],"Et,":[25,155],"i":[26,156],"Bu;":[27,157],"0,":[30],"1)":[31],"to":[32,176],"yield":[33],"monoanionic":[35],"species":[36,182],"[(CO)":[37],"n":[38,53,106,116],"M\u2212EX":[39],"Cl":[41],"2":[42,108,126,134,145,159,198,204,248,271,281,403,418,433],"]":[45,109,146,404],"(M":[47,110,147],"Fe,":[49],"Cr,":[50,112,149],"Mo,":[51,113,150],"W;":[52,151],"4,":[55,118],"5)":[56],"as":[57,65,206,435],"primary":[59,92],"products":[60,93],"which":[61,183],"could":[62],"be":[63,174],"isolated":[64],"solvent":[66,87],"free":[67],"salts":[68],"after":[69],"exchange":[70,88,211],"a":[72,79,95,209,289,319,357],"non":[73],"coordinating":[74],"cation.":[75],"After":[76],"addition":[77],"of":[78,196,232,392,394],"chelating":[80],"Lewis":[81],"base,":[82],"e.g.,":[83],"tmeda,":[84,128,161],"dme,":[85,129],"and":[86,141,190,235,239,256,272,309,339,374,423,460],"dichloromethane":[90],"undergo":[94],"second":[96,219],"salt":[97,220],"elimination":[98,221],"reaction,":[99,212],"yielding":[100],"neutral":[102],"intermetallic":[103,226],"systems":[104,227],"(CO)":[105,142,244,250,257,398,413,420,424],"M\u2212Ga[X(L)":[107],"W,":[114],"Fe;":[115],"5;":[119],"Et;":[124,203],"L":[125,158],"bipy,":[130],"t":[131],"Bu-dab,":[132],")":[135,140,262,402,417],"1":[137,282],"\u2212":[138,165],"14":[139],"5":[143,245,251,258,399,414,421,425],"M-Al[X(L)":[144],"tmpda)":[162],"15":[164],"20,":[166],"23,":[167],"24":[168],").":[169],"The":[170,224,242,429,442],"chloro":[171],"derivatives":[172],"can":[173],"converted":[175],"corresponding":[178],"hydrido":[179],"or":[180],"tetrahydridoboranato":[181],"is":[184,467],"exemplarily":[185],"shown":[186],"by":[187,230,266],"compounds":[188,208],"21":[189],"22":[191],".":[192],"In":[193],"case":[195],"R":[197,310,314,340,344,375,379],"GaCl":[199],"(R":[200],"equiv)":[205],"starting":[207],"ligand":[210],"generating":[213],"GaR":[214],"3,":[215,308,338,373],"occurs,":[216],"before":[217],"takes":[222],"place.":[223],"new":[225],"were":[228],"characterized":[229,265],"means":[231],"elemental":[233],"analysis":[234],"IR,":[236],"Raman,":[237],"NMR,":[238],"mass":[240],"spectroscopy.":[241],"complexes":[243,397],"Cr\u2212Ga[Cl(tmeda)]":[246],"),":[249,255],"W\u2212Al[Et(tmeda)]":[252],"20":[254,273],"W\u2212Al[Cl(tmpda)]":[259],"23":[261,349],"are":[263,427,445],"also":[264],"single-crystal":[267],"X-ray":[268],"diffraction.":[269],"Compounds":[270],"crystallize":[274],"monoclinic":[277],"space":[278,354],"P":[280],"/":[283],"n,":[284],"Z":[285],"4.":[287],"2:":[288],"9.059(4)":[291],"\u00c5,":[292,296,300,322,326,330,360,364,368],"b":[293,323,361],"16.084(7)":[295],"c":[297,327,365],"11.835(6)":[299],"\u03b2":[301,331],"80.6(1)\u00b0,":[303],"V":[304,334,369],"1701(1)":[306],"\u00c5":[307,337,372],"0.037":[312],"w":[315,345,380],"0.118).":[317],"20:":[318],"8.606(2)":[321],"16.463(6)":[325],"12.469(4)":[329],"93.88(2)\u00b0,":[333],"1762(6)":[336],"0.027":[342],"0.065).":[347],"Complex":[348],"crystallizes":[350],"orthorhombic":[353],"Pccn,":[356],"23.990(6)":[359],"9.044(3)":[363],"15.871(4)":[367],"3445(1)":[371],"0.044":[377],"0.088).":[382],"Ab":[383],"initio":[384],"quantum":[385],"chemical":[386],"calculations":[387],"at":[388],"MP2":[390],"level":[391],"theory":[393],"model":[396],"W\u2212E[Cl(NH":[400],"B,":[408],"Ga,":[410],"In,":[411],"Tl),":[412],"W\u2212Al[H(NH":[415],"],":[419],"W\u2212AlH,":[422],"W\u2212AlCl":[426],"reported.":[428],"group-13":[430],"fragments":[431],"E(R)L":[432],"behave":[434],"strong":[436,446],"\u03c3-donors":[437],"significant":[439],"acceptor":[440],"capabilities.":[441],"W\u2212E":[443],"bonds":[444,449],"semipolar":[447],"covalent":[448],"large":[451],"ionic":[452],"contributions":[453],"D":[455,471],"e":[456,472],"(calc)":[457,473],"between":[458],"70":[459],"120":[461],"kcal/mol).":[462,476],"Only":[463],"W\u2212Tl":[465],"bond":[466],"comparatively":[468],"weak":[469],"48":[475]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":6},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":6},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":7},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":8}],"updated_date":"2026-10-02T10:15:12.560889","created_date":"2016-06-24T00:00:00"}