{"id":"https://openalex.org/W1998322955","doi":"https://doi.org/10.1039/a907145h","title":"Synthesis of ruthenium complexes with planar-chiral cyclopentadienyl-pyridine or -phosphine bidentate ligands","display_name":"Synthesis of ruthenium complexes with planar-chiral cyclopentadienyl-pyridine or -phosphine bidentate ligands","publication_year":2000,"publication_date":"2000-01-01","ids":{"openalex":"https://openalex.org/W1998322955","doi":"https://doi.org/10.1039/a907145h","mag":"1998322955"},"language":"en","primary_location":{"id":"doi:10.1039/a907145h","doi":"https://doi.org/10.1039/a907145h","is_oa":false,"landing_page_url":"https://doi.org/10.1039/a907145h","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5050428088","display_name":"Noriko Dodo","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4405287424","display_name":"The Institute of Scientific and Industrial Research, The University of Osaka","ror":"https://ror.org/053t3hh85","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405287424","https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Noriko Dodo","raw_affiliation_strings":["The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan","institution_ids":["https://openalex.org/I4405287424"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5034917955","display_name":"Yuji Matsushima","orcid":"https://orcid.org/0000-0003-1784-6101","observed_orcids":["https://orcid.org/0000-0003-1784-6101"]},"institutions":[{"id":"https://openalex.org/I4405287424","display_name":"The Institute of Scientific and Industrial Research, The University of Osaka","ror":"https://ror.org/053t3hh85","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405287424","https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yuji Matsushima","raw_affiliation_strings":["The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan","institution_ids":["https://openalex.org/I4405287424"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111572263","display_name":"Mitsunari Uno","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4405287424","display_name":"The Institute of Scientific and Industrial Research, The University of Osaka","ror":"https://ror.org/053t3hh85","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405287424","https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Mitsunari Uno","raw_affiliation_strings":["The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan","institution_ids":["https://openalex.org/I4405287424"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112316358","display_name":"Kiyotaka Onitsuka","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4405287424","display_name":"The Institute of Scientific and Industrial Research, The University of Osaka","ror":"https://ror.org/053t3hh85","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405287424","https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kiyotaka Onitsuka","raw_affiliation_strings":["The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan","institution_ids":["https://openalex.org/I4405287424"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5102076689","display_name":"Shigetoshi Takahashi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4405287424","display_name":"The Institute of Scientific and Industrial Research, The University of Osaka","ror":"https://ror.org/053t3hh85","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405287424","https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Shigetoshi Takahashi","raw_affiliation_strings":["The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8-1, Ibaraki, Osaka, Japan","institution_ids":["https://openalex.org/I4405287424"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5102076689"],"corresponding_institution_ids":["https://openalex.org/I4405287424"],"apc_list":null,"apc_paid":null,"fwci":1.9494,"has_fulltext":false,"cited_by_count":42,"citation_normalized_percentile":{"value":0.82905596,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":null,"issue":"1","first_page":"35","last_page":"41"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.6973000168800354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.6973000168800354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.22460000216960907,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.0414000004529953,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ruthenium-complexes","display_name":"ruthenium complexes","score":0.9879999756813049},{"id":"https://openalex.org/keywords/planar-chirality","display_name":"planar chirality","score":0.9760000109672546},{"id":"https://openalex.org/keywords/cyclopentadienyl-ligands","display_name":"cyclopentadienyl ligands","score":0.9380000233650208},{"id":"https://openalex.org/keywords/pyridine-ligands","display_name":"pyridine ligands","score":0.8579999804496765},{"id":"https://openalex.org/keywords/phosphine-ligands","display_name":"phosphine ligands","score":0.9869999885559082},{"id":"https://openalex.org/keywords/bidentate-ligands","display_name":"bidentate ligands","score":0.9639999866485596},{"id":"https://openalex.org/keywords/enantiomerically-pure-complexes","display_name":"enantiomerically pure complexes","score":0.6809999942779541},{"id":"https://openalex.org/keywords/dithiocarbamate-complexes","display_name":"dithiocarbamate complexes","score":0.8309999704360962},{"id":"https://openalex.org/keywords/coordination-chemistry","display_name":"coordination chemistry","score":0.6340000033378601},{"id":"https://openalex.org/keywords/x-ray-crystal-structure","display_name":"X-ray crystal structure","score":0.7480000257492065}],"concepts":[{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.9544230699539185},{"id":"https://openalex.org/C181458950","wikidata":"https://www.wikidata.org/wiki/Q2855060","display_name":"Cyclopentadienyl complex","level":3,"score":0.9271961450576782},{"id":"https://openalex.org/C2777716191","wikidata":"https://www.wikidata.org/wiki/Q207877","display_name":"Phosphine","level":3,"score":0.8317136764526367},{"id":"https://openalex.org/C178516000","wikidata":"https://www.wikidata.org/wiki/Q3023362","display_name":"Denticity","level":3,"score":0.8153455257415771},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.7287341356277466},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7193202972412109},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6026963591575623},{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.5446398258209229},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4950472414493561},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.31687092781066895},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.23069864511489868},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.18602946400642395},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1741713285446167},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.06748819351196289},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/a907145h","doi":"https://doi.org/10.1039/a907145h","is_oa":false,"landing_page_url":"https://doi.org/10.1039/a907145h","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":30,"referenced_works":["https://openalex.org/W1968268583","https://openalex.org/W1991594375","https://openalex.org/W1993095008","https://openalex.org/W1996853488","https://openalex.org/W2003774748","https://openalex.org/W2007586682","https://openalex.org/W2009419341","https://openalex.org/W2021575825","https://openalex.org/W2023118767","https://openalex.org/W2024666848","https://openalex.org/W2039701983","https://openalex.org/W2043156483","https://openalex.org/W2059747135","https://openalex.org/W2065455233","https://openalex.org/W2069683629","https://openalex.org/W2072932137","https://openalex.org/W2078202855","https://openalex.org/W2086523116","https://openalex.org/W2115548957","https://openalex.org/W2153900045","https://openalex.org/W2168923778","https://openalex.org/W2170979955","https://openalex.org/W2949277805","https://openalex.org/W2951854039","https://openalex.org/W2951921505","https://openalex.org/W2952604547","https://openalex.org/W2952684344","https://openalex.org/W2952845563","https://openalex.org/W2953187717","https://openalex.org/W3023224761"],"related_works":["https://openalex.org/W2951551620","https://openalex.org/W2047722066","https://openalex.org/W2053945937","https://openalex.org/W6993034142","https://openalex.org/W2065836434","https://openalex.org/W2044831737","https://openalex.org/W2007828521","https://openalex.org/W2011200038","https://openalex.org/W1977953338","https://openalex.org/W2005421046"],"abstract_inverted_index":{"Novel":[0],"ruthenium":[1,42,55,74,86],"complexes":[2,65,75],"possessing":[3],"planar-chiral":[4,63],"cyclopentadienyl-pyridine":[5],"or":[6],"-phosphine":[7],"bidentate":[8,92],"ligands":[9],"have":[10,66],"been":[11,67,95],"synthesized":[12],"from":[13,39],"(trisubstituted":[14],"cyclopentadienyl)(benzene)ruthenium":[15],"complexes.":[16],"Co-ordination":[17],"of":[18,62,71,83],"the":[19,36,40,48,54,90],"pyridyl":[20],"group":[21],"linked":[22],"to":[23,53],"a":[24,77,84],"cyclopentadienyl":[25],"ring":[26],"through":[27],"an":[28],"ester":[29],"bond":[30],"is":[31],"fairly":[32],"weak,":[33],"so":[34],"that":[35],"pyridine":[37],"dissociates":[38],"central":[41],"atom":[43],"in":[44,57],"acetonitrile.":[45,58],"In":[46],"contrast,":[47],"phosphine":[49],"ligand":[50,93],"tightly":[51],"co-ordinates":[52],"even":[56],"Enantiomerically":[59],"pure":[60,73],"samples":[61],"cyclopentadienylphosphine":[64,91],"prepared":[68],"by":[69,97],"use":[70],"optically":[72],"as":[76],"starting":[78],"material.":[79],"The":[80],"molecular":[81],"structure":[82],"neutral":[85],"dithiocarbamate":[87],"complex":[88],"with":[89],"has":[94],"determined":[96],"X-ray":[98],"crystallography.":[99]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":4},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}