{"id":"https://openalex.org/W1997453635","doi":"https://doi.org/10.1021/ol051559c","title":"Enantioselective Rh-Catalyzed Hydrogenation of Enol Acetates and Enol Carbamates with Monodentate Phosphoramidites","display_name":"Enantioselective Rh-Catalyzed Hydrogenation of Enol Acetates and Enol Carbamates with Monodentate Phosphoramidites","publication_year":2005,"publication_date":"2005-08-17","ids":{"openalex":"https://openalex.org/W1997453635","doi":"https://doi.org/10.1021/ol051559c","mag":"1997453635","pmid":"https://pubmed.ncbi.nlm.nih.gov/16146381"},"language":"en","primary_location":{"id":"doi:10.1021/ol051559c","doi":"https://doi.org/10.1021/ol051559c","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ol051559c","pdf_url":null,"source":{"id":"https://openalex.org/S201989124","display_name":"Organic Letters","issn_l":"1523-7052","issn":["1523-7052","1523-7060"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5008675070","display_name":"Lavinia Panella","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Lavinia Panella","raw_affiliation_strings":["Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands","institution_ids":["https://openalex.org/I169381384"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087713906","display_name":"Ben L. Feringa","orcid":"https://orcid.org/0000-0003-0588-8435","observed_orcids":["https://orcid.org/0000-0003-0588-8435"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Ben L. Feringa","raw_affiliation_strings":["Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands","institution_ids":["https://openalex.org/I169381384"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070751842","display_name":"Johannes G. de Vries","orcid":"https://orcid.org/0000-0001-5245-7748","observed_orcids":["https://orcid.org/0000-0001-5245-7748"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Johannes G. de Vries","raw_affiliation_strings":["Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands","institution_ids":["https://openalex.org/I169381384"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5051792983","display_name":"Adriaan J. Minnaard","orcid":"https://orcid.org/0000-0002-5966-1300","observed_orcids":["https://orcid.org/0000-0002-5966-1300"]},"institutions":[{"id":"https://openalex.org/I169381384","display_name":"University of Groningen","ror":"https://ror.org/012p63287","country_code":"NL","type":"education","lineage":["https://openalex.org/I169381384"]}],"countries":["NL"],"is_corresponding":false,"raw_author_name":"Adriaan J. Minnaard","raw_affiliation_strings":["Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands, and DSM Research, Life Sciences-Advanced Synthesis, Catalysis & Development, P.O. Box 18, 6160 MD Geleen, The Netherlands","institution_ids":["https://openalex.org/I169381384"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I169381384"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.3471,"has_fulltext":false,"cited_by_count":81,"citation_normalized_percentile":{"value":0.96314339,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"7","issue":"19","first_page":"4177","last_page":"4180"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/asymmetric-hydrogenation","display_name":"asymmetric hydrogenation","score":0.9160000085830688},{"id":"https://openalex.org/keywords/rhodium-catalysis","display_name":"rhodium catalysis","score":0.9900000095367432},{"id":"https://openalex.org/keywords/enol-acetates","display_name":"enol acetates","score":0.8709999918937683},{"id":"https://openalex.org/keywords/allyl-alcohol","display_name":"allyl alcohol","score":0.6190000176429749},{"id":"https://openalex.org/keywords/chiral-ligands","display_name":"chiral ligands","score":0.6729999780654907}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9432017803192139},{"id":"https://openalex.org/C2777495281","wikidata":"https://www.wikidata.org/wiki/Q408053","display_name":"Enol","level":3,"score":0.9199336171150208},{"id":"https://openalex.org/C178516000","wikidata":"https://www.wikidata.org/wiki/Q3023362","display_name":"Denticity","level":3,"score":0.7722938060760498},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.7405184507369995},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7164528965950012},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4561331868171692},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D000085","descriptor_name":"Acetates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D002219","descriptor_name":"Carbamates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D002384","descriptor_name":"Catalysis","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D006859","descriptor_name":"Hydrogen","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D009281","descriptor_name":"Naphthalenes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D009943","descriptor_name":"Organophosphorus Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D012238","descriptor_name":"Rhodium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013237","descriptor_name":"Stereoisomerism","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013379","descriptor_name":"Substrate Specificity","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":4,"locations":[{"id":"doi:10.1021/ol051559c","doi":"https://doi.org/10.1021/ol051559c","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ol051559c","pdf_url":null,"source":{"id":"https://openalex.org/S201989124","display_name":"Organic Letters","issn_l":"1523-7052","issn":["1523-7052","1523-7060"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic Letters","raw_type":"journal-article"},{"id":"pmid:16146381","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/16146381","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic letters","raw_type":"Journal Article"},{"id":"pmh:oai:pure.rug.nl:openaire_cris_publications/f89028cc-c31e-47af-adcb-3731353c34f7","doi":null,"is_oa":false,"landing_page_url":"https://hdl.handle.net/11370/f89028cc-c31e-47af-adcb-3731353c34f7","pdf_url":null,"source":{"id":"https://openalex.org/S4306400420","display_name":"University of Groningen research database (University of Groningen / Centre for Information Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I169381384","host_organization_name":"University of Groningen","host_organization_lineage":["https://openalex.org/I169381384"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Panella, L, Feringa, B L, de Vries, J G & Minnaard, A J 2005, 'Enantioselective Rh-catalyzed hydrogenation of enol acetates and enol carbamates with monodentate phosphoramidites', Organic letters, vol. 7, no. 19, pp. 4177-4180. https://doi.org/10.1021/ol051559c","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:rug:oai:pure.rug.nl:publications/f89028cc-c31e-47af-adcb-3731353c34f7","doi":null,"is_oa":false,"landing_page_url":"https://research.rug.nl/en/publications/f89028cc-c31e-47af-adcb-3731353c34f7","pdf_url":null,"source":{"id":"https://openalex.org/S4306400420","display_name":"University of Groningen research database (University of Groningen / Centre for Information Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I169381384","host_organization_name":"University of Groningen","host_organization_lineage":["https://openalex.org/I169381384"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Organic letters, 7(19), 4177 - 4180. AMER CHEMICAL SOC INC","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":30,"referenced_works":["https://openalex.org/W1970270536","https://openalex.org/W1973876887","https://openalex.org/W1982457469","https://openalex.org/W1984541780","https://openalex.org/W1995997849","https://openalex.org/W2005239250","https://openalex.org/W2005692012","https://openalex.org/W2012528932","https://openalex.org/W2028795352","https://openalex.org/W2051774305","https://openalex.org/W2063638977","https://openalex.org/W2097446202","https://openalex.org/W2097998476","https://openalex.org/W2104370807","https://openalex.org/W2111806983","https://openalex.org/W2117771078","https://openalex.org/W2131908868","https://openalex.org/W2142056289","https://openalex.org/W2142637881","https://openalex.org/W2148574963","https://openalex.org/W2158647082","https://openalex.org/W2160259688","https://openalex.org/W2173928412","https://openalex.org/W2175414305","https://openalex.org/W2949817464","https://openalex.org/W2950002590","https://openalex.org/W2950679172","https://openalex.org/W2951093832","https://openalex.org/W2952018091","https://openalex.org/W4252831296"],"related_works":["https://openalex.org/W2950321021","https://openalex.org/W2002005961","https://openalex.org/W2173928412","https://openalex.org/W2950184889","https://openalex.org/W2952938456","https://openalex.org/W4245304971","https://openalex.org/W2175414305","https://openalex.org/W2095418067","https://openalex.org/W2137339936","https://openalex.org/W2123820943"],"abstract_inverted_index":{"[reaction:":[0],"see":[1],"text]":[2],"Monodentate":[3],"phosphoramidites,":[4],"in":[5],"particular":[6],"PipPhos":[7],"and":[8,26],"its":[9],"octahydro":[10],"analogue,":[11],"are":[12],"excellent":[13],"ligands":[14],"for":[15],"the":[16,40,43],"rhodium-catalyzed":[17],"asymmetric":[18],"hydrogenation":[19],"of":[20,42],"aromatic":[21],"enol":[22,24],"acetates,":[23],"carbamates,":[25],"2-dienol":[27],"carbamates":[28,41],"up":[29],"to":[30,39],"98%":[31],"ee.":[32],"These":[33],"latter":[34],"substrates":[35],"were":[36],"hydrogenated":[37],"selectively":[38],"allyl":[44],"alcohol.":[45]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":5}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}