{"id":"https://openalex.org/W1997378308","doi":"https://doi.org/10.1021/jo051861z","title":"Magnetic Nanoparticles as an Orthogonal Support of Polymer Resins: Applications to Solid-Phase Suzuki Cross-Coupling Reactions","display_name":"Magnetic Nanoparticles as an Orthogonal Support of Polymer Resins: Applications to Solid-Phase Suzuki Cross-Coupling Reactions","publication_year":2005,"publication_date":"2005-12-16","ids":{"openalex":"https://openalex.org/W1997378308","doi":"https://doi.org/10.1021/jo051861z","mag":"1997378308","pmid":"https://pubmed.ncbi.nlm.nih.gov/16408961"},"language":"en","primary_location":{"id":"doi:10.1021/jo051861z","doi":"https://doi.org/10.1021/jo051861z","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo051861z","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100343273","display_name":"Yan Qing Zheng","orcid":"https://orcid.org/0000-0002-1126-6360","observed_orcids":["https://orcid.org/0000-0002-1126-6360"]},"institutions":[{"id":"https://openalex.org/I110378019","display_name":"Southern Illinois University Carbondale","ror":"https://ror.org/049kefs16","country_code":"US","type":"education","lineage":["https://openalex.org/I110378019","https://openalex.org/I2801502357"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Yan Zheng","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois 62901-4409"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois 62901-4409","institution_ids":["https://openalex.org/I110378019"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5024664996","display_name":"Philip D. Stevens","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I110378019","display_name":"Southern Illinois University Carbondale","ror":"https://ror.org/049kefs16","country_code":"US","type":"education","lineage":["https://openalex.org/I110378019","https://openalex.org/I2801502357"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Philip D. Stevens","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois 62901-4409"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois 62901-4409","institution_ids":["https://openalex.org/I110378019"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5101402300","display_name":"Yong Gao","orcid":"https://orcid.org/0000-0002-3566-8460","observed_orcids":["https://orcid.org/0000-0002-3566-8460"]},"institutions":[{"id":"https://openalex.org/I110378019","display_name":"Southern Illinois University Carbondale","ror":"https://ror.org/049kefs16","country_code":"US","type":"education","lineage":["https://openalex.org/I110378019","https://openalex.org/I2801502357"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Yong Gao","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois 62901-4409"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois 62901-4409","institution_ids":["https://openalex.org/I110378019"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I110378019"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":6.3697,"has_fulltext":false,"cited_by_count":145,"citation_normalized_percentile":{"value":0.97587359,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"71","issue":"2","first_page":"537","last_page":"542"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10911","display_name":"Chemical Synthesis and Analysis","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/magnetic-nanoparticles","display_name":"magnetic nanoparticles","score":0.9990000128746033},{"id":"https://openalex.org/keywords/palladium-catalysts","display_name":"palladium catalysts","score":0.734000027179718},{"id":"https://openalex.org/keywords/catalyst-immobilization","display_name":"catalyst immobilization","score":0.628000020980835},{"id":"https://openalex.org/keywords/catalyst-recycling","display_name":"catalyst recycling","score":0.6840000152587891},{"id":"https://openalex.org/keywords/aryl-halides","display_name":"aryl halides","score":0.7089999914169312},{"id":"https://openalex.org/keywords/arylboronic-acids","display_name":"arylboronic acids","score":0.9070000052452087}],"concepts":[{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.7384375929832458},{"id":"https://openalex.org/C13205572","wikidata":"https://www.wikidata.org/wiki/Q899891","display_name":"Suzuki reaction","level":4,"score":0.7020780444145203},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.6445186138153076},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6440821290016174},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6125240325927734},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.5994482636451721},{"id":"https://openalex.org/C87023908","wikidata":"https://www.wikidata.org/wiki/Q3870166","display_name":"Magnetic nanoparticles","level":3,"score":0.5666333436965942},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.5606661438941956},{"id":"https://openalex.org/C48424934","wikidata":"https://www.wikidata.org/wiki/Q898912","display_name":"Coupling reaction","level":3,"score":0.5589999556541443},{"id":"https://openalex.org/C2776241998","wikidata":"https://www.wikidata.org/wiki/Q418088","display_name":"Aryl halide","level":4,"score":0.5299544930458069},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.521206259727478},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.5205875039100647},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4837903678417206},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4135398268699646},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.34552162885665894},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3062019944190979},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.09840857982635498},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D001881","descriptor_name":"Borates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D007202","descriptor_name":"Indicators and Reagents","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008280","descriptor_name":"Magnetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008968","descriptor_name":"Molecular Conformation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012117","descriptor_name":"Resins, Synthetic","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D036103","descriptor_name":"Nanotechnology","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":false},{"descriptor_ui":"D049329","descriptor_name":"Nanostructures","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1021/jo051861z","doi":"https://doi.org/10.1021/jo051861z","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jo051861z","pdf_url":null,"source":{"id":"https://openalex.org/S205050996","display_name":"The Journal of Organic Chemistry","issn_l":"0022-3263","issn":["0022-3263","1520-6904"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Organic Chemistry","raw_type":"journal-article"},{"id":"pmid:16408961","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/16408961","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of organic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":20,"referenced_works":["https://openalex.org/W1516423428","https://openalex.org/W1988447242","https://openalex.org/W1988687441","https://openalex.org/W1998280182","https://openalex.org/W2019155440","https://openalex.org/W2019711709","https://openalex.org/W2031036131","https://openalex.org/W2034716970","https://openalex.org/W2037455416","https://openalex.org/W2041250150","https://openalex.org/W2048393999","https://openalex.org/W2049392986","https://openalex.org/W2061343703","https://openalex.org/W2073439903","https://openalex.org/W2074399323","https://openalex.org/W2117875288","https://openalex.org/W2118969052","https://openalex.org/W2179744103","https://openalex.org/W2320556745","https://openalex.org/W2949206075"],"related_works":["https://openalex.org/W2117875288","https://openalex.org/W2999686261","https://openalex.org/W2266682891","https://openalex.org/W7023549247","https://openalex.org/W3092152929","https://openalex.org/W3045811552","https://openalex.org/W2353418331","https://openalex.org/W2770736173","https://openalex.org/W2153728645","https://openalex.org/W2582326512"],"abstract_inverted_index":{"[reaction:":[0],"see":[1],"text]":[2],"Most":[3],"of":[4,17,25,39,54,82,150,154,161],"the":[5,15,35,52,79,119,136,141,147,159],"reactants":[6],"immobilized":[7],"on":[8,86],"conventional":[9],"solid-phase":[10,26,67,155],"resins":[11,27,87,156],"are":[12],"buried":[13],"inside":[14],"interiors":[16],"lightly":[18],"cross-linked":[19],"polystyrene":[20],"beads.":[21],"An":[22],"orthogonal":[23,63,152],"support":[24],"needs":[28],"to":[29,33,43,65,134],"be":[30],"small":[31],"enough":[32],"penetrate":[34],"interpolymeric":[36],"chain":[37],"spaces":[38],"a":[40,107,129],"swollen":[41],"resin":[42],"reach":[44],"reaction":[45,120],"sites.":[46],"In":[47],"this":[48],"paper,":[49],"we":[50],"report":[51],"use":[53],"magnetic":[55,70,126],"nanoparticles":[56],"(":[57],"approximately":[58],"4":[59],"nm)":[60],"as":[61],"an":[62,83,89,124,151],"matrix":[64,153],"assist":[66],"reactions.":[68],"A":[69],"nanoparticle-supported":[71],"homogeneous":[72],"Pd":[73,111],"catalyst":[74,112],"was":[75,113,132],"employed":[76],"for":[77],"promoting":[78],"Suzuki":[80],"cross-coupling":[81],"aryl":[84],"halide":[85],"and":[88,103,116,157],"excessive":[90],"arylboronic":[91],"acid":[92],"in":[93,164],"solution.":[94],"The":[95,110],"workup":[96],"separating":[97],"three":[98],"components":[99],"(the":[100],"catalyst,":[101],"product,":[102],"remaining":[104],"arylborate)":[105],"is":[106],"chromatography-free":[108],"process.":[109],"magnetically":[114],"isolated":[115],"recycled":[117],"from":[118,140],"mixture":[121],"by":[122],"applying":[123],"external":[125],"field.":[127],"Then,":[128],"filtration":[130],"process":[131],"followed":[133],"recover":[135],"excess":[137],"borate":[138],"reagent":[139],"resins/product.":[142],"Our":[143],"work":[144],"here":[145],"presents":[146],"first":[148],"example":[149],"shows":[158],"promise":[160],"employing":[162],"nanomaterials":[163],"organic":[165],"synthesis.":[166]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":8},{"year":2016,"cited_by_count":5},{"year":2015,"cited_by_count":12},{"year":2014,"cited_by_count":7},{"year":2013,"cited_by_count":7},{"year":2012,"cited_by_count":11}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}