{"id":"https://openalex.org/W1996756640","doi":"https://doi.org/10.1021/jp0485340","title":"Inelastic Electron Tunneling Erases Coupling-Pathway Interferences","display_name":"Inelastic Electron Tunneling Erases Coupling-Pathway Interferences","publication_year":2004,"publication_date":"2004-09-11","ids":{"openalex":"https://openalex.org/W1996756640","doi":"https://doi.org/10.1021/jp0485340","mag":"1996756640"},"language":"en","primary_location":{"id":"doi:10.1021/jp0485340","doi":"https://doi.org/10.1021/jp0485340","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp0485340","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5068655587","display_name":"Spiros S. Skourtis","orcid":"https://orcid.org/0000-0002-5834-248X","observed_orcids":["https://orcid.org/0000-0002-5834-248X"]},"institutions":[{"id":"https://openalex.org/I170201317","display_name":"University of Pittsburgh","ror":"https://ror.org/01an3r305","country_code":"US","type":"education","lineage":["https://openalex.org/I170201317"]},{"id":"https://openalex.org/I170897317","display_name":"Duke University","ror":"https://ror.org/00py81415","country_code":"US","type":"education","lineage":["https://openalex.org/I170897317"]},{"id":"https://openalex.org/I34771391","display_name":"University of Cyprus","ror":"https://ror.org/02qjrjx09","country_code":"CY","type":"education","lineage":["https://openalex.org/I34771391"]}],"countries":["CY","US"],"is_corresponding":true,"raw_author_name":"Spiros S. Skourtis","raw_affiliation_strings":["Department of Physics, University of Cyprus, 1678 Nicosia, Cyprus, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, and Departments of Chemistry and Biochemistry, Duke University, Durham, North Carolina 27708"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics, University of Cyprus, 1678 Nicosia, Cyprus, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, and Departments of Chemistry and Biochemistry, Duke University, Durham, North Carolina 27708","institution_ids":["https://openalex.org/I170201317","https://openalex.org/I170897317","https://openalex.org/I34771391"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043531603","display_name":"David H. Waldeck","orcid":"https://orcid.org/0000-0003-2982-0929","observed_orcids":["https://orcid.org/0000-0003-2982-0929"]},"institutions":[{"id":"https://openalex.org/I170201317","display_name":"University of Pittsburgh","ror":"https://ror.org/01an3r305","country_code":"US","type":"education","lineage":["https://openalex.org/I170201317"]},{"id":"https://openalex.org/I170897317","display_name":"Duke University","ror":"https://ror.org/00py81415","country_code":"US","type":"education","lineage":["https://openalex.org/I170897317"]},{"id":"https://openalex.org/I34771391","display_name":"University of Cyprus","ror":"https://ror.org/02qjrjx09","country_code":"CY","type":"education","lineage":["https://openalex.org/I34771391"]}],"countries":["CY","US"],"is_corresponding":false,"raw_author_name":"David H. Waldeck","raw_affiliation_strings":["Department of Physics, University of Cyprus, 1678 Nicosia, Cyprus, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, and Departments of Chemistry and Biochemistry, Duke University, Durham, North Carolina 27708"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics, University of Cyprus, 1678 Nicosia, Cyprus, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, and Departments of Chemistry and Biochemistry, Duke University, Durham, North Carolina 27708","institution_ids":["https://openalex.org/I170201317","https://openalex.org/I170897317","https://openalex.org/I34771391"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5003618068","display_name":"David N. Beratan","orcid":"https://orcid.org/0000-0003-4758-8676","observed_orcids":["https://orcid.org/0000-0003-4758-8676"]},"institutions":[{"id":"https://openalex.org/I170201317","display_name":"University of Pittsburgh","ror":"https://ror.org/01an3r305","country_code":"US","type":"education","lineage":["https://openalex.org/I170201317"]},{"id":"https://openalex.org/I170897317","display_name":"Duke University","ror":"https://ror.org/00py81415","country_code":"US","type":"education","lineage":["https://openalex.org/I170897317"]},{"id":"https://openalex.org/I34771391","display_name":"University of Cyprus","ror":"https://ror.org/02qjrjx09","country_code":"CY","type":"education","lineage":["https://openalex.org/I34771391"]}],"countries":["CY","US"],"is_corresponding":true,"raw_author_name":"David N. Beratan","raw_affiliation_strings":["Department of Physics, University of Cyprus, 1678 Nicosia, Cyprus, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, and Departments of Chemistry and Biochemistry, Duke University, Durham, North Carolina 27708"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics, University of Cyprus, 1678 Nicosia, Cyprus, Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, and Departments of Chemistry and Biochemistry, Duke University, Durham, North Carolina 27708","institution_ids":["https://openalex.org/I170201317","https://openalex.org/I170897317","https://openalex.org/I34771391"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5003618068","https://openalex.org/A5068655587"],"corresponding_institution_ids":["https://openalex.org/I170201317","https://openalex.org/I170897317","https://openalex.org/I34771391"],"apc_list":null,"apc_paid":null,"fwci":3.4847,"has_fulltext":false,"cited_by_count":66,"citation_normalized_percentile":{"value":0.9176511,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"108","issue":"40","first_page":"15511","last_page":"15518"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.9038000106811523,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.9038000106811523,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.04699999839067459,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10382","display_name":"Quantum and electron transport phenomena","score":0.009499999694526196,"subfield":{"id":"https://openalex.org/subfields/3104","display_name":"Condensed Matter Physics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/inelastic-electron-tunneling","display_name":"inelastic electron tunneling","score":0.9950000047683716},{"id":"https://openalex.org/keywords/nonadiabatic-electron-transfer","display_name":"nonadiabatic electron transfer","score":0.9120000004768372},{"id":"https://openalex.org/keywords/coherence-loss","display_name":"coherence loss","score":0.7279999852180481},{"id":"https://openalex.org/keywords/decoherence","display_name":"decoherence","score":0.6850000023841858},{"id":"https://openalex.org/keywords/bridge-vibration","display_name":"bridge vibration","score":0.6019999980926514},{"id":"https://openalex.org/keywords/donor-acceptor-interactions","display_name":"donor-acceptor interactions","score":0.8309999704360962},{"id":"https://openalex.org/keywords/electron-transfer-rate","display_name":"electron transfer rate","score":0.8569999933242798},{"id":"https://openalex.org/keywords/molecular-electronics","display_name":"molecular electronics","score":0.6980000138282776},{"id":"https://openalex.org/keywords/tunnel-barrier","display_name":"tunnel barrier","score":0.6919999718666077}],"concepts":[{"id":"https://openalex.org/C120398109","wikidata":"https://www.wikidata.org/wiki/Q175751","display_name":"Quantum tunnelling","level":2,"score":0.7487116456031799},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.5542739629745483},{"id":"https://openalex.org/C147120987","wikidata":"https://www.wikidata.org/wiki/Q2225","display_name":"Electron","level":2,"score":0.539894700050354},{"id":"https://openalex.org/C2781181686","wikidata":"https://www.wikidata.org/wiki/Q4226068","display_name":"Coherence (philosophical gambling strategy)","level":2,"score":0.518100917339325},{"id":"https://openalex.org/C177731217","wikidata":"https://www.wikidata.org/wiki/Q2622244","display_name":"Mesoscopic physics","level":2,"score":0.5167455077171326},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.45983240008354187},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.4482173025608063},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4481222331523895},{"id":"https://openalex.org/C122527463","wikidata":"https://www.wikidata.org/wiki/Q578430","display_name":"Quantum decoherence","level":3,"score":0.43800753355026245},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.4338109493255615},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.4004782438278198},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.31215065717697144},{"id":"https://openalex.org/C84114770","wikidata":"https://www.wikidata.org/wiki/Q46344","display_name":"Quantum","level":2,"score":0.14544916152954102},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jp0485340","doi":"https://doi.org/10.1021/jp0485340","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp0485340","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":53,"referenced_works":["https://openalex.org/W202906003","https://openalex.org/W1492361996","https://openalex.org/W1658650122","https://openalex.org/W1676620288","https://openalex.org/W1966082719","https://openalex.org/W1967189497","https://openalex.org/W1969067782","https://openalex.org/W1969455508","https://openalex.org/W1970778405","https://openalex.org/W1970809021","https://openalex.org/W1972254147","https://openalex.org/W1973312152","https://openalex.org/W1978568638","https://openalex.org/W1980900596","https://openalex.org/W1986272079","https://openalex.org/W1994994267","https://openalex.org/W2001833390","https://openalex.org/W2002489839","https://openalex.org/W2008088867","https://openalex.org/W2010061372","https://openalex.org/W2012915245","https://openalex.org/W2014472022","https://openalex.org/W2016301982","https://openalex.org/W2016663361","https://openalex.org/W2027748614","https://openalex.org/W2028558680","https://openalex.org/W2033103770","https://openalex.org/W2043334053","https://openalex.org/W2044979610","https://openalex.org/W2048083925","https://openalex.org/W2048961299","https://openalex.org/W2059635104","https://openalex.org/W2062663699","https://openalex.org/W2064075901","https://openalex.org/W2070237575","https://openalex.org/W2070249435","https://openalex.org/W2073280539","https://openalex.org/W2074628515","https://openalex.org/W2077222377","https://openalex.org/W2079185228","https://openalex.org/W2087206639","https://openalex.org/W2106960391","https://openalex.org/W2118500892","https://openalex.org/W2121953512","https://openalex.org/W2143531448","https://openalex.org/W2155824593","https://openalex.org/W2513228678","https://openalex.org/W2951247880","https://openalex.org/W2990455438","https://openalex.org/W3004420581","https://openalex.org/W4211208981","https://openalex.org/W4236572243","https://openalex.org/W4254260635"],"related_works":["https://openalex.org/W1991355165","https://openalex.org/W1498923276","https://openalex.org/W4298276783","https://openalex.org/W1975586442","https://openalex.org/W1925227782","https://openalex.org/W1965399183","https://openalex.org/W2040803771","https://openalex.org/W4211186928","https://openalex.org/W4296906559","https://openalex.org/W1503679273"],"abstract_inverted_index":{"Theoretical":[0],"analysis":[1],"of":[2,100],"nonadiabatic":[3],"electron-transfer":[4,76,94],"reactions":[5],"in":[6,103,120,127,141],"molecules":[7,121],"usually":[8],"assumes":[9],"that":[10,29,115],"electron":[11,33,139],"amplitude":[12],"propagates":[13],"coherently":[14],"from":[15,117],"the":[16,19,31,40,43,49,52,70,75],"reductant":[17],"to":[18,89,124,137],"oxidant":[20],"via":[21],"covalent":[22],"and":[23,67,73,132],"noncovalent":[24],"coupling":[25],"pathways.":[26],"We":[27,58],"show":[28,68],"when":[30],"tunneling":[32,54,111],"excites":[34],"local":[35],"bridge":[36],"vibrations":[37],"(inelastic":[38],"tunneling),":[39],"excitation":[41],"\u201clabels\u201d":[42],"physical":[44],"pathway":[45],"traversed.":[46],"As":[47],"such,":[48],"coherence":[50,84,125],"among":[51],"bridge-mediated":[53],"pathways":[55,108],"is":[56,78,122],"destroyed.":[57],"illustrate":[59],"this":[60],"effect":[61,97],"using":[62],"a":[63,87],"simple":[64],"model":[65],"Hamiltonian":[66],"how":[69],"donor\u2212acceptor":[71],"interaction,":[72],"thus":[74],"rate,":[77],"modified":[79],"by":[80],"inelastic":[81,118],"effects.":[82],"Pathway":[83,113],"loss":[85,126],"provides":[86],"mechanism":[88],"relax":[90],"orbital-symmetry":[91],"constraints":[92],"on":[93],"reactions.":[95],"This":[96],"may":[98],"be":[99],"particular":[101],"significance":[102],"macromolecules":[104],"with":[105],"destructively":[106],"interfering":[107],"or":[109],"low":[110],"barriers.":[112],"decoherence":[114],"arises":[116],"effects":[119],"analogous":[123],"mesoscopic":[128],"\u201cwhich":[129],"way\u201d":[130],"interferometers":[131],"might":[133],"provide":[134],"an":[135],"approach":[136],"gate":[138],"flow":[140],"molecular-scale":[142],"devices.":[143]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":6},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-10T09:11:00.788812","created_date":"2016-06-24T00:00:00"}