{"id":"https://openalex.org/W1996467331","doi":"https://doi.org/10.1063/1.1698996","title":"Adsorption Studies on Clay Minerals. II. A Formulation of the Thermodynamics of Exchange Adsorption","display_name":"Adsorption Studies on Clay Minerals. II. A Formulation of the Thermodynamics of Exchange Adsorption","publication_year":1953,"publication_date":"1953-04-01","ids":{"openalex":"https://openalex.org/W1996467331","doi":"https://doi.org/10.1063/1.1698996","mag":"1996467331"},"language":"en","primary_location":{"id":"doi:10.1063/1.1698996","doi":"https://doi.org/10.1063/1.1698996","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.1698996","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W1996467331"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5108470849","display_name":"George L. Gaines","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I32971472","display_name":"Yale University","ror":"https://ror.org/03v76x132","country_code":"US","type":"education","lineage":["https://openalex.org/I32971472"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"George L. Gaines","raw_affiliation_strings":["Sterling Chemistry Laboratory, Yale University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sterling Chemistry Laboratory, Yale University","institution_ids":["https://openalex.org/I32971472"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5037487325","display_name":"Henry Carrison Thomas","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I32971472","display_name":"Yale University","ror":"https://ror.org/03v76x132","country_code":"US","type":"education","lineage":["https://openalex.org/I32971472"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Henry C. Thomas","raw_affiliation_strings":["Sterling Chemistry Laboratory, Yale University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sterling Chemistry Laboratory, Yale University","institution_ids":["https://openalex.org/I32971472"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I32971472"],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":10.7704,"has_fulltext":false,"cited_by_count":864,"citation_normalized_percentile":{"value":0.98041045,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"21","issue":"4","first_page":"714","last_page":"718"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11852","display_name":"Clay minerals and soil interactions","score":0.9556000232696533,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11852","display_name":"Clay minerals and soil interactions","score":0.9556000232696533,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13604","display_name":"Adsorption, diffusion, and thermodynamic properties of materials","score":0.017999999225139618,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12524","display_name":"Chemical Synthesis and Characterization","score":0.009100000374019146,"subfield":{"id":"https://openalex.org/subfields/2311","display_name":"Waste Management and Disposal"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/clay-minerals","display_name":"clay minerals","score":0.7990000247955322},{"id":"https://openalex.org/keywords/exchange-adsorption","display_name":"exchange adsorption","score":0.9660000205039978},{"id":"https://openalex.org/keywords/ion-exchange","display_name":"ion exchange","score":0.7870000004768372},{"id":"https://openalex.org/keywords/thermodynamic-equilibrium-constants","display_name":"thermodynamic equilibrium constants","score":0.8880000114440918},{"id":"https://openalex.org/keywords/activity-coefficients","display_name":"activity coefficients","score":0.9789999723434448},{"id":"https://openalex.org/keywords/solvent-effects","display_name":"solvent effects","score":0.9049999713897705},{"id":"https://openalex.org/keywords/operating-variables","display_name":"operating variables","score":0.5910000205039978},{"id":"https://openalex.org/keywords/adsorption-thermodynamics","display_name":"adsorption thermodynamics","score":0.6779999732971191}],"concepts":[{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.8346979022026062},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.767769455909729},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6135768890380859},{"id":"https://openalex.org/C45374587","wikidata":"https://www.wikidata.org/wiki/Q12525525","display_name":"Computation","level":2,"score":0.5269699096679688},{"id":"https://openalex.org/C168167062","wikidata":"https://www.wikidata.org/wiki/Q1117970","display_name":"Component (thermodynamics)","level":2,"score":0.5069401264190674},{"id":"https://openalex.org/C117760992","wikidata":"https://www.wikidata.org/wiki/Q389137","display_name":"Ion exchange","level":3,"score":0.469882994890213},{"id":"https://openalex.org/C10710636","wikidata":"https://www.wikidata.org/wiki/Q857809","display_name":"Equilibrium constant","level":2,"score":0.4658466577529907},{"id":"https://openalex.org/C170961132","wikidata":"https://www.wikidata.org/wiki/Q745224","display_name":"Activity coefficient","level":3,"score":0.43994003534317017},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.42897239327430725},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.3081662654876709},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2351377308368683},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.17748931050300598},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1552869975566864},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.15358394384384155},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.05735588073730469},{"id":"https://openalex.org/C11413529","wikidata":"https://www.wikidata.org/wiki/Q8366","display_name":"Algorithm","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.1698996","doi":"https://doi.org/10.1063/1.1698996","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.1698996","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":4,"referenced_works":["https://openalex.org/W1984054788","https://openalex.org/W2318787598","https://openalex.org/W2321541803","https://openalex.org/W2330939236"],"related_works":["https://openalex.org/W2167187137","https://openalex.org/W1986512834","https://openalex.org/W2060445084","https://openalex.org/W2025881040","https://openalex.org/W1972548777","https://openalex.org/W2056076203","https://openalex.org/W1981319147","https://openalex.org/W2064557450","https://openalex.org/W2953379331","https://openalex.org/W2325385699"],"abstract_inverted_index":{"Expressions":[0],"for":[1,8,24],"thermodynamic":[2],"equilibrium":[3],"constants":[4],"are":[5,32,49],"set":[6],"up":[7],"the":[9,22,25,28,36,39],"ion-exchange":[10],"equilibria":[11],"of":[12,17,27,38],"models":[13],"defined":[14],"in":[15],"terms":[16],"operational":[18],"variables.":[19],"Formulas":[20],"summarizing":[21],"methods":[23],"computation":[26],"requisite":[29],"activity":[30],"coefficients":[31],"given.":[33],"In":[34],"particular,":[35],"effects":[37],"solvent,":[40],"which":[41],"is":[42],"considered":[43],"as":[44],"an":[45],"independently":[46],"variable":[47],"component,":[48],"taken":[50],"explicitly":[51],"into":[52],"account.":[53]},"counts_by_year":[{"year":2026,"cited_by_count":7},{"year":2025,"cited_by_count":10},{"year":2024,"cited_by_count":11},{"year":2023,"cited_by_count":18},{"year":2022,"cited_by_count":16},{"year":2021,"cited_by_count":15},{"year":2020,"cited_by_count":11},{"year":2019,"cited_by_count":17},{"year":2018,"cited_by_count":20},{"year":2017,"cited_by_count":25},{"year":2016,"cited_by_count":24},{"year":2015,"cited_by_count":23},{"year":2014,"cited_by_count":24},{"year":2013,"cited_by_count":19},{"year":2012,"cited_by_count":24}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2016-06-24T00:00:00"}