{"id":"https://openalex.org/W1995907864","doi":"https://doi.org/10.1021/la100701b","title":"Surface Structures of an Amphiphilic Tri-Block Copolymer in Air and in Water Probed Using Sum Frequency Generation Vibrational Spectroscopy","display_name":"Surface Structures of an Amphiphilic Tri-Block Copolymer in Air and in Water Probed Using Sum Frequency Generation Vibrational Spectroscopy","publication_year":2010,"publication_date":"2010-05-13","ids":{"openalex":"https://openalex.org/W1995907864","doi":"https://doi.org/10.1021/la100701b","mag":"1995907864","pmid":"https://pubmed.ncbi.nlm.nih.gov/20465236"},"language":"en","primary_location":{"id":"doi:10.1021/la100701b","doi":"https://doi.org/10.1021/la100701b","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la100701b","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5004391315","display_name":"Cornelius B. Kristalyn","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Cornelius B. Kristalyn","raw_affiliation_strings":["Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109","Department of Chemistry; University of Michigan; 930 North University Avenue Ann Arbor Michigan 48109 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109","institution_ids":["https://openalex.org/I27837315"]},{"raw_affiliation_string":"Department of Chemistry; University of Michigan; 930 North University Avenue Ann Arbor Michigan 48109 USA","institution_ids":["https://openalex.org/I27837315"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5048756404","display_name":"Xiaolin L\u00fc","orcid":"https://orcid.org/0000-0002-0932-8489","observed_orcids":["https://orcid.org/0000-0002-0932-8489","https://orcid.org/0000-0003-4507-3214"]},"institutions":[{"id":"https://openalex.org/I1328775524","display_name":"Zhejiang Sci-Tech University","ror":"https://ror.org/03893we55","country_code":"CN","type":"education","lineage":["https://openalex.org/I1328775524"]},{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["CN","US"],"is_corresponding":false,"raw_author_name":"Xiaolin Lu","raw_affiliation_strings":["Department of Chemistry, Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Zhejiang Sci-Tech University, Hangzhou 310018, China","Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Education Ministry, Zhejiang Sci-Tech University, Hangzhou 310018, China","institution_ids":["https://openalex.org/I1328775524"]},{"raw_affiliation_string":"Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109","institution_ids":["https://openalex.org/I27837315"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010796214","display_name":"Craig J. Weinman","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Craig J. Weinman","raw_affiliation_strings":["Department of Materials Science & Engineering, Cornell University, Ithaca, New York 14853","Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science & Engineering, Cornell University, Ithaca, New York 14853","institution_ids":["https://openalex.org/I205783295"]},{"raw_affiliation_string":"Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853","institution_ids":["https://openalex.org/I205783295"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029662019","display_name":"Christopher Kemper Ober","orcid":"https://orcid.org/0000-0002-3805-3314","observed_orcids":["https://orcid.org/0000-0002-3805-3314"]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Christopher K. Ober","raw_affiliation_strings":["Department of Materials Science & Engineering, Cornell University, Ithaca, New York 14853","Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science & Engineering, Cornell University, Ithaca, New York 14853","institution_ids":["https://openalex.org/I205783295"]},{"raw_affiliation_string":"Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853","institution_ids":["https://openalex.org/I205783295"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108081503","display_name":"Edward J. Kr\u00e4mer","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Edward J. Kramer","raw_affiliation_strings":["Department of Chemical Engineering","Materials Department"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical Engineering","institution_ids":[]},{"raw_affiliation_string":"Materials Department","institution_ids":[]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054123780","display_name":"Zhan Chen","orcid":"https://orcid.org/0000-0001-8687-8348","observed_orcids":["https://orcid.org/0000-0001-8687-8348"]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Zhan Chen","raw_affiliation_strings":["Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109","institution_ids":["https://openalex.org/I27837315"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5054123780"],"corresponding_institution_ids":["https://openalex.org/I27837315"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.961,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.68802521,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"26","issue":"13","first_page":"11337","last_page":"11343"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.6317999958992004,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.6317999958992004,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.2653999924659729,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12071","display_name":"Marine Biology and Environmental Chemistry","score":0.03370000049471855,"subfield":{"id":"https://openalex.org/subfields/2212","display_name":"Ocean Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/amphiphilic-triblock-copolymers","display_name":"amphiphilic triblock copolymers","score":0.9399999976158142},{"id":"https://openalex.org/keywords/polymer-surface-structure","display_name":"polymer surface structure","score":0.6060000061988831},{"id":"https://openalex.org/keywords/fluorinated-alkyl-groups","display_name":"fluorinated alkyl groups","score":0.7689999938011169},{"id":"https://openalex.org/keywords/ethoxy-groups","display_name":"ethoxy groups","score":0.9240000247955322},{"id":"https://openalex.org/keywords/antifouling-coatings","display_name":"antifouling coatings","score":0.7409999966621399},{"id":"https://openalex.org/keywords/polymer-films","display_name":"polymer films","score":0.4449999928474426},{"id":"https://openalex.org/keywords/polymer-water-interface","display_name":"polymer-water interface","score":0.7580000162124634},{"id":"https://openalex.org/keywords/polymer-air-interface","display_name":"polymer-air interface","score":0.8669999837875366},{"id":"https://openalex.org/keywords/polymer-film-thickness","display_name":"polymer film thickness","score":0.4440000057220459},{"id":"https://openalex.org/keywords/caf2-substrate","display_name":"CaF2 substrate","score":0.6949999928474426}],"concepts":[{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.7682560682296753},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.7087079286575317},{"id":"https://openalex.org/C67407626","wikidata":"https://www.wikidata.org/wiki/Q5723218","display_name":"Amphiphile","level":4,"score":0.6461626291275024},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5637549161911011},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.5298072099685669},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.47120994329452515},{"id":"https://openalex.org/C160018778","wikidata":"https://www.wikidata.org/wiki/Q3123190","display_name":"Sum-frequency generation","level":4,"score":0.46173393726348877},{"id":"https://openalex.org/C6556556","wikidata":"https://www.wikidata.org/wiki/Q899239","display_name":"Contact angle","level":2,"score":0.4520539939403534},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.4469899535179138},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.4405378997325897},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3464551568031311},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2380056381225586},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.2152782380580902},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.07777908444404602},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C78854221","wikidata":"https://www.wikidata.org/wiki/Q756033","display_name":"Nonlinear optics","level":3,"score":0.0},{"id":"https://openalex.org/C520434653","wikidata":"https://www.wikidata.org/wiki/Q38867","display_name":"Laser","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[{"descriptor_ui":"D000388","descriptor_name":"Air","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D008962","descriptor_name":"Models, Theoretical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011108","descriptor_name":"Polymers","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013057","descriptor_name":"Spectrum Analysis","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D013499","descriptor_name":"Surface Properties","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D014732","descriptor_name":"Vibration","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D014867","descriptor_name":"Water","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D017550","descriptor_name":"Spectroscopy, Fourier Transform Infrared","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D057927","descriptor_name":"Hydrophobic and Hydrophilic Interactions","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/la100701b","doi":"https://doi.org/10.1021/la100701b","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la100701b","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},{"id":"pmid:20465236","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/20465236","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir : the ACS journal of surfaces and colloids","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":53,"referenced_works":["https://openalex.org/W1965307135","https://openalex.org/W1968073244","https://openalex.org/W1971178659","https://openalex.org/W1971585423","https://openalex.org/W1973624547","https://openalex.org/W1973702883","https://openalex.org/W1975366935","https://openalex.org/W1979723206","https://openalex.org/W1980149506","https://openalex.org/W1983660131","https://openalex.org/W1986001588","https://openalex.org/W1986617369","https://openalex.org/W1987176498","https://openalex.org/W1991821478","https://openalex.org/W2002650530","https://openalex.org/W2015106186","https://openalex.org/W2017297771","https://openalex.org/W2019875773","https://openalex.org/W2022166684","https://openalex.org/W2022951823","https://openalex.org/W2023531633","https://openalex.org/W2025434047","https://openalex.org/W2027375070","https://openalex.org/W2028365184","https://openalex.org/W2031110811","https://openalex.org/W2031799468","https://openalex.org/W2032128691","https://openalex.org/W2037019009","https://openalex.org/W2037855380","https://openalex.org/W2037904817","https://openalex.org/W2039534196","https://openalex.org/W2040753698","https://openalex.org/W2041233437","https://openalex.org/W2045111209","https://openalex.org/W2048981720","https://openalex.org/W2053940175","https://openalex.org/W2060548005","https://openalex.org/W2064871903","https://openalex.org/W2069200264","https://openalex.org/W2080411202","https://openalex.org/W2080750303","https://openalex.org/W2085369674","https://openalex.org/W2086365876","https://openalex.org/W2098908528","https://openalex.org/W2117331520","https://openalex.org/W2121242766","https://openalex.org/W2129151312","https://openalex.org/W2135350520","https://openalex.org/W2137419733","https://openalex.org/W2150850983","https://openalex.org/W2165372810","https://openalex.org/W2167431158","https://openalex.org/W2464552632"],"related_works":["https://openalex.org/W2000781433","https://openalex.org/W155260321","https://openalex.org/W1509969897","https://openalex.org/W3159658071","https://openalex.org/W2026736298","https://openalex.org/W2054492145","https://openalex.org/W2366485691","https://openalex.org/W2043337062","https://openalex.org/W2751975149","https://openalex.org/W2098908528"],"abstract_inverted_index":{"Sum":[0],"frequency":[1],"generation":[2],"(SFG)":[3],"vibrational":[4],"spectroscopy":[5],"has":[6,139],"been":[7,140],"applied":[8],"to":[9],"investigate":[10],"surface":[11,65,134,165,180],"structures":[12,66],"of":[13,38,67,136],"an":[14,39],"amphiphilic":[15,46],"surface-active":[16,36],"block":[17],"copolymer":[18,48,69],"(SABC)":[19],"film":[20,70],"deposited":[21],"on":[22,163],"a":[23,35],"CaF(2)":[24],"substrate,":[25],"in":[26,29,31,71,74,119,122,142,166,181],"air":[27,72,120,168],"and":[28,73,121,147,169,171],"water":[30,75,123,182],"situ.":[32],"Developed":[33],"as":[34,55,57,99,101],"component":[37],"antifouling":[40],"coating":[41],"for":[42],"marine":[43],"applications,":[44],"this":[45,137],"triblock":[47],"contains":[49],"both":[50,167],"hydrophobic":[51,158],"fluorinated":[52],"alkyl":[53],"groups":[54,149],"well":[56,100],"hydrophilic":[58],"ethoxy":[59,186],"groups.":[60,187],"It":[61],"was":[62,161,176],"found":[63],"that":[64,174],"the":[68,81,94,102,116,128,145,157,164,179],"cannot":[76],"be":[77,91,125],"probed":[78],"directly":[79],"using":[80],"SFG":[82,88,130],"experimental":[83],"geometry":[84],"we":[85,172],"adopted":[86],"because":[87],"signals":[89],"can":[90,124],"contributed":[92],"from":[93,127],"polymer/air":[95],"(or":[96],"polymer/water)":[97],"interface":[98],"buried":[103],"polymer/CaF(2)":[104],"substrate":[105],"interface.":[106],"Using":[107],"polymer":[108,117,138],"films":[109],"with":[110,154],"varied":[111],"thicknesses,":[112],"structural":[113],"information":[114],"about":[115],"surfaces":[118],"deduced":[126],"detected":[129],"signals.":[131],"With":[132],"SFG,":[133],"restructuring":[135],"observed":[141],"water,":[143,170],"especially":[144],"methyl":[146],"methylene":[148],"change":[150],"orientations":[151],"upon":[152],"contact":[153],"water.":[155],"However,":[156],"fluoroalkyl":[159],"group":[160],"present":[162],"believe":[173],"it":[175],"held":[177],"near":[178],"by":[183],"its":[184],"neighboring":[185]},"counts_by_year":[{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}