{"id":"https://openalex.org/W1995686597","doi":"https://doi.org/10.1039/p29960000023","title":"Hydroxyl-radical-induced reactions of poly (acrylic acid); a pulse radiolysis, EPR and product study. Part II. Oxygenated aqueous solutions","display_name":"Hydroxyl-radical-induced reactions of poly (acrylic acid); a pulse radiolysis, EPR and product study. Part II. Oxygenated aqueous solutions","publication_year":1996,"publication_date":"1996-01-01","ids":{"openalex":"https://openalex.org/W1995686597","doi":"https://doi.org/10.1039/p29960000023","mag":"1995686597"},"language":"en","primary_location":{"id":"doi:10.1039/p29960000023","doi":"https://doi.org/10.1039/p29960000023","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29960000023","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 2","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5060110923","display_name":"Piotr Ula\u0144ski","orcid":"https://orcid.org/0000-0002-4310-3574","observed_orcids":["https://orcid.org/0000-0002-4310-3574"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Piotr Ulanski","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068622337","display_name":"Eberhard Bothe","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Eberhard Bothe","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109718313","display_name":"Knut Hildenbrand","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Knut Hildenbrand","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108476507","display_name":"Janusz Marian Rosiak","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Janusz M. Rosiak","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5009103445","display_name":"Clemens von Sonntag","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Clemens von Sonntag","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.9908,"has_fulltext":false,"cited_by_count":45,"citation_normalized_percentile":{"value":0.83632424,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":null,"issue":"1","first_page":"23","last_page":"23"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.7968999743461609,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.7968999743461609,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10210","display_name":"Advanced oxidation water treatment","score":0.08720000088214874,"subfield":{"id":"https://openalex.org/subfields/2312","display_name":"Water Science and Technology"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.0478999987244606,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/poly-acrylic-acid","display_name":"poly(acrylic acid)","score":0.9539999961853027},{"id":"https://openalex.org/keywords/hydroxyl-radicals","display_name":"hydroxyl radicals","score":0.9670000076293945},{"id":"https://openalex.org/keywords/peroxyl-radicals","display_name":"peroxy radicals","score":0.7910000085830688},{"id":"https://openalex.org/keywords/oxygen-consumption","display_name":"oxygen consumption","score":0.33399999141693115},{"id":"https://openalex.org/keywords/ph-dependence","display_name":"pH dependence","score":0.6700000166893005},{"id":"https://openalex.org/keywords/hydrogen-abstraction","display_name":"hydrogen abstraction","score":0.527999997138977},{"id":"https://openalex.org/keywords/decarboxylation","display_name":"decarboxylation","score":0.7599999904632568},{"id":"https://openalex.org/keywords/chain-scission","display_name":"chain scission","score":0.7459999918937683},{"id":"https://openalex.org/keywords/hydroperoxide-decomposition","display_name":"hydroperoxide decomposition","score":0.9070000052452087},{"id":"https://openalex.org/keywords/bimolecular-termination","display_name":"bimolecular termination","score":0.675000011920929}],"concepts":[{"id":"https://openalex.org/C66887884","wikidata":"https://www.wikidata.org/wiki/Q2126498","display_name":"Radiolysis","level":3,"score":0.9383817911148071},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9180618524551392},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.9178292751312256},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6417828798294067},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.638260543346405},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.5910475254058838},{"id":"https://openalex.org/C2780002320","wikidata":"https://www.wikidata.org/wiki/Q413447","display_name":"Acetylacetone","level":2,"score":0.5518900156021118},{"id":"https://openalex.org/C2780503075","wikidata":"https://www.wikidata.org/wiki/Q324628","display_name":"Acrylic acid","level":4,"score":0.4779667556285858},{"id":"https://openalex.org/C77176794","wikidata":"https://www.wikidata.org/wiki/Q187689","display_name":"Oxidizing agent","level":2,"score":0.4593499004840851},{"id":"https://openalex.org/C2780595602","wikidata":"https://www.wikidata.org/wiki/Q898436","display_name":"Decarboxylation","level":3,"score":0.45272496342658997},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.4294445514678955},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3235305845737457},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.18142345547676086},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.16098439693450928},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.12746605277061462},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.09126195311546326},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.0},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/p29960000023","doi":"https://doi.org/10.1039/p29960000023","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29960000023","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Perkin Transactions 2","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322679","display_name":"International Atomic Energy Agency","ror":"https://ror.org/02zt1gg83"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":29,"referenced_works":["https://openalex.org/W106697270","https://openalex.org/W242625311","https://openalex.org/W1926950498","https://openalex.org/W1940787743","https://openalex.org/W1966817137","https://openalex.org/W1970205548","https://openalex.org/W2011883105","https://openalex.org/W2013363298","https://openalex.org/W2020367128","https://openalex.org/W2022628102","https://openalex.org/W2025179867","https://openalex.org/W2035201668","https://openalex.org/W2037716145","https://openalex.org/W2040239861","https://openalex.org/W2048917812","https://openalex.org/W2055096662","https://openalex.org/W2068110850","https://openalex.org/W2068544355","https://openalex.org/W2069432002","https://openalex.org/W2074838202","https://openalex.org/W2088240455","https://openalex.org/W2090143415","https://openalex.org/W2102834112","https://openalex.org/W2107302566","https://openalex.org/W2118226734","https://openalex.org/W2135321248","https://openalex.org/W2168472599","https://openalex.org/W2221294497","https://openalex.org/W2318621416"],"related_works":["https://openalex.org/W4254560719","https://openalex.org/W2022628102","https://openalex.org/W1970404441","https://openalex.org/W2089762620","https://openalex.org/W3208700446","https://openalex.org/W2008644872","https://openalex.org/W2107771631","https://openalex.org/W1970962038","https://openalex.org/W346917386","https://openalex.org/W4233715128"],"abstract_inverted_index":{"Hydroxyl":[0],"radicals":[1,37,46,107,126,153],"were":[2],"generated":[3],"radiolytically":[4],"in":[5,24,128,137,251],"N2O\u2013O2(4:1)-saturated":[6],"dilute":[7],"aqueous":[8],"solutions":[9],"of":[10,75,103,131,140,148,194,210,220,223,242,254],"poly(acrylic":[11],"acid),":[12],"PAA.":[13],"They":[14],"react":[15],"with":[16,113,134,266],"PAA":[17,23,36,105,125,152,226],"by":[18,40,70,92,109,225,234,239,263],"abstracting":[19],"H":[20],"atoms":[21],"from":[22,157],"both":[25],"the":[26,31,43,76,93,97,101,104,122,129,138,141,192,218,243,252,255],"\u03b1-":[27],"and":[28,57,191],"\u03b2positions":[29],"to":[30,85,162,175,186,202],"carboxy":[32],"group.":[33],"The":[34,73,207,229,246],"resulting":[35],"are":[38,232,249],"converted":[39],"O2":[41,90,144,211],"into":[42],"corresponding":[44],"peroxyl":[45,106,142],"(k=":[47],"3.1":[48],"\u00d7":[49,60],"108":[50,61],"dm33":[51],"mol\u20131":[52,63],"s\u20131":[53,64],"at":[54,65,79,159,164,172,177,183,188,199,204,213],"pH":[55,66,81,160,165,173,178,184,189,200,205,214],"3.5":[56,174,201],"k=":[58],"1":[59],"dm3":[62],"10,":[67],"as":[68,167,259],"measured":[69],"pulse":[71,264],"radiolysis).":[72],"lowering":[74],"rate":[77],"constant":[78],"high":[80,208],"has":[82,260],"been":[83,261],"attributed":[84],"a":[86,240],"diffusion":[87],"barrier":[88],"for":[89],"exerted":[91],"ion":[94],"cloud":[95],"around":[96],"charged":[98],"macroradical.":[99],"Although":[100],"lifetimes":[102],"(measured":[108],"EPR":[110],"spectroscopy)":[111],"increase":[112,136],"increasing":[114],"pH,":[115],"they":[116],"still":[117],"decay":[118],"much":[119],"faster":[120],"than":[121],"very":[123],"long-lived":[124],"formed":[127,233,250],"absence":[130],"O2.":[132],"Concomitant":[133],"an":[135],"lifetime":[139],"radicals,":[143],"uptake":[145,212],"(in":[146],"units":[147],"mol":[149,151],"per":[150],"initially":[154],"formed)":[155],"increases":[156],"1.7":[158],"2.5":[161],"17":[163],"10":[166,215],"does":[168],"decarboxylation":[169],"(from":[170,181,197],"1.0":[171],"13":[176],"10),":[179],"scission":[180],"0.05":[182],"2":[185],"2.4":[187],"9)":[190],"formation":[193],"acetylacetone-like":[195,230],"products":[196,231],"0.35":[198],"1.05":[203],"10).":[206],"yield":[209],"is":[216],"mainly":[217],"result":[219],"repetitive":[221],"abstraction":[222],"\u03b1-hydrogens":[224],"\u03b1-peroxyl":[227],"radicals.":[228],"intramolecular":[235],"1,5-H-transfer":[236],"reactions":[237,258],"followed":[238],"decomposition":[241],"ensuing":[244],"hydroperoxides.":[245],"chain":[247],"breaks":[248],"course":[253],"bimolecular":[256],"termination":[257],"shown":[262],"radiolysis":[265],"low-angle":[267],"laser":[268],"light-scattering":[269],"detection.":[270]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":6},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":2},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}
