{"id":"https://openalex.org/W1995064448","doi":"https://doi.org/10.1021/ja950391v","title":"Syntheses and Crystal Structures of Disulfide-Bridged Binuclear Ruthenium Compounds: The First UV\u2212Vis, Raman, ESR, and XPS Spectroscopic Characterization of a Valence-Averaged Mixed-Valent RuIIISSRuII Core","display_name":"Syntheses and Crystal Structures of Disulfide-Bridged Binuclear Ruthenium Compounds: The First UV\u2212Vis, Raman, ESR, and XPS Spectroscopic Characterization of a Valence-Averaged Mixed-Valent RuIIISSRuII Core","publication_year":1996,"publication_date":"1996-01-01","ids":{"openalex":"https://openalex.org/W1995064448","doi":"https://doi.org/10.1021/ja950391v","mag":"1995064448"},"language":"en","primary_location":{"id":"doi:10.1021/ja950391v","doi":"https://doi.org/10.1021/ja950391v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja950391v","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5103101661","display_name":"Kazuko Matsumoto","orcid":"https://orcid.org/0000-0003-4377-878X","observed_orcids":["https://orcid.org/0000-0003-4377-878X"]},"institutions":[{"id":"https://openalex.org/I150744194","display_name":"Waseda University","ror":"https://ror.org/00ntfnx83","country_code":"JP","type":"education","lineage":["https://openalex.org/I150744194"]},{"id":"https://openalex.org/I201537933","display_name":"Tohoku University","ror":"https://ror.org/01dq60k83","country_code":"JP","type":"education","lineage":["https://openalex.org/I201537933"]},{"id":"https://openalex.org/I4210110524","display_name":"Nissan (Japan)","ror":"https://ror.org/01nks1c62","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210110524"]},{"id":"https://openalex.org/I4405275670","display_name":"Nissan ARC, Ltd. (Japan)","ror":"https://ror.org/0434z3y25","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405275670"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kazuko Matsumoto","raw_affiliation_strings":["Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan","institution_ids":["https://openalex.org/I150744194","https://openalex.org/I201537933","https://openalex.org/I4210110524","https://openalex.org/I4405275670"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062436020","display_name":"Takaya Matsumoto","orcid":"https://orcid.org/0000-0003-3678-8541","observed_orcids":["https://orcid.org/0000-0003-3678-8541"]},"institutions":[{"id":"https://openalex.org/I150744194","display_name":"Waseda University","ror":"https://ror.org/00ntfnx83","country_code":"JP","type":"education","lineage":["https://openalex.org/I150744194"]},{"id":"https://openalex.org/I201537933","display_name":"Tohoku University","ror":"https://ror.org/01dq60k83","country_code":"JP","type":"education","lineage":["https://openalex.org/I201537933"]},{"id":"https://openalex.org/I4210110524","display_name":"Nissan (Japan)","ror":"https://ror.org/01nks1c62","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210110524"]},{"id":"https://openalex.org/I4405275670","display_name":"Nissan ARC, Ltd. (Japan)","ror":"https://ror.org/0434z3y25","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405275670"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Takaya Matsumoto","raw_affiliation_strings":["Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan","institution_ids":["https://openalex.org/I150744194","https://openalex.org/I201537933","https://openalex.org/I4210110524","https://openalex.org/I4405275670"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5048557783","display_name":"Masaki Kawano","orcid":"https://orcid.org/0000-0001-9886-4226","observed_orcids":["https://orcid.org/0000-0001-9886-4226"]},"institutions":[{"id":"https://openalex.org/I150744194","display_name":"Waseda University","ror":"https://ror.org/00ntfnx83","country_code":"JP","type":"education","lineage":["https://openalex.org/I150744194"]},{"id":"https://openalex.org/I201537933","display_name":"Tohoku University","ror":"https://ror.org/01dq60k83","country_code":"JP","type":"education","lineage":["https://openalex.org/I201537933"]},{"id":"https://openalex.org/I4210110524","display_name":"Nissan (Japan)","ror":"https://ror.org/01nks1c62","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210110524"]},{"id":"https://openalex.org/I4405275670","display_name":"Nissan ARC, Ltd. (Japan)","ror":"https://ror.org/0434z3y25","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405275670"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Masaki Kawano","raw_affiliation_strings":["Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan","institution_ids":["https://openalex.org/I150744194","https://openalex.org/I201537933","https://openalex.org/I4210110524","https://openalex.org/I4405275670"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067442504","display_name":"Hiroshi Ohnuki","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I150744194","display_name":"Waseda University","ror":"https://ror.org/00ntfnx83","country_code":"JP","type":"education","lineage":["https://openalex.org/I150744194"]},{"id":"https://openalex.org/I201537933","display_name":"Tohoku University","ror":"https://ror.org/01dq60k83","country_code":"JP","type":"education","lineage":["https://openalex.org/I201537933"]},{"id":"https://openalex.org/I4210110524","display_name":"Nissan (Japan)","ror":"https://ror.org/01nks1c62","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210110524"]},{"id":"https://openalex.org/I4405275670","display_name":"Nissan ARC, Ltd. (Japan)","ror":"https://ror.org/0434z3y25","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405275670"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Hiroshi Ohnuki","raw_affiliation_strings":["Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan","institution_ids":["https://openalex.org/I150744194","https://openalex.org/I201537933","https://openalex.org/I4210110524","https://openalex.org/I4405275670"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000950866","display_name":"Yushi Shichi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I150744194","display_name":"Waseda University","ror":"https://ror.org/00ntfnx83","country_code":"JP","type":"education","lineage":["https://openalex.org/I150744194"]},{"id":"https://openalex.org/I201537933","display_name":"Tohoku University","ror":"https://ror.org/01dq60k83","country_code":"JP","type":"education","lineage":["https://openalex.org/I201537933"]},{"id":"https://openalex.org/I4210110524","display_name":"Nissan (Japan)","ror":"https://ror.org/01nks1c62","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210110524"]},{"id":"https://openalex.org/I4405275670","display_name":"Nissan ARC, Ltd. (Japan)","ror":"https://ror.org/0434z3y25","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405275670"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yushi Shichi","raw_affiliation_strings":["Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan","institution_ids":["https://openalex.org/I150744194","https://openalex.org/I201537933","https://openalex.org/I4210110524","https://openalex.org/I4405275670"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072810227","display_name":"Toshikazu Nishide","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I150744194","display_name":"Waseda University","ror":"https://ror.org/00ntfnx83","country_code":"JP","type":"education","lineage":["https://openalex.org/I150744194"]},{"id":"https://openalex.org/I201537933","display_name":"Tohoku University","ror":"https://ror.org/01dq60k83","country_code":"JP","type":"education","lineage":["https://openalex.org/I201537933"]},{"id":"https://openalex.org/I4210110524","display_name":"Nissan (Japan)","ror":"https://ror.org/01nks1c62","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210110524"]},{"id":"https://openalex.org/I4405275670","display_name":"Nissan ARC, Ltd. (Japan)","ror":"https://ror.org/0434z3y25","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405275670"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Toshikazu Nishide","raw_affiliation_strings":["Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan","institution_ids":["https://openalex.org/I150744194","https://openalex.org/I201537933","https://openalex.org/I4210110524","https://openalex.org/I4405275670"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5018237556","display_name":"Toshio Sato","orcid":"https://orcid.org/0000-0002-7173-7697","observed_orcids":["https://orcid.org/0000-0002-7173-7697"]},"institutions":[{"id":"https://openalex.org/I150744194","display_name":"Waseda University","ror":"https://ror.org/00ntfnx83","country_code":"JP","type":"education","lineage":["https://openalex.org/I150744194"]},{"id":"https://openalex.org/I201537933","display_name":"Tohoku University","ror":"https://ror.org/01dq60k83","country_code":"JP","type":"education","lineage":["https://openalex.org/I201537933"]},{"id":"https://openalex.org/I4210110524","display_name":"Nissan (Japan)","ror":"https://ror.org/01nks1c62","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210110524"]},{"id":"https://openalex.org/I4405275670","display_name":"Nissan ARC, Ltd. (Japan)","ror":"https://ror.org/0434z3y25","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405275670"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Toshio Sato","raw_affiliation_strings":["Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Chemistry, Waseda University, Tokyo 169, Japan, Nissan ARC Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, Central Engineering Laboratories, Nissan Motor Co. Ltd., 1, Natsushima, Yokosuka, Kanagawa 237, Japan, and Instrumental Analysis Center of Chemistry, Faculty of Science, Tohoku University, Aramaki Aoba, Aoba-ku, Sendai 980, Japan","institution_ids":["https://openalex.org/I150744194","https://openalex.org/I201537933","https://openalex.org/I4210110524","https://openalex.org/I4405275670"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.8675,"has_fulltext":false,"cited_by_count":70,"citation_normalized_percentile":{"value":0.93980547,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"118","issue":"15","first_page":"3597","last_page":"3609"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.25589999556541443,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.25589999556541443,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.21619999408721924,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.17309999465942383,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/mixed-valent-ruthenium","display_name":"mixed-valent ruthenium","score":0.9010000228881836},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5109999775886536},{"id":"https://openalex.org/keywords/resonance-raman-spectroscopy","display_name":"resonance Raman spectroscopy","score":0.9139999747276306},{"id":"https://openalex.org/keywords/electron-spin-resonance","display_name":"electron spin resonance","score":0.5910000205039978},{"id":"https://openalex.org/keywords/x-ray-photoelectron-spectroscopy","display_name":"X-ray photoelectron spectroscopy","score":0.8489999771118164},{"id":"https://openalex.org/keywords/uv-vis-spectroscopy","display_name":"UV-Vis spectroscopy","score":0.6460000276565552},{"id":"https://openalex.org/keywords/pi-pi-transition","display_name":"\u03c0\u2192\u03c0* transitions","score":0.5699999928474426}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9201987981796265},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.7966845035552979},{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.7261878848075867},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6571296453475952},{"id":"https://openalex.org/C168900304","wikidata":"https://www.wikidata.org/wiki/Q171407","display_name":"Valence (chemistry)","level":2,"score":0.5813778042793274},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.5522864460945129},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.5386092662811279},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.4830970764160156},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.47176840901374817},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.434232622385025},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.1405971348285675},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.12704089283943176},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C185544564","wikidata":"https://www.wikidata.org/wiki/Q81197","display_name":"Nuclear physics","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/ja950391v","doi":"https://doi.org/10.1021/ja950391v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja950391v","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmh:oai:irdb.nii.ac.jp:00897:0005215402","doi":null,"is_oa":false,"landing_page_url":"http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100865279","pdf_url":null,"source":{"id":"https://openalex.org/S7407056385","display_name":"Institutional Repositories DataBase (IRDB)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I184597095","host_organization_name":"National Institute of Informatics","host_organization_lineage":["https://openalex.org/I184597095"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal article"},{"id":"pmh:oai:t2r2.star.titech.ac.jp:50604070","doi":null,"is_oa":false,"landing_page_url":"http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100865279","pdf_url":null,"source":{"id":"https://openalex.org/S4377196385","display_name":"Tokyo Tech Research Repository (Tokyo Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I114531698","host_organization_name":"Tokyo Institute of Technology","host_organization_lineage":["https://openalex.org/I114531698"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":52,"referenced_works":["https://openalex.org/W1515004291","https://openalex.org/W1963824403","https://openalex.org/W1977627299","https://openalex.org/W1979013068","https://openalex.org/W1982471247","https://openalex.org/W1987855341","https://openalex.org/W1989484997","https://openalex.org/W1995287303","https://openalex.org/W1995531586","https://openalex.org/W1995574126","https://openalex.org/W1996316701","https://openalex.org/W1997224583","https://openalex.org/W1999895709","https://openalex.org/W2004186107","https://openalex.org/W2006512040","https://openalex.org/W2007673706","https://openalex.org/W2013469813","https://openalex.org/W2014520139","https://openalex.org/W2015935433","https://openalex.org/W2017854765","https://openalex.org/W2018489787","https://openalex.org/W2019069822","https://openalex.org/W2019117044","https://openalex.org/W2031246600","https://openalex.org/W2037262965","https://openalex.org/W2041436151","https://openalex.org/W2042064080","https://openalex.org/W2043002533","https://openalex.org/W2046409025","https://openalex.org/W2046952811","https://openalex.org/W2048158093","https://openalex.org/W2052072645","https://openalex.org/W2059401704","https://openalex.org/W2061724372","https://openalex.org/W2065076380","https://openalex.org/W2065417227","https://openalex.org/W2070728756","https://openalex.org/W2072894575","https://openalex.org/W2080898182","https://openalex.org/W2084259059","https://openalex.org/W2084485339","https://openalex.org/W2164477621","https://openalex.org/W2259495959","https://openalex.org/W2317341346","https://openalex.org/W2341189802","https://openalex.org/W2497007159","https://openalex.org/W2949127766","https://openalex.org/W2950681919","https://openalex.org/W2950862051","https://openalex.org/W3004922931","https://openalex.org/W3004945875","https://openalex.org/W4211218496"],"related_works":["https://openalex.org/W2065417227","https://openalex.org/W2898680673","https://openalex.org/W1973385425","https://openalex.org/W7208469641","https://openalex.org/W2048759651","https://openalex.org/W1967879395","https://openalex.org/W2014520139","https://openalex.org/W432935260","https://openalex.org/W2076207715","https://openalex.org/W2381450704"],"abstract_inverted_index":{"Disulfide-bridged":[0],"binuclear":[1,304],"ruthenium":[2],"complexes,":[3],"[{RuCl(P(OMe)":[4,18],"3":[5,19,27,29,39,41,43,57,59,76,78,80,291],")":[6,20,30,44,60,81,386],"2":[7,9,11,13,21,23,25,31,45,47,49,61,63,65,67,82,84,86,117,119,127,286,384],"}":[8,46,62,83],"(\u03bc-Cl)":[10,64,116],"(\u03bc-S":[12,24,48,66,85,118],")]":[14,50,68,87],"(":[15,34,52,70,89],"1":[16,282],"),":[17,37,55,73,92],"}(\u03bc-Cl)":[22],"){Ru(CH":[26],"CN)(P(OMe)":[28,58],"]":[32],"+":[33,36],"[2]":[35,105,222],"[{Ru(CH":[38,56,75],"CN)":[40,77],"(P(OMe)":[42,79],"3+":[51,54,141,154,167,203,226,241,275,354,393,429],"[3]":[53,140,153,166,202,225,240,274,353,392,428],"2+":[69,72,109],"[4]":[71,108],"and":[74,96,107,142,204,224,227,265,289,303,367,445],"4+":[88,91,144,163,206,420],"[5]":[90,143,162,205,419],"have":[93,100,110,145,189],"been":[94,101],"synthesized,":[95],"their":[97],"crystal":[98],"structures":[99],"solved.":[102],"Compounds":[103,139],"1,":[104,221],"+,":[106,223],"a":[111,136,146,157,173,178,208,243,277,326,338,433],"triply":[112],"bridged":[113,148],"Ru":[114,133,374],"III":[115,121,441],")Ru":[120],"core,":[122,151,180],"in":[123,135,400,414],"which":[124,197,336],"the":[125,131,169,187,212,258,312,318,341,345,360,365,370,401,409,415,443],"S":[126],"2-":[128,385],"ligand":[129],"bridges":[130],"two":[132],"atoms":[134],"cis":[137,234],"configuration.":[138],"singly":[147],"trans":[149,214],"-RuSSRu":[150,215,235],"whereby":[152],"corresponds":[155],"to":[156,262,300,404],"one-electron":[158,416],"reduced":[159],"form":[160],"of":[161,172,211,220,273,311,317,320,332,340,344,352,359,364,442],".":[164,421],"Compound":[165,391],"is":[168,183,296,337,430],"first":[170],"example":[171],"well-characterized":[174],"mixed-valent":[175,434],"compound":[176,418],"with":[177,229,280,307,436],"trans-MSSM":[179],"where":[181],"M":[182],"any":[184,358,397],"metal.":[185],"All":[186],"compounds":[188,236,306],"intense":[190],"absorption":[191],"bands":[192],"at":[193],"around":[194],"700":[195],"nm,":[196,255],"can":[198],"be":[199],"explained":[200],"for":[201,233],"as":[207,432],"\u03c0\u2212\u03c0*":[209],"transition":[210],"distinct":[213],"core.":[216],"Resonance":[217],"Raman":[218,246],"spectroscopy":[219],"comparison":[228],"several":[230],"literature":[231],"values":[232,314],"show":[237,260],"that":[238],"only":[239],"exhibits":[242],"strong":[244,261],"\u03bd(S\u2212S)":[245,268],"band,":[247],"when":[248],"excited":[249],"by":[250,315],"\u03bb":[251],"e":[252],"=":[253,283,287,292],"647.1":[254],"whereas":[256],"all":[257],"others":[259],"medium":[263],"\u03bd(Ru\u2212S)":[264],"very":[266,327],"weak":[267],"bands.":[269],"The":[270,348],"ESR":[271],"spectrum":[272,351],"shows":[276],"rhombic":[278],"signal":[279],"g":[281,285,290,313],"2.12,":[284],"2.05,":[288],"1.995.":[293],"This":[294],"anisotropy":[295],"unusually":[297],"small,":[298],"compared":[299],"most":[301],"mononuclear":[302],"Ru(III)":[305,368],"various":[308],"ligands.":[309],"Analysis":[310],"use":[316],"matrix":[319],"spin\u2212orbit":[321,329],"coupling":[322,330],"Hamiltonian":[323],"has":[324],"revealed":[325],"small":[328],"constant":[331],"100":[333],"cm":[334],"-1,":[335],"result":[339],"extensive":[342],"covalency":[343],"metal\u2212disulfide":[346],"bond.":[347],"X-ray":[349],"photoelectron":[350],"did":[355],"not":[356,395],"give":[357,396],"expected":[361],"double":[362],"peaks":[363,372],"Ru(II)":[366],"components;":[369],"observed":[371,413],"are":[373,424],"3d":[375],"5/2":[376],"281.0":[377],"eV,":[378,382],"3P":[379],"3/2":[380,388],"462.4":[381],"S(S":[383],"2P":[387],"162.7":[389],"eV.":[390],"does":[394],"intervalence-transition":[398],"band":[399,411],"longer-wavelength":[402],"visible":[403],"near-IR":[405],"region,":[406],"other":[407],"than":[408],"UV\u2212vis":[410],"similarly":[412],"oxidized":[417],"These":[422],"characteristics":[423],"reasonably":[425],"understood,":[426],"if":[427],"regarded":[431],"complex":[435],"valence-averaged":[437],"ground":[438],"state":[439],"(class":[440],"Robin":[444],"Day":[446],"classification).":[447]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}
