{"id":"https://openalex.org/W1993300767","doi":"https://doi.org/10.1021/jp036327e","title":"Kinetics and Growth Mechanism of Electrodeposited Palladium Nanocrystallites","display_name":"Kinetics and Growth Mechanism of Electrodeposited Palladium Nanocrystallites","publication_year":2003,"publication_date":"2003-12-10","ids":{"openalex":"https://openalex.org/W1993300767","doi":"https://doi.org/10.1021/jp036327e","mag":"1993300767"},"language":"en","primary_location":{"id":"doi:10.1021/jp036327e","doi":"https://doi.org/10.1021/jp036327e","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp036327e","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://stars.library.ucf.edu/facultybib2000/4213","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5068941744","display_name":"Debasis Bera","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Debasis Bera","raw_affiliation_strings":["Surface Engineering and Nanotechnology Facility (SNF), Advanced Materials Processing Center (AMPAC) and Mechanical, Materials and Aerospace Engineering (MMAE), University of Central Florida, Eng. 1, Room #381, 4000 Central Florida Boulevard, Orlando, Florida 32816"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Surface Engineering and Nanotechnology Facility (SNF), Advanced Materials Processing Center (AMPAC) and Mechanical, Materials and Aerospace Engineering (MMAE), University of Central Florida, Eng. 1, Room #381, 4000 Central Florida Boulevard, Orlando, Florida 32816","institution_ids":["https://openalex.org/I106165777"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111636302","display_name":"Suresh C. Kuiry","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Suresh C. Kuiry","raw_affiliation_strings":["Surface Engineering and Nanotechnology Facility (SNF), Advanced Materials Processing Center (AMPAC) and Mechanical, Materials and Aerospace Engineering (MMAE), University of Central Florida, Eng. 1, Room #381, 4000 Central Florida Boulevard, Orlando, Florida 32816"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Surface Engineering and Nanotechnology Facility (SNF), Advanced Materials Processing Center (AMPAC) and Mechanical, Materials and Aerospace Engineering (MMAE), University of Central Florida, Eng. 1, Room #381, 4000 Central Florida Boulevard, Orlando, Florida 32816","institution_ids":["https://openalex.org/I106165777"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5026168431","display_name":"Sudipta Seal","orcid":"https://orcid.org/0000-0002-0963-3344","observed_orcids":["https://orcid.org/0000-0002-0963-3344"]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Sudipta Seal","raw_affiliation_strings":["Surface Engineering and Nanotechnology Facility (SNF), Advanced Materials Processing Center (AMPAC) and Mechanical, Materials and Aerospace Engineering (MMAE), University of Central Florida, Eng. 1, Room #381, 4000 Central Florida Boulevard, Orlando, Florida 32816"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Surface Engineering and Nanotechnology Facility (SNF), Advanced Materials Processing Center (AMPAC) and Mechanical, Materials and Aerospace Engineering (MMAE), University of Central Florida, Eng. 1, Room #381, 4000 Central Florida Boulevard, Orlando, Florida 32816","institution_ids":["https://openalex.org/I106165777"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5026168431"],"corresponding_institution_ids":["https://openalex.org/I106165777"],"apc_list":null,"apc_paid":null,"fwci":3.833,"has_fulltext":false,"cited_by_count":55,"citation_normalized_percentile":{"value":0.92670128,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"108","issue":"2","first_page":"556","last_page":"562"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11200","display_name":"Electrodeposition and Electroless Coatings","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11200","display_name":"Electrodeposition and Electroless Coatings","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/palladium-electrodeposition","display_name":"palladium electrodeposition","score":0.921999990940094},{"id":"https://openalex.org/keywords/electrodeposition-kinetics","display_name":"electrodeposition kinetics","score":0.8759999871253967},{"id":"https://openalex.org/keywords/parabolic-rate-law","display_name":"parabolic rate law","score":0.8550000190734863},{"id":"https://openalex.org/keywords/three-dimensional-growth","display_name":"three-dimensional growth","score":0.7049999833106995},{"id":"https://openalex.org/keywords/nucleation-density","display_name":"nucleation density","score":0.8130000233650208},{"id":"https://openalex.org/keywords/grain-boundary-nucleation","display_name":"grain boundary nucleation","score":0.7620000243186951},{"id":"https://openalex.org/keywords/crystallographic-texture","display_name":"crystallographic texture","score":0.8109999895095825},{"id":"https://openalex.org/keywords/preferential-growth","display_name":"preferential growth","score":0.4959999918937683},{"id":"https://openalex.org/keywords/diffusion-limitation","display_name":"diffusion limitation","score":0.6480000019073486}],"concepts":[{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.9757261276245117},{"id":"https://openalex.org/C61048295","wikidata":"https://www.wikidata.org/wiki/Q909022","display_name":"Nucleation","level":2,"score":0.7717902660369873},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7430540323257446},{"id":"https://openalex.org/C51807945","wikidata":"https://www.wikidata.org/wiki/Q3503392","display_name":"Electroplating","level":3,"score":0.5864763259887695},{"id":"https://openalex.org/C2781195486","wikidata":"https://www.wikidata.org/wiki/Q289436","display_name":"Texture (cosmology)","level":3,"score":0.4925892949104309},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4838367998600006},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.47303053736686707},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.4603419601917267},{"id":"https://openalex.org/C175854130","wikidata":"https://www.wikidata.org/wiki/Q98276914","display_name":"Nanocrystal","level":2,"score":0.42839616537094116},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.23034003376960754},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.17874199151992798},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.16701486706733704},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.08809331059455872},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.06632763147354126},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C115961682","wikidata":"https://www.wikidata.org/wiki/Q860623","display_name":"Image (mathematics)","level":2,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C154945302","wikidata":"https://www.wikidata.org/wiki/Q11660","display_name":"Artificial intelligence","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/jp036327e","doi":"https://doi.org/10.1021/jp036327e","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp036327e","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},{"id":"pmh:oai:stars.library.ucf.edu:facultybib2000-5212","doi":null,"is_oa":true,"landing_page_url":"https://stars.library.ucf.edu/facultybib2000/4213","pdf_url":null,"source":{"id":"https://openalex.org/S4210172555","display_name":"Journal of International Crisis and Risk Communication Research","issn_l":"2576-0017","issn":["2576-0017","2576-0025"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","vabb-shw"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Faculty Bibliography 2000s","raw_type":"text"},{"id":"pmh:oai:stars.library.ucf.edu:scopus2000-6314","doi":null,"is_oa":true,"landing_page_url":"https://stars.library.ucf.edu/scopus2000/5315","pdf_url":null,"source":{"id":"https://openalex.org/S4210172555","display_name":"Journal of International Crisis and Risk Communication Research","issn_l":"2576-0017","issn":["2576-0017","2576-0025"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","vabb-shw"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Scopus Export 2000s","raw_type":"text"}],"best_oa_location":{"id":"pmh:oai:stars.library.ucf.edu:facultybib2000-5212","doi":null,"is_oa":true,"landing_page_url":"https://stars.library.ucf.edu/facultybib2000/4213","pdf_url":null,"source":{"id":"https://openalex.org/S4210172555","display_name":"Journal of International Crisis and Risk Communication Research","issn_l":"2576-0017","issn":["2576-0017","2576-0025"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","vabb-shw"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Faculty Bibliography 2000s","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":36,"referenced_works":["https://openalex.org/W1008895281","https://openalex.org/W1522958773","https://openalex.org/W1557681670","https://openalex.org/W1783686700","https://openalex.org/W1965122089","https://openalex.org/W1978738006","https://openalex.org/W1981548767","https://openalex.org/W1984314119","https://openalex.org/W1985997303","https://openalex.org/W1986104011","https://openalex.org/W1986845785","https://openalex.org/W2002052849","https://openalex.org/W2004225529","https://openalex.org/W2007652898","https://openalex.org/W2012793062","https://openalex.org/W2022792052","https://openalex.org/W2023720616","https://openalex.org/W2028100341","https://openalex.org/W2029849672","https://openalex.org/W2036141453","https://openalex.org/W2042071294","https://openalex.org/W2046933034","https://openalex.org/W2047137396","https://openalex.org/W2055752363","https://openalex.org/W2058642931","https://openalex.org/W2059207316","https://openalex.org/W2060205815","https://openalex.org/W2069810795","https://openalex.org/W2081399755","https://openalex.org/W2082349588","https://openalex.org/W2092102983","https://openalex.org/W2095487543","https://openalex.org/W2161078578","https://openalex.org/W2313227266","https://openalex.org/W2321996886","https://openalex.org/W2609724571"],"related_works":["https://openalex.org/W2055476013","https://openalex.org/W4252549091","https://openalex.org/W2057969550","https://openalex.org/W2031330403","https://openalex.org/W4387418246","https://openalex.org/W1986845785","https://openalex.org/W3025115762","https://openalex.org/W2623344047","https://openalex.org/W1748174457","https://openalex.org/W2910409069"],"abstract_inverted_index":{"Palladium":[0],"particles":[1,31,92,133,147],"have":[2,32,93],"been":[3,33,37,94],"electrodeposited":[4,90,131,145],"on":[5,126],"AISI":[6],"316":[7],"stainless":[8],"steel":[9,127],"substrate":[10],"from":[11,187],"aqueous":[12],"solution":[13,189],"of":[14,19,26,42,44,52,67,73,76,88,106,135,138,143,155,164,172,181],"palladium":[15,30,45,68,91,108,132,146,174,183],"chloride.":[16],"The":[17,80,104,129,140,162],"kinetics":[18,41],"the":[20,40,64,74,77,89,107,112,123,144,152,165,170,173,179,192],"electrodeposition":[21,43],"process":[22],"and":[23,55,86,102],"growth":[24,105,154,171],"mechanism":[25],"such":[27,156],"three-dimensionally":[28],"grown":[29],"studied.":[34],"It":[35,59],"has":[36],"found":[38,116],"that":[39,63,121,169],"follows":[46],"parabolic":[47],"law,":[48],"which":[49],"indicates":[50],"involvement":[51],"instantaneous":[53],"nucleation":[54,65],"subsequent":[56],"three-dimensional":[57],"growth.":[58],"was":[60,70,115,148,176],"also":[61],"observed":[62],"density":[66],"electrodeposits":[69,175],"a":[71,136],"function":[72],"nature":[75],"electrode":[78,193],"substrate.":[79,128],"structure,":[81],"morphology,":[82],"texture,":[83],"chemical":[84],"state,":[85],"composition":[87],"characterized":[95],"using":[96],"SEM,":[97],"TEM,":[98],"XPS,":[99],"EDS,":[100],"EBSD,":[101],"OIM.":[103],"nuclei":[109],"situated":[110],"at":[111,122],"grain":[113,124],"interior":[114],"to":[117,151,190],"be":[118],"more":[119],"than":[120],"boundaries":[125],"micron-size":[130],"consisted":[134],"number":[137],"nanocrytallites.":[139],"surface":[141],"morphology":[142],"uneven":[149],"due":[150],"preferential":[153],"nanocrystallites":[157],"in":[158],"certain":[159],"crystallographic":[160],"directions.":[161],"results":[163],"present":[166],"investigation":[167],"indicate":[168],"limited":[177],"by":[178],"diffusivity":[180],"bulky":[182],"tetrachloro":[184],"square-planar":[185],"complex":[186],"bulk":[188],"near":[191],"surface.":[194]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":3},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}