{"id":"https://openalex.org/W1992862869","doi":"https://doi.org/10.1081/amp-200042132","title":"KINETICS AND MECHANISM OF ESTERIFICATION OF MONOEPOXIES","display_name":"KINETICS AND MECHANISM OF ESTERIFICATION OF MONOEPOXIES","publication_year":2005,"publication_date":"2005-03-16","ids":{"openalex":"https://openalex.org/W1992862869","doi":"https://doi.org/10.1081/amp-200042132","mag":"1992862869"},"language":"en","primary_location":{"id":"doi:10.1081/amp-200042132","doi":"https://doi.org/10.1081/amp-200042132","is_oa":false,"landing_page_url":"https://doi.org/10.1081/amp-200042132","pdf_url":null,"source":{"id":"https://openalex.org/S166620827","display_name":"Materials and Manufacturing Processes","issn_l":"1042-6914","issn":["1042-6914","1532-2475"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Materials and Manufacturing Processes","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5043134941","display_name":"Neelam Pal","orcid":"https://orcid.org/0000-0001-9567-796X","observed_orcids":["https://orcid.org/0000-0001-9567-796X"]},"institutions":[{"id":"https://openalex.org/I4210090456","display_name":"Harcourt Butler Technical University","ror":"https://ror.org/0181a8730","country_code":"IN","type":"education","lineage":["https://openalex.org/I4210090456"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Neelam Pal","raw_affiliation_strings":["Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India","institution_ids":["https://openalex.org/I4210090456"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077671282","display_name":"Akanksha Srivastava","orcid":"https://orcid.org/0000-0002-7013-2581","observed_orcids":["https://orcid.org/0000-0002-7013-2581"]},"institutions":[{"id":"https://openalex.org/I4210090456","display_name":"Harcourt Butler Technical University","ror":"https://ror.org/0181a8730","country_code":"IN","type":"education","lineage":["https://openalex.org/I4210090456"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Akanksha Srivastava","raw_affiliation_strings":["Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India","institution_ids":["https://openalex.org/I4210090456"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028927562","display_name":"Sudha Agrawal","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090456","display_name":"Harcourt Butler Technical University","ror":"https://ror.org/0181a8730","country_code":"IN","type":"education","lineage":["https://openalex.org/I4210090456"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Sudha Agrawal","raw_affiliation_strings":["Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India","institution_ids":["https://openalex.org/I4210090456"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5027163905","display_name":"J. S. P.","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090456","display_name":"Harcourt Butler Technical University","ror":"https://ror.org/0181a8730","country_code":"IN","type":"education","lineage":["https://openalex.org/I4210090456"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"J.S.P. Rai","raw_affiliation_strings":["Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Plastic Technology, Harcourt Butler Technological Institute, Kanpur, India","institution_ids":["https://openalex.org/I4210090456"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5027163905"],"corresponding_institution_ids":["https://openalex.org/I4210090456"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":22,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"20","issue":"2","first_page":"317","last_page":"327"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.36059999465942383,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.36059999465942383,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.288100004196167,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11145","display_name":"Epoxy Resin Curing Processes","score":0.17319999635219574,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/esterification","display_name":"esterification","score":0.9390000104904175},{"id":"https://openalex.org/keywords/glycidyl-ethers","display_name":"glycidyl ethers","score":0.9319999814033508},{"id":"https://openalex.org/keywords/acrylic-acid","display_name":"acrylic acid","score":0.8090000152587891},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.9309999942779541},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.7480000257492065},{"id":"https://openalex.org/keywords/activation-energy","display_name":"activation energy","score":0.9629999995231628},{"id":"https://openalex.org/keywords/arrhenius-parameters","display_name":"Arrhenius parameters","score":0.6570000052452087},{"id":"https://openalex.org/keywords/inductive-effects","display_name":"inductive effects","score":0.7749999761581421},{"id":"https://openalex.org/keywords/reaction-thermodynamics","display_name":"reaction thermodynamics","score":0.6079999804496765},{"id":"https://openalex.org/keywords/transition-state","display_name":"transition state","score":0.7279999852180481}],"concepts":[{"id":"https://openalex.org/C95121573","wikidata":"https://www.wikidata.org/wiki/Q190474","display_name":"Activation energy","level":2,"score":0.7803399562835693},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.7683402299880981},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.7130330801010132},{"id":"https://openalex.org/C86183883","wikidata":"https://www.wikidata.org/wiki/Q507505","display_name":"Arrhenius equation","level":3,"score":0.6763851046562195},{"id":"https://openalex.org/C175804951","wikidata":"https://www.wikidata.org/wiki/Q3268188","display_name":"Diluent","level":2,"score":0.5696202516555786},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.5364419221878052},{"id":"https://openalex.org/C13723534","wikidata":"https://www.wikidata.org/wiki/Q367131","display_name":"Entropy of activation","level":4,"score":0.5285072922706604},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.5093430280685425},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.5039722323417664},{"id":"https://openalex.org/C2777247709","wikidata":"https://www.wikidata.org/wiki/Q115493","display_name":"Triphenylphosphine","level":3,"score":0.4857495427131653},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4843062460422516},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.4759504497051239},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.4748033583164215},{"id":"https://openalex.org/C86369940","wikidata":"https://www.wikidata.org/wiki/Q2421183","display_name":"Activated complex","level":4,"score":0.41486412286758423},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.39618316292762756},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.38876962661743164},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.29554709792137146},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1081/amp-200042132","doi":"https://doi.org/10.1081/amp-200042132","is_oa":false,"landing_page_url":"https://doi.org/10.1081/amp-200042132","pdf_url":null,"source":{"id":"https://openalex.org/S166620827","display_name":"Materials and Manufacturing Processes","issn_l":"1042-6914","issn":["1042-6914","1532-2475"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Materials and Manufacturing Processes","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":16,"referenced_works":["https://openalex.org/W1933627589","https://openalex.org/W1969370347","https://openalex.org/W1986938663","https://openalex.org/W2003708643","https://openalex.org/W2017481305","https://openalex.org/W2069108920","https://openalex.org/W2072977946","https://openalex.org/W2073897815","https://openalex.org/W2075793373","https://openalex.org/W2076992271","https://openalex.org/W2082702247","https://openalex.org/W2083170658","https://openalex.org/W2086644915","https://openalex.org/W2101398857","https://openalex.org/W2162814274","https://openalex.org/W2940903866"],"related_works":["https://openalex.org/W2035871943","https://openalex.org/W2046808871","https://openalex.org/W2057711385","https://openalex.org/W2537283564","https://openalex.org/W2110917593","https://openalex.org/W2103488954","https://openalex.org/W2008094217","https://openalex.org/W7167644638","https://openalex.org/W2364890140","https://openalex.org/W4249634758"],"abstract_inverted_index":{"The":[0,39,61,84,95],"esterification":[1,66],"of":[2,16,41,56,64,67],"monoepoxy":[3,69],"diluents":[4],"(phenyl,":[5],"cresyl,":[6],"and":[7,11,31,34,58,77,97,107,116,130],"butyl":[8,59],"glycidyl":[9],"ethers)":[10],"acrylic":[12],"acid":[13],"in":[14,119],"presence":[15],"triphenylphosphine":[17],"as":[18,71],"catalyst":[19],"was":[20,44,114],"performed":[21],"at":[22],"70":[23],"\u25cb,":[24,26,28,30],"75":[25],"80":[27],"85":[29],"90":[32],"\u25cbC,":[33],"it":[35],"followed":[36],"first-order":[37],"kinetics.":[38],"reactivity":[40],"aromatic":[42],"monoepoxies":[43],"found":[45,89],"to":[46,52,81,90],"be":[47],"higher":[48],"than":[49],"aliphatic,":[50],"due":[51],"the":[53,65,68,92,112],"inductive":[54],"effect":[55],"phenyl":[57],"groups.":[60],"activation":[62,101],"energy":[63,109],"increases":[70],"Pv":[72],"<":[73,75],"Cv":[74],"Bv":[76],"varies":[78],"from":[79],"67":[80],"82":[82],"KJ/mole.":[83],"specific":[85],"rate":[86],"constants":[87],"were":[88],"obey":[91],"Arrhenius":[93],"expression.":[94],"kinetic":[96],"thermodynamic":[98],"parameters":[99],"viz.,":[100],"energy,":[102],"frequency":[103],"factor,":[104],"entropy,":[105],"enthalpy,":[106],"free":[108],"revealed":[110],"that":[111],"reaction":[113],"spontaneous":[115],"irreversible,":[117],"resulting":[118],"a":[120],"highly":[121],"ordered,":[122],"activated":[123],"complex.":[124],"A":[125],"suitable":[126],"mechanism":[127],"is":[128],"proposed":[129],"discussed.":[131]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":2}],"updated_date":"2026-10-05T09:50:58.205359","created_date":"2016-06-24T00:00:00"}