{"id":"https://openalex.org/W1992792017","doi":"https://doi.org/10.1063/1.465907","title":"Vibrational energy transfer among adsorbate modes: Picosecond dynamics on stepped H/Si(111)","display_name":"Vibrational energy transfer among adsorbate modes: Picosecond dynamics on stepped H/Si(111)","publication_year":1993,"publication_date":"1993-10-15","ids":{"openalex":"https://openalex.org/W1992792017","doi":"https://doi.org/10.1063/1.465907","mag":"1992792017"},"language":"en","primary_location":{"id":"doi:10.1063/1.465907","doi":"https://doi.org/10.1063/1.465907","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.465907","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5012347848","display_name":"Klaus Kuhnke","orcid":"https://orcid.org/0000-0001-9981-1732","observed_orcids":["https://orcid.org/0000-0001-9981-1732"]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]},{"id":"https://openalex.org/I5124864","display_name":"\u00c9cole Polytechnique F\u00e9d\u00e9rale de Lausanne","ror":"https://ror.org/02s376052","country_code":"CH","type":"education","lineage":["https://openalex.org/I2799323385","https://openalex.org/I5124864"]}],"countries":["CH","US"],"is_corresponding":false,"raw_author_name":"K. Kuhnke","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974","Lucent","Swiss Federal Institute of Technology Lausanne"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]},{"raw_affiliation_string":"Lucent","institution_ids":[]},{"raw_affiliation_string":"Swiss Federal Institute of Technology Lausanne","institution_ids":["https://openalex.org/I5124864"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113496088","display_name":"M. Morin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]},{"id":"https://openalex.org/I153718931","display_name":"University of Ottawa","ror":"https://ror.org/03c4mmv16","country_code":"CA","type":"education","lineage":["https://openalex.org/I153718931"]}],"countries":["CA","US"],"is_corresponding":false,"raw_author_name":"M. Morin","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974","Lucent","University of Ottawa"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]},{"raw_affiliation_string":"Lucent","institution_ids":[]},{"raw_affiliation_string":"University of Ottawa","institution_ids":["https://openalex.org/I153718931"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101434744","display_name":"P. Jakob","orcid":"https://orcid.org/0000-0001-6478-309X","observed_orcids":["https://orcid.org/0000-0001-6478-309X"]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]},{"id":"https://openalex.org/I62916508","display_name":"Technical University of Munich","ror":"https://ror.org/02kkvpp62","country_code":"DE","type":"education","lineage":["https://openalex.org/I62916508"]}],"countries":["DE","US"],"is_corresponding":false,"raw_author_name":"P. Jakob","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974","Lucent","Technical University of Munich"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]},{"raw_affiliation_string":"Lucent","institution_ids":[]},{"raw_affiliation_string":"Technical University of Munich","institution_ids":["https://openalex.org/I62916508"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036054425","display_name":"Nicholas J. Levinos","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]},{"id":"https://openalex.org/I4387152956","display_name":"Alcatel-Lucent (France)","ror":"https://ror.org/024850w61","country_code":"FR","type":"company","lineage":["https://openalex.org/I2738502077","https://openalex.org/I4210149358","https://openalex.org/I4387152956"]}],"countries":["FR","US"],"is_corresponding":false,"raw_author_name":"N. J. Levinos","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974","Alcatel-Lucent"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]},{"raw_affiliation_string":"Alcatel-Lucent","institution_ids":["https://openalex.org/I4387152956"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051239060","display_name":"Yves Jean Chabal","orcid":"https://orcid.org/0000-0002-6435-0347","observed_orcids":["https://orcid.org/0000-0002-6435-0347"]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]},{"id":"https://openalex.org/I4387152956","display_name":"Alcatel-Lucent (France)","ror":"https://ror.org/024850w61","country_code":"FR","type":"company","lineage":["https://openalex.org/I2738502077","https://openalex.org/I4210149358","https://openalex.org/I4387152956"]}],"countries":["FR","US"],"is_corresponding":false,"raw_author_name":"Y. J. Chabal","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974","Alcatel-Lucent"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]},{"raw_affiliation_string":"Alcatel-Lucent","institution_ids":["https://openalex.org/I4387152956"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111405196","display_name":"Alex L. Harris","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1283103587","display_name":"AT&T (United States)","ror":"https://ror.org/02bbd5539","country_code":"US","type":"company","lineage":["https://openalex.org/I1283103587"]},{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"A. L. Harris","raw_affiliation_strings":["AT&T Bell Laboratories, Murray Hill, New Jersey 07974","[Brookhaven National Laboratory]"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"AT&T Bell Laboratories, Murray Hill, New Jersey 07974","institution_ids":["https://openalex.org/I1283103587"]},{"raw_affiliation_string":"[Brookhaven National Laboratory]","institution_ids":["https://openalex.org/I200870766"]}]}],"institutions":[],"countries_distinct_count":5,"institutions_distinct_count":6,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":4.4201,"has_fulltext":false,"cited_by_count":64,"citation_normalized_percentile":{"value":0.95117796,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"99","issue":"8","first_page":"6114","last_page":"6125"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.6518999934196472,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.6518999934196472,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13531","display_name":"Surface and Thin Film Phenomena","score":0.28760001063346863,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10566","display_name":"Laser-Matter Interactions and Applications","score":0.010499999858438969,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/vibrational-energy-transfer","display_name":"vibrational energy transfer","score":0.8880000114440918},{"id":"https://openalex.org/keywords/si-h-stretching-mode","display_name":"Si-H stretching mode","score":0.8029999732971191},{"id":"https://openalex.org/keywords/hydrogen-terminated-si-111","display_name":"hydrogen-terminated Si(111)","score":0.8519999980926514},{"id":"https://openalex.org/keywords/dipole-dipole-interaction","display_name":"dipole-dipole interaction","score":0.8600000143051147},{"id":"https://openalex.org/keywords/picosecond-infrared-spectroscopy","display_name":"picosecond infrared spectroscopy","score":0.6660000085830688},{"id":"https://openalex.org/keywords/sum-frequency-generation","display_name":"sum-frequency generation","score":0.9210000038146973}],"concepts":[{"id":"https://openalex.org/C55005982","wikidata":"https://www.wikidata.org/wiki/Q3902709","display_name":"Picosecond","level":3,"score":0.7312919497489929},{"id":"https://openalex.org/C121349320","wikidata":"https://www.wikidata.org/wiki/Q285851","display_name":"Vicinal","level":2,"score":0.6618549823760986},{"id":"https://openalex.org/C2776638177","wikidata":"https://www.wikidata.org/wiki/Q838625","display_name":"Terrace (agriculture)","level":2,"score":0.5861624479293823},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5519827008247375},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.5507166385650635},{"id":"https://openalex.org/C173523689","wikidata":"https://www.wikidata.org/wiki/Q215589","display_name":"Dipole","level":2,"score":0.5351546406745911},{"id":"https://openalex.org/C84662259","wikidata":"https://www.wikidata.org/wiki/Q3935813","display_name":"Vibrational energy relaxation","level":3,"score":0.5351003408432007},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.49970197677612305},{"id":"https://openalex.org/C158355884","wikidata":"https://www.wikidata.org/wiki/Q11388","display_name":"Infrared","level":2,"score":0.49227967858314514},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.43377065658569336},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.405988872051239},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.36718806624412537},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.14922979474067688},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.14796289801597595},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.07418617606163025},{"id":"https://openalex.org/C95457728","wikidata":"https://www.wikidata.org/wiki/Q309","display_name":"History","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C520434653","wikidata":"https://www.wikidata.org/wiki/Q38867","display_name":"Laser","level":2,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C166957645","wikidata":"https://www.wikidata.org/wiki/Q23498","display_name":"Archaeology","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.465907","doi":"https://doi.org/10.1063/1.465907","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.465907","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320308269","display_name":"Alexander von Humboldt-Stiftung","ror":"https://ror.org/012kf4317"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W1965372456","https://openalex.org/W1978231175","https://openalex.org/W1980117816","https://openalex.org/W1985474014","https://openalex.org/W1987869326","https://openalex.org/W1992942529","https://openalex.org/W1996668330","https://openalex.org/W1997546949","https://openalex.org/W2031316117","https://openalex.org/W2046682151","https://openalex.org/W2048939859","https://openalex.org/W2049964613","https://openalex.org/W2050768366","https://openalex.org/W2051811093","https://openalex.org/W2066954452","https://openalex.org/W2077986272","https://openalex.org/W2078290379","https://openalex.org/W2078345212","https://openalex.org/W2124428607"],"related_works":["https://openalex.org/W2138194510","https://openalex.org/W2088002982","https://openalex.org/W1978231175","https://openalex.org/W1966023440","https://openalex.org/W2085154362","https://openalex.org/W2021270906","https://openalex.org/W4250743221","https://openalex.org/W2514098735","https://openalex.org/W2024199544","https://openalex.org/W2140327442"],"abstract_inverted_index":{"Direct":[0],"measurements":[1],"of":[2,73,79,125,147,209,239,247,251],"interadsorbate":[3,98],"vibrational":[4,29,40],"energy":[5,52,99,104,114,127,152,170],"flow":[6,115],"among":[7],"Si\u2013H":[8,150,176],"stretching":[9],"modes":[10,41,233],"on":[11,93],"hydrogen-terminated,":[12],"stepped":[13],"vicinal":[14],"H/Si(111)":[15],"surfaces":[16,55,95],"are":[17,42,56,89],"made.":[18],"A":[19],"two-color":[20],"picosecond":[21],"infrared":[22,36],"method":[23],"is":[24,31,116,158,166,195,219,243],"used":[25],"in":[26,61,82,220],"which":[27],"one":[28],"mode":[30,151,155,205],"pumped":[32],"by":[33,44,58,172,216],"a":[34,120,143],"resonant":[35,46],"pulse":[37],"and":[38,64,69,199,231,235],"other":[39],"probed":[43],"vibrationally":[45],"sum":[47],"frequency":[48],"generation":[49],"to":[50,106,118,160,213,223],"observe":[51],"transfer.":[53],"The":[54,91,130,164,207],"prepared":[57],"chemical":[59],"etching":[60],"HF":[62],"solutions":[63],"have":[65],"monohydride-terminated":[66],"(111)-(1\u00d71)":[67],"terraces,":[68],"average":[70],"terrace":[71,149,154,204,232],"widths":[72],"approximately":[74],"five":[75],"atoms.":[76],"Two":[77],"types":[78],"surfaces,":[80],"differing":[81],"having":[83],"either":[84],"monohydride-":[85],"or":[86],"dihydride-terminated":[87,137],"steps,":[88],"examined.":[90],"results":[92,184],"both":[94],"confirm":[96],"that":[97,133,228],"transfer":[100,171],"competes":[101],"efficiently":[102],"with":[103,168],"relaxation":[105],"the":[107,110,113,126,134,148,179,182,191,203,210,214,229,240,252],"substrate.":[108],"On":[109,178],"dihydride-stepped":[111],"surface,":[112,181],"analyzed":[117],"give":[119],"relatively":[121],"complete":[122],"kinetic":[123,237],"model":[124,131,165],"equilibration":[128],"pathways.":[129],"confirms":[132],"fast":[135],"relaxing":[136],"steps":[138,212],"(60\u2013120":[139],"ps":[140],"lifetime)":[141],"drain":[142,202],"large":[144],"fraction":[145],"(\u223c2/3)":[146],"(the":[153],"intrinsic":[156],"lifetime":[157,194],"fit":[159],"be":[161,224],"\u223c1.4":[162],"ns).":[163],"consistent":[167],"terrace\u2013step":[169,188],"dipole\u2013dipole":[173],"coupling":[174,208],"between":[175],"oscillators.":[177],"monohydride-stepped":[180,241],"experimental":[183],"suggest":[185],"even":[186],"stronger":[187],"coupling,":[189],"but":[190],"monohydride":[192,211],"step":[193,230],"long":[196],"(\u2273500":[197],"ps)":[198],"does":[200],"not":[201],"energy.":[206],"terraces":[215],"dipole":[217],"interactions":[218,250],"fact":[221],"calculated":[222],"strong":[225,248],"enough":[226],"so":[227],"mix,":[234],"detailed":[236],"analysis":[238],"surface":[242],"therefore":[244],"ambiguous":[245],"because":[246],"spectral":[249],"modes.":[253]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2018,"cited_by_count":2},{"year":2016,"cited_by_count":2},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}