{"id":"https://openalex.org/W1992763508","doi":"https://doi.org/10.1063/1.445151","title":"Unimolecular and bimolecular reactions in the C4H6+\u22c5 system: Experiment and theory","display_name":"Unimolecular and bimolecular reactions in the C4H6+\u22c5 system: Experiment and theory","publication_year":1983,"publication_date":"1983-03-15","ids":{"openalex":"https://openalex.org/W1992763508","doi":"https://doi.org/10.1063/1.445151","mag":"1992763508"},"language":"en","primary_location":{"id":"doi:10.1063/1.445151","doi":"https://doi.org/10.1063/1.445151","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.445151","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5063887646","display_name":"Martin F. Jarrold","orcid":"https://orcid.org/0000-0001-7084-176X","observed_orcids":["https://orcid.org/0000-0001-7084-176X"]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Martin F. Jarrold","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056959585","display_name":"Lewis M. Bass","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Lewis M. Bass","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036674387","display_name":"Paul R. Kemper","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Paul R. Kemper","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057867182","display_name":"Petra A. M. van Koppen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Petra A. M. van Koppen","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5033847316","display_name":"Michael T. Bowers","orcid":"https://orcid.org/0000-0002-0260-7178","observed_orcids":["https://orcid.org/0000-0002-0260-7178"]},"institutions":[{"id":"https://openalex.org/I154570441","display_name":"University of California, Santa Barbara","ror":"https://ror.org/02t274463","country_code":"US","type":"education","lineage":["https://openalex.org/I154570441"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael T. Bowers","raw_affiliation_strings":["Department of Chemistry, University of California, Santa Barbara, California 93106"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of California, Santa Barbara, California 93106","institution_ids":["https://openalex.org/I154570441"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I154570441"],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":3.5542,"has_fulltext":false,"cited_by_count":31,"citation_normalized_percentile":{"value":0.92620095,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":96},"biblio":{"volume":"78","issue":"6","first_page":"3756","last_page":"3766"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10523","display_name":"Atomic and Molecular Physics","score":0.7143999934196472,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10523","display_name":"Atomic and Molecular Physics","score":0.7143999934196472,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12044","display_name":"Advanced Physical and Chemical Molecular Interactions","score":0.16670000553131104,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.05689999833703041,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/c4h6","display_name":"C4H6","score":0.7509999871253967},{"id":"https://openalex.org/keywords/metastable-ions","display_name":"metastable ions","score":0.5720000267028809},{"id":"https://openalex.org/keywords/unimolecular-reactions","display_name":"unimolecular reactions","score":0.8149999976158142},{"id":"https://openalex.org/keywords/bimolecular-reactions","display_name":"bimolecular reactions","score":0.9769999980926514},{"id":"https://openalex.org/keywords/charge-transfer","display_name":"charge transfer","score":0.6650000214576721},{"id":"https://openalex.org/keywords/rate-constants","display_name":"rate constants","score":0.6000000238418579},{"id":"https://openalex.org/keywords/branching-ratios","display_name":"branching ratios","score":0.9929999709129333},{"id":"https://openalex.org/keywords/isotopic-scrambling","display_name":"isotopic scrambling","score":0.921999990940094},{"id":"https://openalex.org/keywords/deuterium-labeling","display_name":"deuterium labeling","score":0.9580000042915344}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7801734209060669},{"id":"https://openalex.org/C58364064","wikidata":"https://www.wikidata.org/wiki/Q102296","display_name":"Deuterium","level":2,"score":0.7426022291183472},{"id":"https://openalex.org/C206175624","wikidata":"https://www.wikidata.org/wiki/Q595731","display_name":"Branching (polymer chemistry)","level":2,"score":0.7274336814880371},{"id":"https://openalex.org/C89464430","wikidata":"https://www.wikidata.org/wiki/Q849516","display_name":"Metastability","level":2,"score":0.6435150504112244},{"id":"https://openalex.org/C46460574","wikidata":"https://www.wikidata.org/wiki/Q370559","display_name":"Branching fraction","level":2,"score":0.4301123023033142},{"id":"https://openalex.org/C69928629","wikidata":"https://www.wikidata.org/wiki/Q1386472","display_name":"Kinetic isotope effect","level":3,"score":0.4206393361091614},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.3724568486213684},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.3575271964073181},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.33038702607154846},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.3282129168510437},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.14124110341072083},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08423608541488647}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.445151","doi":"https://doi.org/10.1063/1.445151","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.445151","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[{"score":0.8299999833106995,"display_name":"Affordable and clean energy","id":"https://metadata.un.org/sdg/7"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":52,"referenced_works":["https://openalex.org/W177056569","https://openalex.org/W584461677","https://openalex.org/W628855653","https://openalex.org/W1532012335","https://openalex.org/W1964146095","https://openalex.org/W1968052781","https://openalex.org/W1969975828","https://openalex.org/W1974061129","https://openalex.org/W1974817600","https://openalex.org/W1983049520","https://openalex.org/W1983512742","https://openalex.org/W1985825519","https://openalex.org/W1989645564","https://openalex.org/W1991331296","https://openalex.org/W1993930361","https://openalex.org/W1996693021","https://openalex.org/W2000454226","https://openalex.org/W2000755606","https://openalex.org/W2004585848","https://openalex.org/W2004831015","https://openalex.org/W2009730491","https://openalex.org/W2010630643","https://openalex.org/W2011871875","https://openalex.org/W2012950958","https://openalex.org/W2015213257","https://openalex.org/W2018389313","https://openalex.org/W2034063126","https://openalex.org/W2035790504","https://openalex.org/W2037840148","https://openalex.org/W2038485193","https://openalex.org/W2038690902","https://openalex.org/W2043071397","https://openalex.org/W2044147189","https://openalex.org/W2045810892","https://openalex.org/W2047792639","https://openalex.org/W2051153686","https://openalex.org/W2054575062","https://openalex.org/W2055553279","https://openalex.org/W2077553173","https://openalex.org/W2079823561","https://openalex.org/W2083610975","https://openalex.org/W2088600020","https://openalex.org/W2091434020","https://openalex.org/W2093930931","https://openalex.org/W2095125046","https://openalex.org/W2164769486","https://openalex.org/W2329928296","https://openalex.org/W2895858418","https://openalex.org/W2949773964","https://openalex.org/W2950275589","https://openalex.org/W2951742337","https://openalex.org/W2952711950"],"related_works":["https://openalex.org/W2310715627","https://openalex.org/W2004831015","https://openalex.org/W3120842177","https://openalex.org/W7101081985","https://openalex.org/W1631266563","https://openalex.org/W2045949948","https://openalex.org/W4403143652","https://openalex.org/W1503714657","https://openalex.org/W2317374997","https://openalex.org/W4250312647"],"abstract_inverted_index":{"New":[0],"experimental":[1,46,87],"data":[2,47,53],"on":[3],"the":[4,51,67,70,80,83,86,105,130],"metastable":[5],"reactions":[6,13],"of":[7,54,69,82,98,129],"C4H6+\u22c5":[8],"are":[9,64],"presented.":[10],"The":[11,45,89],"bimolecular":[12,106],"between":[14,19,79,108],"C2H2+\u22c5":[15],"and":[16,18,21,33,38,50,56,85,101,110],"C2H4":[17,111],"C2H4+\u22c5":[20],"C2H2":[22],"have":[23],"been":[24],"reinvestigated":[25],"using":[26,42],"a":[27,119,126],"tandem":[28],"ICR.":[29],"Total":[30],"rate":[31],"constants":[32],"branching":[34,90],"ratios":[35,91],"were":[36,92],"measured":[37],"isotopic":[39],"scrambling":[40],"investigated":[41],"deuterium":[43],"labeling.":[44],"reported":[48],"here":[49],"PIPECO":[52],"Werner":[55],"Baer":[57],"[J.":[58],"Chem.":[59],"Phys.":[60],"62,":[61],"2900":[62],"(1975)]":[63],"compared":[65],"with":[66],"predictions":[68,81],"transition":[71],"state":[72],"switching":[73],"model.":[74],"Good":[75],"agreement":[76],"was":[77],"found":[78,93],"model":[84],"data.":[88],"to":[94,115],"be":[95],"strong":[96],"functions":[97],"both":[99],"energy":[100],"angular":[102],"momentum.":[103],"In":[104],"reaction":[107],"C2H2+":[109],"charge":[112],"transfer":[113],"appears":[114],"occur":[116],"predominently":[117],"via":[118],"loosely":[120],"bound":[121],"intermediate":[122],"which":[123],"only":[124],"samples":[125],"small":[127],"volume":[128],"available":[131],"C4H+\u22c56":[132],"phase":[133],"space.":[134]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2016,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}