{"id":"https://openalex.org/W1992015050","doi":"https://doi.org/10.1055/s-2006-949440","title":"Sc(III)-Catalyzed Vinylsilane Addition toN-Phenylglyoxamide","display_name":"Sc(III)-Catalyzed Vinylsilane Addition toN-Phenylglyoxamide","publication_year":2006,"publication_date":"2006-10-24","ids":{"openalex":"https://openalex.org/W1992015050","doi":"https://doi.org/10.1055/s-2006-949440","mag":"1992015050"},"language":"en","primary_location":{"id":"doi:10.1055/s-2006-949440","doi":"https://doi.org/10.1055/s-2006-949440","is_oa":false,"landing_page_url":"https://doi.org/10.1055/s-2006-949440","pdf_url":null,"source":{"id":"https://openalex.org/S135102583","display_name":"Synfacts","issn_l":"1861-194X","issn":["1861-194X","1861-1958"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310321135","host_organization_name":"Georg Thieme Verlag","host_organization_lineage":["https://openalex.org/P4310321135","https://openalex.org/P4310320000"],"host_organization_lineage_names":["Georg Thieme Verlag","Thieme Medical Publishers (Germany)"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synfacts","raw_type":"journal-article"},"volume":null,"type":"editorial","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"D. Evans","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"D. Evans","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5012739930","display_name":"Yimon Aye","orcid":"https://orcid.org/0000-0002-1256-4159","observed_orcids":["https://orcid.org/0000-0002-1256-4159"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Y. Aye","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":"2006","issue":"11","first_page":"1139","last_page":"1139"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.9940999746322632,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.001500000013038516,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.0007999999797903001,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/chiral-allylic-alcohols","display_name":"chiral allylic alcohols","score":0.8889999985694885},{"id":"https://openalex.org/keywords/asymmetric-synthesis","display_name":"asymmetric synthesis","score":0.8029999732971191},{"id":"https://openalex.org/keywords/homoallylic-alcohols","display_name":"homoallylic alcohols","score":0.8059999942779541},{"id":"https://openalex.org/keywords/propargylic-alcohols","display_name":"propargylic alcohols","score":0.8769999742507935},{"id":"https://openalex.org/keywords/stereoselectivity","display_name":"stereoselectivity","score":0.5899999737739563}],"concepts":[{"id":"https://openalex.org/C2780987620","wikidata":"https://www.wikidata.org/wiki/Q6620649","display_name":"Vinylsilane","level":3,"score":0.9579481482505798},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9120851755142212},{"id":"https://openalex.org/C2778545935","wikidata":"https://www.wikidata.org/wiki/Q417321","display_name":"Phenylacetylene","level":3,"score":0.6826249361038208},{"id":"https://openalex.org/C2776254738","wikidata":"https://www.wikidata.org/wiki/Q81406","display_name":"Alkene","level":3,"score":0.6479250192642212},{"id":"https://openalex.org/C2781066024","wikidata":"https://www.wikidata.org/wiki/Q156","display_name":"Alcohol","level":2,"score":0.62138432264328},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6211978197097778},{"id":"https://openalex.org/C2778439535","wikidata":"https://www.wikidata.org/wiki/Q188777","display_name":"Amide","level":2,"score":0.6148087382316589},{"id":"https://openalex.org/C120095180","wikidata":"https://www.wikidata.org/wiki/Q2695010","display_name":"Allylic rearrangement","level":3,"score":0.6002750992774963},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.5641413927078247},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.5436259508132935},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.5367904901504517},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.512031614780426},{"id":"https://openalex.org/C2779554281","wikidata":"https://www.wikidata.org/wiki/Q27122080","display_name":"Citronellol","level":4,"score":0.467505544424057},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.4435356855392456},{"id":"https://openalex.org/C2778240251","wikidata":"https://www.wikidata.org/wiki/Q410836","display_name":"Geraniol","level":3,"score":0.0},{"id":"https://openalex.org/C2777278459","wikidata":"https://www.wikidata.org/wiki/Q170885","display_name":"Essential oil","level":2,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1055/s-2006-949440","doi":"https://doi.org/10.1055/s-2006-949440","is_oa":false,"landing_page_url":"https://doi.org/10.1055/s-2006-949440","pdf_url":null,"source":{"id":"https://openalex.org/S135102583","display_name":"Synfacts","issn_l":"1861-194X","issn":["1861-194X","1861-1958"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310321135","host_organization_name":"Georg Thieme Verlag","host_organization_lineage":["https://openalex.org/P4310321135","https://openalex.org/P4310320000"],"host_organization_lineage_names":["Georg Thieme Verlag","Thieme Medical Publishers (Germany)"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synfacts","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2004407662","https://openalex.org/W2950864114","https://openalex.org/W2088736474","https://openalex.org/W2012596888","https://openalex.org/W1989511348","https://openalex.org/W2953322606","https://openalex.org/W2908021485","https://openalex.org/W2104794316","https://openalex.org/W4233224337","https://openalex.org/W7045734974"],"abstract_inverted_index":{"Significance":[0],"In":[1,75],"the":[2,51,82],"presence":[3],"of":[4,11,50],"a":[5,9,90],"Sc(III)/nor\u00adephedrinepybox":[6],"catalyst":[7],"system,":[8],"variety":[10],"vinylsilanes":[12,36,47],"were":[13],"added":[14],"selectively":[15],"to":[16,19,27],"N":[17],"-phenylglyox\u00adamide":[18],"afford":[20,89],"chiral":[21,91],"allylic":[22],"alcohol":[23,66,93],"products":[24],"in":[25],"moderate":[26],"excellent":[28,32],"yield,":[29],"and":[30,57],"with":[31,84,94],"enantioselectivity.":[33,96],"When":[34,54],"aromatic":[35],"are":[37,42,60],"used,":[38],"E":[39],"-allylic":[40],"alcohols":[41],"obtained":[43],"exclusively,":[44],"whereas":[45],"alkyl-substituted":[46],"show":[48],"retention":[49],"alkene":[52],"geometry.":[53],"R":[55,58],"2":[56],"3":[59],"alkyl":[61],"groups,":[62],"an":[63],"isomerized":[64],"homoallylic":[65],"is":[67,73],"observed":[68],"if":[69],"no":[70],"external":[71],"base":[72],"added.":[74],"addition,":[76],"it":[77],"was":[78],"also":[79],"shown":[80],"that":[81],"reaction":[83],"(trimethyl\u00adsilyl)phenylacetylene":[85],"as":[86],"nucleophile":[87],"can":[88],"propargylic":[92],"good":[95]},"counts_by_year":[{"year":2023,"cited_by_count":1}],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-06-24T00:00:00"}