{"id":"https://openalex.org/W1990683134","doi":"https://doi.org/10.1039/f19888404487","title":"Studies of the temperature dependence of retention in supercritical fluid chromatography","display_name":"Studies of the temperature dependence of retention in supercritical fluid chromatography","publication_year":1988,"publication_date":"1988-01-01","ids":{"openalex":"https://openalex.org/W1990683134","doi":"https://doi.org/10.1039/f19888404487","mag":"1990683134"},"language":"en","primary_location":{"id":"doi:10.1039/f19888404487","doi":"https://doi.org/10.1039/f19888404487","is_oa":false,"landing_page_url":"https://doi.org/10.1039/f19888404487","pdf_url":null,"source":{"id":"https://openalex.org/S4210228976","display_name":"Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases","issn_l":"0300-9599","issn":["0300-9599","2050-5655"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5112216498","display_name":"Keith D. Bartle","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Keith D. Bartle","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113900775","display_name":"Anthony A. Clifford","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Anthony A. Clifford","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033449049","display_name":"Jacob P. Kithinji","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jacob P. Kithinji","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5000901784","display_name":"Gavin F. Shilstone","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Gavin F. Shilstone","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":2.4511,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.88062,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"84","issue":"12","first_page":"4487","last_page":"4487"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10908","display_name":"Analytical Chemistry and Chromatography","score":0.9146000146865845,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10908","display_name":"Analytical Chemistry and Chromatography","score":0.9146000146865845,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10402","display_name":"Phase Equilibria and Thermodynamics","score":0.07150000333786011,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13604","display_name":"Adsorption, diffusion, and thermodynamic properties of materials","score":0.011599999852478504,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/supercritical-fluid-chromatography","display_name":"supercritical fluid chromatography","score":0.9319999814033508},{"id":"https://openalex.org/keywords/temperature-dependence-of-retention","display_name":"temperature dependence of retention","score":0.8650000095367432},{"id":"https://openalex.org/keywords/capacity-factor","display_name":"capacity factor","score":0.7559999823570251},{"id":"https://openalex.org/keywords/naphthalene","display_name":"naphthalene","score":0.8420000076293945},{"id":"https://openalex.org/keywords/fluorene","display_name":"fluorene","score":0.9990000128746033},{"id":"https://openalex.org/keywords/phenanthrene","display_name":"phenanthrene","score":1.0},{"id":"https://openalex.org/keywords/pyrene","display_name":"pyrene","score":0.9990000128746033},{"id":"https://openalex.org/keywords/polycyclic-aromatic-hydrocarbons","display_name":"polycyclic aromatic hydrocarbons","score":0.9309999942779541},{"id":"https://openalex.org/keywords/supercritical-carbon-dioxide","display_name":"supercritical carbon dioxide","score":0.9800000190734863},{"id":"https://openalex.org/keywords/peng-robinson-equation-of-state","display_name":"Peng-Robinson equation of state","score":0.9850000143051147},{"id":"https://openalex.org/keywords/fugacity-coefficients","display_name":"fugacity coefficients","score":0.902999997138977},{"id":"https://openalex.org/keywords/enthalpy-of-solution","display_name":"enthalpy of solution","score":0.9470000267028809},{"id":"https://openalex.org/keywords/enthalpy-of-sublimation","display_name":"enthalpy of sublimation","score":0.9539999961853027}],"concepts":[{"id":"https://openalex.org/C118419359","wikidata":"https://www.wikidata.org/wiki/Q682585","display_name":"Supercritical fluid","level":2,"score":0.8278889656066895},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8133105039596558},{"id":"https://openalex.org/C2779255514","wikidata":"https://www.wikidata.org/wiki/Q179724","display_name":"Naphthalene","level":2,"score":0.802156925201416},{"id":"https://openalex.org/C58437636","wikidata":"https://www.wikidata.org/wiki/Q217249","display_name":"Sublimation (psychology)","level":2,"score":0.7237392663955688},{"id":"https://openalex.org/C2776891815","wikidata":"https://www.wikidata.org/wiki/Q422037","display_name":"Phenanthrene","level":2,"score":0.7049382925033569},{"id":"https://openalex.org/C85084404","wikidata":"https://www.wikidata.org/wiki/Q898412","display_name":"Fugacity","level":2,"score":0.7049269676208496},{"id":"https://openalex.org/C2778951431","wikidata":"https://www.wikidata.org/wiki/Q415723","display_name":"Pyrene","level":2,"score":0.6574127674102783},{"id":"https://openalex.org/C2776211377","wikidata":"https://www.wikidata.org/wiki/Q417934","display_name":"Fluorene","level":3,"score":0.5571269989013672},{"id":"https://openalex.org/C203147553","wikidata":"https://www.wikidata.org/wiki/Q332584","display_name":"Supercritical fluid chromatography","level":3,"score":0.5483849048614502},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.4840180575847626},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.4467405676841736},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.4387572407722473},{"id":"https://openalex.org/C123460561","wikidata":"https://www.wikidata.org/wiki/Q677065","display_name":"Gas chromatography","level":2,"score":0.3585399389266968},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2592056691646576},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.22024106979370117},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.06633532047271729},{"id":"https://openalex.org/C542102704","wikidata":"https://www.wikidata.org/wiki/Q183257","display_name":"Psychotherapist","level":1,"score":0.0},{"id":"https://openalex.org/C15744967","wikidata":"https://www.wikidata.org/wiki/Q9418","display_name":"Psychology","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/f19888404487","doi":"https://doi.org/10.1039/f19888404487","is_oa":false,"landing_page_url":"https://doi.org/10.1039/f19888404487","pdf_url":null,"source":{"id":"https://openalex.org/S4210228976","display_name":"Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases","issn_l":"0300-9599","issn":["0300-9599","2050-5655"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W59575751","https://openalex.org/W2129105108","https://openalex.org/W2079155726","https://openalex.org/W2131171810","https://openalex.org/W2130037193","https://openalex.org/W2051478869","https://openalex.org/W2144120772","https://openalex.org/W2009195024","https://openalex.org/W2015338977","https://openalex.org/W2088701088"],"abstract_inverted_index":{"The":[0,31],"capacity":[1],"factors":[2],"for":[3],"the":[4,47,57,62,67,70,74,89,94],"chromatographic":[5],"retention":[6],"of":[7,41,50,61,64,66,88,91,93],"naphthalene,":[8],"fluorene,":[9],"phenanthrene":[10],"and":[11,28,83],"pyrene":[12],"in":[13,56,69],"supercritical":[14,58],"carbon":[15],"dioxide":[16],"using":[17,46],"an":[18],"octadecyl":[19],"silate":[20],"bonded-phase":[21],"column":[22],"have":[23],"been":[24],"measured":[25],"between":[26],"300":[27],"400":[29],"K.":[30],"results,":[32],"which":[33,79],"go":[34],"through":[35],"a":[36,39],"maximum":[37],"as":[38],"function":[40],"temperature,":[42],"are":[43,77,80],"quantitatively":[44],"explained":[45],"Peng\u2013Robinson":[48],"equation":[49],"state":[51],"to":[52,85],"calculate":[53],"fugacity":[54],"coefficients":[55],"phase.":[59],"Values":[60],"enthalpies":[63,90],"solution":[65],"compounds":[68],"stationary":[71],"phase":[72,76],"from":[73],"vapour":[75],"obtained":[78],"approximately":[81],"equal":[82],"opposite":[84],"published":[86],"values":[87],"sublimation":[92],"compounds.":[95]},"counts_by_year":[{"year":2012,"cited_by_count":1}],"updated_date":"2025-11-06T03:46:38.306776","created_date":"2016-06-24T00:00:00"}