{"id":"https://openalex.org/W1987903333","doi":"https://doi.org/10.1021/la804080g","title":"Alkyl and Alkoxyl Monolayers Directly Attached to Silicon: Chemical Durability in Aqueous Solutions","display_name":"Alkyl and Alkoxyl Monolayers Directly Attached to Silicon: Chemical Durability in Aqueous Solutions","publication_year":2009,"publication_date":"2009-03-31","ids":{"openalex":"https://openalex.org/W1987903333","doi":"https://doi.org/10.1021/la804080g","mag":"1987903333","pmid":"https://pubmed.ncbi.nlm.nih.gov/19334747"},"language":"en","primary_location":{"id":"doi:10.1021/la804080g","doi":"https://doi.org/10.1021/la804080g","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la804080g","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5002686051","display_name":"Hikaru Sano","orcid":"https://orcid.org/0000-0002-7557-0767","observed_orcids":["https://orcid.org/0000-0002-7557-0767"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Hikaru Sano","raw_affiliation_strings":["Department of Materials Science and Engineering, Kyoto University, Yoshida Hommachi, Sakyo-Ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science and Engineering, Kyoto University, Yoshida Hommachi, Sakyo-Ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049530546","display_name":"Hajime Maeda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Hajime Maeda","raw_affiliation_strings":["Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030968278","display_name":"Takashi Ichii","orcid":"https://orcid.org/0000-0002-4021-8894","observed_orcids":["https://orcid.org/0000-0002-4021-8894"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Takashi Ichii","raw_affiliation_strings":["Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076928966","display_name":"Kuniaki Murase","orcid":"https://orcid.org/0000-0002-7564-9416","observed_orcids":["https://orcid.org/0000-0002-7564-9416"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kuniaki Murase","raw_affiliation_strings":["Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027448387","display_name":"Kei Noda","orcid":"https://orcid.org/0000-0003-2031-8975","observed_orcids":["https://orcid.org/0000-0003-2031-8975"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kei Noda","raw_affiliation_strings":["Department of Electronic Science and Engineering, Kyoto University Kyotodaigaku-katsura, Nishikyo-ku, Kyoto 615-8510, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Electronic Science and Engineering, Kyoto University Kyotodaigaku-katsura, Nishikyo-ku, Kyoto 615-8510, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103355023","display_name":"Kazumi Matsushige","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kazumi Matsushige","raw_affiliation_strings":["Department of Electronic Science and Engineering, Kyoto University Kyotodaigaku-katsura, Nishikyo-ku, Kyoto 615-8510, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Electronic Science and Engineering, Kyoto University Kyotodaigaku-katsura, Nishikyo-ku, Kyoto 615-8510, Japan","institution_ids":["https://openalex.org/I22299242"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5010330520","display_name":"Hiroyuki Sugimura","orcid":"https://orcid.org/0000-0002-6415-8558","observed_orcids":["https://orcid.org/0000-0002-6415-8558"]},"institutions":[{"id":"https://openalex.org/I22299242","display_name":"Kyoto University","ror":"https://ror.org/02kpeqv85","country_code":"JP","type":"education","lineage":["https://openalex.org/I22299242"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Hiroyuki Sugimura","raw_affiliation_strings":["Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Materials Science and Engineering, Kyoto University Yoshida-hommachi, Sakyo-ku, Kyoto 606-8501, Japan","institution_ids":["https://openalex.org/I22299242"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5010330520"],"corresponding_institution_ids":["https://openalex.org/I22299242"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.8974,"has_fulltext":false,"cited_by_count":52,"citation_normalized_percentile":{"value":0.94934495,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"25","issue":"10","first_page":"5516","last_page":"5525"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.5820000171661377,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.5820000171661377,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.23399999737739563,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10859","display_name":"Polymer Surface Interaction Studies","score":0.14480000734329224,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/self-assembled-monolayers","display_name":"self-assembled monolayers","score":0.9850000143051147},{"id":"https://openalex.org/keywords/alkyl-monolayers","display_name":"alkyl monolayers","score":0.9039999842643738},{"id":"https://openalex.org/keywords/si-111-surface","display_name":"Si(111) surface","score":0.8309999704360962},{"id":"https://openalex.org/keywords/chemical-durability","display_name":"chemical durability","score":0.609000027179718},{"id":"https://openalex.org/keywords/hydrofluoric-acid","display_name":"hydrofluoric acid","score":0.6179999709129333},{"id":"https://openalex.org/keywords/sodium-carbonate","display_name":"sodium carbonate","score":0.9259999990463257},{"id":"https://openalex.org/keywords/pitting-corrosion","display_name":"pitting corrosion","score":0.531000018119812},{"id":"https://openalex.org/keywords/surface-roughening","display_name":"surface roughening","score":0.9660000205039978},{"id":"https://openalex.org/keywords/si-c-bonds","display_name":"Si-C bonds","score":0.8220000267028809},{"id":"https://openalex.org/keywords/grazing-incidence-x-ray-reflectivity","display_name":"grazing incidence X-ray reflectivity","score":0.7680000066757202},{"id":"https://openalex.org/keywords/1-hexadecene","display_name":"1-hexadecene","score":0.7670000195503235},{"id":"https://openalex.org/keywords/1-hexadecanol","display_name":"1-hexadecanol","score":0.9430000185966492},{"id":"https://openalex.org/keywords/1-dodecanol","display_name":"1-dodecanol","score":0.9070000052452087}],"concepts":[{"id":"https://openalex.org/C7070889","wikidata":"https://www.wikidata.org/wiki/Q902488","display_name":"Monolayer","level":2,"score":0.8342515230178833},{"id":"https://openalex.org/C90150868","wikidata":"https://www.wikidata.org/wiki/Q39513","display_name":"Alkoxy group","level":3,"score":0.8054279685020447},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.764568567276001},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.7627964615821838},{"id":"https://openalex.org/C104304963","wikidata":"https://www.wikidata.org/wiki/Q5316114","display_name":"Durability","level":2,"score":0.7033783197402954},{"id":"https://openalex.org/C544956773","wikidata":"https://www.wikidata.org/wiki/Q670","display_name":"Silicon","level":2,"score":0.6859890818595886},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.49659472703933716},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.47726625204086304},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4236268401145935},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3721272349357605},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3562043309211731},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.2786390781402588},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.2580191195011139},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.07999551296234131}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/la804080g","doi":"https://doi.org/10.1021/la804080g","is_oa":false,"landing_page_url":"https://doi.org/10.1021/la804080g","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},{"id":"pmid:19334747","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19334747","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir : the ACS journal of surfaces and colloids","raw_type":"Journal Article"},{"id":"pmh:oai:irdb.nii.ac.jp:01221:0000075356","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/2433/109540","pdf_url":null,"source":{"id":"https://openalex.org/S7407056385","display_name":"Institutional Repositories DataBase (IRDB)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I184597095","host_organization_name":"National Institute of Informatics","host_organization_lineage":["https://openalex.org/I184597095"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"LANGMUIR","raw_type":"journal article"},{"id":"pmh:oai:repository.kulib.kyoto-u.ac.jp:2433/109540","doi":null,"is_oa":false,"landing_page_url":"http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=KyotoUniv&SrcApp=KyotoUniv&DestLinkType=FullRecord&KeyUT=ISI:000266081000019&DestApp=WOS","pdf_url":null,"source":{"id":"https://openalex.org/S4306401454","display_name":"Kyoto University Research Information Repository (Kyoto University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I22299242","host_organization_name":"Kyoto University","host_organization_lineage":["https://openalex.org/I22299242"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":45,"referenced_works":["https://openalex.org/W1969580675","https://openalex.org/W1970782195","https://openalex.org/W1972091231","https://openalex.org/W1972557924","https://openalex.org/W1972875212","https://openalex.org/W1985376675","https://openalex.org/W1985707986","https://openalex.org/W1990904262","https://openalex.org/W1991291890","https://openalex.org/W1991615398","https://openalex.org/W1992842675","https://openalex.org/W1993691645","https://openalex.org/W1995622658","https://openalex.org/W1997618980","https://openalex.org/W2004200115","https://openalex.org/W2008136979","https://openalex.org/W2008712026","https://openalex.org/W2009791501","https://openalex.org/W2010770591","https://openalex.org/W2011488302","https://openalex.org/W2012458387","https://openalex.org/W2015871726","https://openalex.org/W2016145579","https://openalex.org/W2022265330","https://openalex.org/W2024865697","https://openalex.org/W2028276661","https://openalex.org/W2031443077","https://openalex.org/W2031889861","https://openalex.org/W2039103845","https://openalex.org/W2045660771","https://openalex.org/W2049667872","https://openalex.org/W2054284893","https://openalex.org/W2054836251","https://openalex.org/W2056359589","https://openalex.org/W2060548005","https://openalex.org/W2067396462","https://openalex.org/W2081602000","https://openalex.org/W2083424391","https://openalex.org/W2094498700","https://openalex.org/W2119764213","https://openalex.org/W2134819724","https://openalex.org/W2155525175","https://openalex.org/W2162123284","https://openalex.org/W2481846676","https://openalex.org/W3004793631"],"related_works":["https://openalex.org/W2017530262","https://openalex.org/W1983187253","https://openalex.org/W2067396462","https://openalex.org/W2092685342","https://openalex.org/W2088453677","https://openalex.org/W1977657643","https://openalex.org/W2040655808","https://openalex.org/W2131614097","https://openalex.org/W338113367","https://openalex.org/W2981251479"],"abstract_inverted_index":{"For":[0],"practical":[1],"application":[2],"of":[3,8,25,52,70,106],"self-assembled":[4],"monolayers":[5],"(SAMs),":[6],"knowledge":[7],"their":[9],"chemical":[10,50,154],"durability":[11,69],"in":[12,126,135,153],"acidic":[13],"or":[14,36],"basic":[15],"solutions":[16],"is":[17,109],"important.":[18],"In":[19],"the":[20,68,71,87,92,100,139,151,158],"present":[21],"work,":[22],"a":[23,30,41,53],"series":[24],"SAMs":[26,72,89,141],"directly":[27],"immobilized":[28],"on":[29],"silicon":[31],"(111)":[32],"surface":[33,124],"through":[34],"Si-C":[35,162],"Si-O-C":[37],"covalent":[38],"bonds":[39],"without":[40],"native":[42],"oxide":[43],"layer":[44],"were":[45,142],"prepared":[46],"by":[47,111],"thermally":[48],"activated":[49],"reactions":[51],"hydrogen-terminated":[54],"Si(111)":[55,107],"substrate":[56],"with":[57],"linear":[58],"molecules,":[59],"i.e.,":[60,120,161],"1-hexadecene,":[61],"1-hexadecanol,":[62],"1-dodecanol,":[63],"and":[64,75,96,103,122,163],"n-dodecanal,":[65],"to":[66,73,150],"investigate":[67],"HF":[74],"Na2CO3":[76],"solutions.":[77,128],"While":[78],"grazing":[79],"incidence":[80],"X-ray":[81],"reflectivity":[82],"measurements":[83],"showed":[84],"that":[85],"all":[86],"as-prepared":[88],"had":[90],"almost":[91],"same":[93],"film":[94],"density":[95],"molecular":[97],"coverage,":[98],"keeping":[99],"original":[101],"step":[102],"terrace":[104],"structure":[105],"as":[108],"observed":[110],"atomic":[112],"force":[113],"microscopy,":[114],"they":[115],"gave":[116],"different":[117],"degradation":[118],"behaviors,":[119],"pitting":[121],"concomitant":[123],"roughening":[125],"both":[127,136],"1-hexadecene":[129],"SAM":[130],"was":[131],"stable":[132],"against":[133],"immersion":[134],"solutions,":[137],"while":[138],"other":[140],"damaged":[143],"within":[144],"60":[145],"min,":[146],"most":[147],"likely":[148],"due":[149],"difference":[152],"bonding":[155],"modes":[156],"at":[157],"SAM/Si":[159],"interface,":[160],"Si-O-C.":[164]},"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":5},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":8},{"year":2012,"cited_by_count":4}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2016-06-24T00:00:00"}