{"id":"https://openalex.org/W1987758441","doi":"https://doi.org/10.1063/1.456082","title":"Ultraviolet photodissociation dynamics of H2S and D2S","display_name":"Ultraviolet photodissociation dynamics of H2S and D2S","publication_year":1989,"publication_date":"1989-02-01","ids":{"openalex":"https://openalex.org/W1987758441","doi":"https://doi.org/10.1063/1.456082","mag":"1987758441"},"language":"en","primary_location":{"id":"doi:10.1063/1.456082","doi":"https://doi.org/10.1063/1.456082","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.456082","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5029412939","display_name":"Brad R. Weiner","orcid":"https://orcid.org/0000-0002-5255-1918","observed_orcids":["https://orcid.org/0000-0002-5255-1918"]},"institutions":[{"id":"https://openalex.org/I1288214837","display_name":"United States Naval Research Laboratory","ror":"https://ror.org/04d23a975","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028"]},{"id":"https://openalex.org/I4388482685","display_name":"Naval Research Laboratory Chemistry Division","ror":"https://ror.org/025vw1435","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028","https://openalex.org/I4388482685"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Brad R. Weiner","raw_affiliation_strings":["Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375","institution_ids":["https://openalex.org/I1288214837","https://openalex.org/I4388482685"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110621985","display_name":"Harold B. Levene","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1288214837","display_name":"United States Naval Research Laboratory","ror":"https://ror.org/04d23a975","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028"]},{"id":"https://openalex.org/I4388482685","display_name":"Naval Research Laboratory Chemistry Division","ror":"https://ror.org/025vw1435","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028","https://openalex.org/I4388482685"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Harold B. Levene","raw_affiliation_strings":["Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375","institution_ids":["https://openalex.org/I1288214837","https://openalex.org/I4388482685"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5068283070","display_name":"James J. Valentini","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1288214837","display_name":"United States Naval Research Laboratory","ror":"https://ror.org/04d23a975","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028"]},{"id":"https://openalex.org/I4388482685","display_name":"Naval Research Laboratory Chemistry Division","ror":"https://ror.org/025vw1435","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028","https://openalex.org/I4388482685"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James J. Valentini","raw_affiliation_strings":["Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375","institution_ids":["https://openalex.org/I1288214837","https://openalex.org/I4388482685"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5082346178","display_name":"Andrew P. Baronavski","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1288214837","display_name":"United States Naval Research Laboratory","ror":"https://ror.org/04d23a975","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028"]},{"id":"https://openalex.org/I4388482685","display_name":"Naval Research Laboratory Chemistry Division","ror":"https://ror.org/025vw1435","country_code":"US","type":"facility","lineage":["https://openalex.org/I1288214837","https://openalex.org/I1330347796","https://openalex.org/I175003984","https://openalex.org/I3130687028","https://openalex.org/I4388482685"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"A. P. Baronavski","raw_affiliation_strings":["Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Division, Naval Research Laboratory, Washington, D.C. 20375","institution_ids":["https://openalex.org/I1288214837","https://openalex.org/I4388482685"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":5.8167,"has_fulltext":false,"cited_by_count":83,"citation_normalized_percentile":{"value":0.97650602,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":97},"biblio":{"volume":"90","issue":"3","first_page":"1403","last_page":"1414"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9047999978065491,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9047999978065491,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.029100000858306885,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11111","display_name":"Spectroscopy and Laser Applications","score":0.017500000074505806,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrogen-sulfide","display_name":"hydrogen sulfide","score":0.8230000138282776},{"id":"https://openalex.org/keywords/deuterium-sulfide","display_name":"deuterium sulfide","score":0.9769999980926514},{"id":"https://openalex.org/keywords/ultraviolet-photodissociation","display_name":"ultraviolet photodissociation","score":0.8970000147819519},{"id":"https://openalex.org/keywords/rotational-state-distribution","display_name":"rotational state distribution","score":0.8859999775886536},{"id":"https://openalex.org/keywords/free-jet-expansion","display_name":"free jet expansion","score":0.6370000243186951}],"concepts":[{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.8769193887710571},{"id":"https://openalex.org/C2908647359","wikidata":"https://www.wikidata.org/wiki/Q2625603","display_name":"Population","level":2,"score":0.6711506843566895},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.6594372987747192},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.629798412322998},{"id":"https://openalex.org/C193201615","wikidata":"https://www.wikidata.org/wiki/Q2788607","display_name":"Triatomic molecule","level":3,"score":0.6279233694076538},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5760045051574707},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.5184099674224854},{"id":"https://openalex.org/C155675718","wikidata":"https://www.wikidata.org/wiki/Q161254","display_name":"Angular momentum","level":2,"score":0.49060359597206116},{"id":"https://openalex.org/C169146920","wikidata":"https://www.wikidata.org/wiki/Q2140940","display_name":"Rotational energy","level":2,"score":0.47129571437835693},{"id":"https://openalex.org/C83581075","wikidata":"https://www.wikidata.org/wiki/Q1361503","display_name":"Excitation","level":2,"score":0.43924272060394287},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.4123358130455017},{"id":"https://openalex.org/C2780477314","wikidata":"https://www.wikidata.org/wiki/Q241056","display_name":"Excimer laser","level":3,"score":0.41211098432540894},{"id":"https://openalex.org/C520434653","wikidata":"https://www.wikidata.org/wiki/Q38867","display_name":"Laser","level":2,"score":0.30840927362442017},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2893885672092438},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.25928330421447754},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.10695779323577881},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.09809863567352295},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C149923435","wikidata":"https://www.wikidata.org/wiki/Q37732","display_name":"Demography","level":1,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0},{"id":"https://openalex.org/C144024400","wikidata":"https://www.wikidata.org/wiki/Q21201","display_name":"Sociology","level":0,"score":0.0},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1063/1.456082","doi":"https://doi.org/10.1063/1.456082","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.456082","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},{"id":"pmh:oai:digitalcommons.unl.edu:usnavyresearch-1025","doi":null,"is_oa":false,"landing_page_url":"http://digitalcommons.unl.edu/usnavyresearch/26","pdf_url":null,"source":{"id":"https://openalex.org/S4306400577","display_name":"Lincoln (University of Nebraska)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I114395901","host_organization_name":"University of Nebraska\u2013Lincoln","host_organization_lineage":["https://openalex.org/I114395901"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"United States Navy: Publications","raw_type":"text"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W1535873931","https://openalex.org/W1587564793","https://openalex.org/W1976141815","https://openalex.org/W1977839553","https://openalex.org/W1979478307","https://openalex.org/W1982474556","https://openalex.org/W1998693008","https://openalex.org/W2002933833","https://openalex.org/W2003601070","https://openalex.org/W2003924186","https://openalex.org/W2006005108","https://openalex.org/W2006393859","https://openalex.org/W2010732253","https://openalex.org/W2021353946","https://openalex.org/W2026512276","https://openalex.org/W2030317976","https://openalex.org/W2034493004","https://openalex.org/W2038842821","https://openalex.org/W2046002177","https://openalex.org/W2046034853","https://openalex.org/W2053068750","https://openalex.org/W2056371711","https://openalex.org/W2068854112","https://openalex.org/W2069187015","https://openalex.org/W2079663892","https://openalex.org/W2080948093","https://openalex.org/W2082906744","https://openalex.org/W2084035607","https://openalex.org/W2084293776","https://openalex.org/W2091662948","https://openalex.org/W2105498422","https://openalex.org/W2113839233","https://openalex.org/W2798856947","https://openalex.org/W4232254845"],"related_works":["https://openalex.org/W2021353946","https://openalex.org/W2020503012","https://openalex.org/W2026512276","https://openalex.org/W2005059917","https://openalex.org/W2083816169","https://openalex.org/W2021846239","https://openalex.org/W2016009300","https://openalex.org/W2043520949","https://openalex.org/W3185536137","https://openalex.org/W2080910827"],"abstract_inverted_index":{"Nascent":[0,44],"SH(X":[1,45,103,121],"2\u03a0i,":[2,6,46,104,108,122,126],"v\u2033=0,1)":[3,7],"and":[4,16,34,37,40,89,106,124],"SD(X":[5,107,125],"rotational":[8,48,92,149],"state":[9,13,18,49,118,150],"population":[10,14,19,133],"distributions,":[11],"spin\u2013orbit":[12],"ratios,":[15],"\u039b-doublet":[17,132],"ratios":[20,134],"have":[21,110],"been":[22,111],"measured":[23],"following":[24,51],"the":[25,74,86,96,114,136,144,160],"UV":[26],"excimer":[27],"laser":[28],"photodissociation":[29,54],"of":[30,55,102,130,135],"H2S":[31,57,66],"(\u03bb=193,":[32],"222,":[33],"248":[35],"nm)":[36],"D2S":[38],"(\u03bb=193":[39],"222":[41],"nm),":[42],"respectively.":[43],"v\u2033=0)":[47],"distributions":[50,119,151],"193":[52],"nm":[53],"cold":[56],"in":[58,67,85,95],"a":[59,68],"free":[60],"jet":[61],"expansion":[62],"vs":[63],"300":[64],"K":[65],"flowing":[69],"gas":[70],"cell":[71],"were":[72],"essentially":[73,140],"same,":[75],"indicating":[76],"that":[77],"photofragment":[78],"angular":[79],"momentum":[80],"must":[81],"be":[82],"originating":[83],"predominantly":[84],"dissociation":[87],"event,":[88],"not":[90],"from":[91],"energy":[93],"contained":[94],"parent":[97],"triatom.":[98],"Laser":[99],"excitation":[100],"spectra":[101],"v\u2033=1)":[105,109],"recorded":[112],"for":[113,120,142,159],"first":[115],"time.":[116],"Rotational":[117],"v\u2033)":[123,127],"are":[128,139,152],"independent":[129],"v\u2033.":[131],"nascent":[137,148],"photofragments":[138],"unity":[141],"all":[143],"cases":[145],"measured.":[146],"The":[147],"consistent":[153],"with":[154],"an":[155],"impact":[156],"parameter":[157],"model":[158],"dissociating":[161],"triatomic":[162],"molecule.":[163]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":1}],"updated_date":"2026-10-27T15:51:10.671819","created_date":"2016-06-24T00:00:00"}