{"id":"https://openalex.org/W1986708371","doi":"https://doi.org/10.1039/c1dt10786k","title":"MgCl2.6PhCH2OH \u2013 A new molecular adduct as support material for Ziegler\u2013Natta catalyst: synthesis, characterization and catalytic activity","display_name":"MgCl2.6PhCH2OH \u2013 A new molecular adduct as support material for Ziegler\u2013Natta catalyst: synthesis, characterization and catalytic activity","publication_year":2011,"publication_date":"2011-01-01","ids":{"openalex":"https://openalex.org/W1986708371","doi":"https://doi.org/10.1039/c1dt10786k","mag":"1986708371","pmid":"https://pubmed.ncbi.nlm.nih.gov/21909567"},"language":"en","primary_location":{"id":"doi:10.1039/c1dt10786k","doi":"https://doi.org/10.1039/c1dt10786k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c1dt10786k","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5088421204","display_name":"Edwin S. Gnanakumar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Edwin S. Gnanakumar","raw_affiliation_strings":["Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, 411 008, India","Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road,Pune,India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, 411 008, India","institution_ids":["https://openalex.org/I3125981224"]},{"raw_affiliation_string":"Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road,Pune,India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078658705","display_name":"K. S. Thushara","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"K. S. Thushara","raw_affiliation_strings":["Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006444762","display_name":"Deu S. Bhange","orcid":"https://orcid.org/0000-0002-4082-6654","observed_orcids":["https://orcid.org/0000-0002-4082-6654"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Deu S. Bhange","raw_affiliation_strings":["Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5064078476","display_name":"Renny Mathew","orcid":"https://orcid.org/0000-0003-4041-2803","observed_orcids":["https://orcid.org/0000-0003-4041-2803"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Renny Mathew","raw_affiliation_strings":["Central NMR Facility, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Central NMR Facility, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070945761","display_name":"Thalasseril Govindankuttykaimal Ajithkumar","orcid":"https://orcid.org/0000-0002-9217-2138","observed_orcids":["https://orcid.org/0000-0002-9217-2138"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"T. G. Ajithkumar","raw_affiliation_strings":["Central NMR Facility, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Central NMR Facility, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022968378","display_name":"Pattuparambil Ramanpillai Rajamohanan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"P. R. Rajamohanan","raw_affiliation_strings":["Central NMR Facility, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Central NMR Facility, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111912129","display_name":"Sumit Bhaduri","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I111979921","display_name":"Northwestern University","ror":"https://ror.org/000e0be47","country_code":"US","type":"education","lineage":["https://openalex.org/I111979921"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Sumit Bhaduri","raw_affiliation_strings":["Department of Chemistry, Northwestern University, Evanston, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Northwestern University, Evanston, USA","institution_ids":["https://openalex.org/I111979921"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030363496","display_name":"Chinnakonda S. Gopinath","orcid":"https://orcid.org/0000-0002-4525-3912","observed_orcids":["https://orcid.org/0000-0002-4525-3912"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"Chinnakonda S. Gopinath","raw_affiliation_strings":["Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Catalysis Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune, India","institution_ids":["https://openalex.org/I3125981224"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5030363496","https://openalex.org/A5111912129"],"corresponding_institution_ids":["https://openalex.org/I111979921","https://openalex.org/I3125981224"],"apc_list":null,"apc_paid":null,"fwci":1.1099,"has_fulltext":false,"cited_by_count":20,"citation_normalized_percentile":{"value":0.73142857,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"40","issue":"41","first_page":"10936","last_page":"10936"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9955999851226807,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/benzyl-alcohol","display_name":"benzyl alcohol","score":0.7329999804496765},{"id":"https://openalex.org/keywords/molecular-adducts","display_name":"molecular adducts","score":0.8560000061988831},{"id":"https://openalex.org/keywords/ziegler-natta-catalysts","display_name":"Ziegler-Natta catalysts","score":0.828000009059906},{"id":"https://openalex.org/keywords/supported-catalysts","display_name":"supported catalysts","score":0.6840000152587891},{"id":"https://openalex.org/keywords/ethylene-polymerization","display_name":"ethylene polymerization","score":0.9879999756813049},{"id":"https://openalex.org/keywords/magnesium-chloride","display_name":"magnesium chloride","score":0.39899998903274536},{"id":"https://openalex.org/keywords/mgo6-octahedra","display_name":"MgO6 octahedra","score":0.9200000166893005},{"id":"https://openalex.org/keywords/raman-spectroscopy","display_name":"Raman spectroscopy","score":0.7160000205039978},{"id":"https://openalex.org/keywords/catalyst-supports","display_name":"catalyst supports","score":0.48899999260902405}],"concepts":[{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.8918365836143494},{"id":"https://openalex.org/C2780654073","wikidata":"https://www.wikidata.org/wiki/Q1134313","display_name":"Natta","level":4,"score":0.8598642945289612},{"id":"https://openalex.org/C2780841128","wikidata":"https://www.wikidata.org/wiki/Q5073781","display_name":"Characterization (materials science)","level":2,"score":0.7331295013427734},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.7015842795372009},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4449286460876465},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.40421804785728455},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.34295934438705444},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2362411618232727},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.18213722109794617},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.15966486930847168},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.038961172103881836}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/c1dt10786k","doi":"https://doi.org/10.1039/c1dt10786k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c1dt10786k","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},{"id":"pmid:21909567","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/21909567","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton transactions (Cambridge, England : 2003)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":41,"referenced_works":["https://openalex.org/W1479784489","https://openalex.org/W1559238515","https://openalex.org/W1935721620","https://openalex.org/W1983990447","https://openalex.org/W1986569113","https://openalex.org/W1988021111","https://openalex.org/W1988389565","https://openalex.org/W1989208565","https://openalex.org/W1989450329","https://openalex.org/W1989971737","https://openalex.org/W1993087359","https://openalex.org/W1995254375","https://openalex.org/W1997140103","https://openalex.org/W2001993668","https://openalex.org/W2003110406","https://openalex.org/W2005148839","https://openalex.org/W2011199933","https://openalex.org/W2011775791","https://openalex.org/W2015080424","https://openalex.org/W2032610705","https://openalex.org/W2033600767","https://openalex.org/W2034166795","https://openalex.org/W2035993894","https://openalex.org/W2040119610","https://openalex.org/W2044445580","https://openalex.org/W2057868701","https://openalex.org/W2059268380","https://openalex.org/W2061653842","https://openalex.org/W2068594070","https://openalex.org/W2071963728","https://openalex.org/W2088046961","https://openalex.org/W2088184963","https://openalex.org/W2107746113","https://openalex.org/W2121871844","https://openalex.org/W2153200399","https://openalex.org/W2166328140","https://openalex.org/W2171831026","https://openalex.org/W2291444549","https://openalex.org/W2313282331","https://openalex.org/W2330677464","https://openalex.org/W4248006798"],"related_works":["https://openalex.org/W2327596584","https://openalex.org/W2076543765","https://openalex.org/W1964653234","https://openalex.org/W2091741650","https://openalex.org/W1978302342","https://openalex.org/W2098400191","https://openalex.org/W2316972487","https://openalex.org/W1479784489","https://openalex.org/W2181997155","https://openalex.org/W2026631683"],"abstract_inverted_index":{"Benzyl":[0],"alcohol":[1,65],"has":[2,82],"been":[3,39,83],"used":[4],"to":[5,53,106],"prepare":[6],"a":[7,14,69,101],"single":[8],"phase":[9],"MgCl(2).6BzOH":[10,31],"molecular":[11,32],"adduct":[12,33],"as":[13],"support":[15,115],"for":[16,85],"an":[17],"ethylene":[18,87],"polymerization":[19,88,92],"catalyst":[20,37,80,98,103],"(Ziegler":[21],"catalyst).":[22],"The":[23,47,78,90],"structural,":[24],"spectroscopic":[25],"and":[26,34,75,116],"morphological":[27],"aspects":[28],"of":[29,49,56,62,94,110],"the":[30,35,54,63,86,95,107,114],"Ziegler":[36],"have":[38],"thoroughly":[40],"studied":[41],"by":[42],"various":[43],"physicochemical":[44],"characterization":[45],"techniques.":[46],"presence":[48],"MgO(6)":[50],"octahedrons":[51],"due":[52],"interaction":[55,109],"Mg(2+)":[57],"with":[58,100,113],"six":[59],"-OH":[60],"groups":[61],"benzyl":[64],"is":[66,104],"confirmed":[67],"from":[68],"Raman":[70],"feature":[71],"at":[72],"703":[73],"cm(-1),":[74],"structural":[76],"studies.":[77],"supported":[79],"activity":[81,93],"evaluated":[84],"reaction.":[89],"lower":[91],"titanated":[96],"Ziegler-Natta":[97],"compared":[99],"standard":[102],"attributed":[105],"strong":[108],"titanium":[111],"chloride":[112],"associated":[117],"electronic":[118],"factors.":[119]},"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":1},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":4}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}