{"id":"https://openalex.org/W1985758387","doi":"https://doi.org/10.1021/ma0005116","title":"Mechanism of Polymerization Reaction of 2,5-Bis(tetrahydrothiopheniomethyl)furan Dichloride. Effect of Aromatic Resonance Energy on the Polymerization of Bis(sulfonium) Salts","display_name":"Mechanism of Polymerization Reaction of 2,5-Bis(tetrahydrothiopheniomethyl)furan Dichloride. Effect of Aromatic Resonance Energy on the Polymerization of Bis(sulfonium) Salts","publication_year":2000,"publication_date":"2000-10-01","ids":{"openalex":"https://openalex.org/W1985758387","doi":"https://doi.org/10.1021/ma0005116","mag":"1985758387"},"language":"en","primary_location":{"id":"doi:10.1021/ma0005116","doi":"https://doi.org/10.1021/ma0005116","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma0005116","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5057432547","display_name":"Bong Rae Cho","orcid":"https://orcid.org/0000-0001-8560-5399","observed_orcids":["https://orcid.org/0000-0001-8560-5399"]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Bong Rae Cho","raw_affiliation_strings":["Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100383847","display_name":"Tae Hoon Kim","orcid":"https://orcid.org/0000-0001-8811-654X","observed_orcids":["https://orcid.org/0000-0001-8811-654X"]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Tae Hoon Kim","raw_affiliation_strings":["Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005096405","display_name":"Kyung Hwa Son","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Kyung Hwa Son","raw_affiliation_strings":["Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108482459","display_name":"Yong Kwan Kim","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Yong Kwan Kim","raw_affiliation_strings":["Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5114020250","display_name":"Yun Kyong Lee","orcid":"https://orcid.org/0000-0002-4972-0047","observed_orcids":["https://orcid.org/0000-0002-4972-0047"]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Yun Kyong Lee","raw_affiliation_strings":["Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea","institution_ids":["https://openalex.org/I197347611"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111718986","display_name":"Seung\u2010Joon Jeon","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197347611","display_name":"Korea University","ror":"https://ror.org/047dqcg40","country_code":"KR","type":"education","lineage":["https://openalex.org/I197347611"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Seung-Joon Jeon","raw_affiliation_strings":["Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Molecular Opto-Electronics Laboratory, Department of Chemistry, Korea University, 1-Anamdong, Seoul 136-701, Korea","institution_ids":["https://openalex.org/I197347611"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I197347611"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.2784,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.47433544,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":94},"biblio":{"volume":"33","issue":"22","first_page":"8167","last_page":"8172"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8862000107765198,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8862000107765198,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.04749999940395355,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13304","display_name":"Synthesis and Reactivity of Sulfur-Containing Compounds","score":0.011800000444054604,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polymerization-mechanism","display_name":"polymerization mechanism","score":0.8700000047683716},{"id":"https://openalex.org/keywords/free-radical-polymerization","display_name":"radical polymerization","score":0.9160000085830688},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.6669999957084656},{"id":"https://openalex.org/keywords/thiophene","display_name":"thiophene","score":0.722000002861023},{"id":"https://openalex.org/keywords/furan","display_name":"furan","score":0.8809999823570251},{"id":"https://openalex.org/keywords/phenyl-substituent-effects","display_name":"phenyl substituent effects","score":0.5809999704360962}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8434317111968994},{"id":"https://openalex.org/C2777040163","wikidata":"https://www.wikidata.org/wiki/Q423240","display_name":"Sulfonium","level":3,"score":0.8069512844085693},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.7955399751663208},{"id":"https://openalex.org/C2778659115","wikidata":"https://www.wikidata.org/wiki/Q243992","display_name":"Furan","level":2,"score":0.6344152688980103},{"id":"https://openalex.org/C2779953032","wikidata":"https://www.wikidata.org/wiki/Q305364","display_name":"Thiophene","level":2,"score":0.6019285917282104},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5975670218467712},{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.5643385648727417},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.5365735292434692},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5205891728401184},{"id":"https://openalex.org/C84687054","wikidata":"https://www.wikidata.org/wiki/Q17125192","display_name":"Ionic polymerization","level":5,"score":0.4279303550720215},{"id":"https://openalex.org/C95121573","wikidata":"https://www.wikidata.org/wiki/Q190474","display_name":"Activation energy","level":2,"score":0.42468926310539246},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.4069215953350067},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.24460190534591675},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.11247730255126953},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.10581102967262268},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.08510401844978333}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ma0005116","doi":"https://doi.org/10.1021/ma0005116","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma0005116","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":9,"referenced_works":["https://openalex.org/W1489755967","https://openalex.org/W1969891604","https://openalex.org/W1997148790","https://openalex.org/W2034531272","https://openalex.org/W2049162155","https://openalex.org/W2057183790","https://openalex.org/W2329978124","https://openalex.org/W2952440427","https://openalex.org/W4245140981"],"related_works":["https://openalex.org/W2079998326","https://openalex.org/W2063877942","https://openalex.org/W2094564983","https://openalex.org/W2044348996","https://openalex.org/W2003120653","https://openalex.org/W2002559132","https://openalex.org/W1685620852","https://openalex.org/W7096278650","https://openalex.org/W1497844468","https://openalex.org/W1522283708"],"abstract_inverted_index":{"The":[0,11,69],"mechanism":[1,18],"of":[2,5,33,41,57,79],"polymerization":[3,30,50],"reaction":[4,12,43,51],"2,5-bis(tetrahydrothiopheniomethyl)furan":[6],"dichloride":[7],"was":[8],"studied":[9],"kinetically.":[10],"proceeds":[13],"by":[14],"the":[15,34,39,48,54,58,75,80],"(E1cb)":[16],"irr":[17],"to":[19,65,67,74],"afford":[20],"a":[21,27],"2,5-dihydrofuran":[22],"intermediate":[23],"M,":[24],"which":[25],"undergoes":[26],"free":[28],"radical":[29],"reaction.":[31],"Comparison":[32],"kinetic":[35],"results":[36,70],"reveals":[37],"that":[38,46],"rate":[40],"elimination":[42],"increases,":[44],"whereas":[45],"for":[47],"subsequent":[49],"decreases":[52],"as":[53],"aromatic":[55,81],"moiety":[56],"bis(sulfonium)":[59],"salts":[60],"is":[61],"changed":[62],"from":[63],"phenyl":[64],"thiophene":[66],"furan.":[68],"have":[71],"been":[72],"attributed":[73],"decreased":[76],"resonance":[77],"energy":[78],"rings.":[82]},"counts_by_year":[{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-09-26T08:19:03.415552","created_date":"2016-06-24T00:00:00"}
