{"id":"https://openalex.org/W1985496728","doi":"https://doi.org/10.1134/s0036023612030096","title":"The reaction of ammonium tetra(isothiocyanato)diamminechromate(III) with \u025b-caprolactam in aqueous solution. Revised refinement of the structure of (HCpl2)3[Cr(NCS)6]","display_name":"The reaction of ammonium tetra(isothiocyanato)diamminechromate(III) with \u025b-caprolactam in aqueous solution. Revised refinement of the structure of (HCpl2)3[Cr(NCS)6]","publication_year":2012,"publication_date":"2012-05-01","ids":{"openalex":"https://openalex.org/W1985496728","doi":"https://doi.org/10.1134/s0036023612030096","mag":"1985496728"},"language":"en","primary_location":{"id":"doi:10.1134/s0036023612030096","doi":"https://doi.org/10.1134/s0036023612030096","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s0036023612030096","pdf_url":null,"source":{"id":"https://openalex.org/S127769916","display_name":"Russian Journal of Inorganic Chemistry","issn_l":"0036-0236","issn":["0036-0236","1531-8613","3034-560X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["dongbi-d","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Russian Journal of Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072664486","display_name":"Irina V. Isakova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I45791419","display_name":"Kuzbass State Technical University","ror":"https://ror.org/02hfhf494","country_code":"RU","type":"education","lineage":["https://openalex.org/I45791419"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"I. V. Isakova","raw_affiliation_strings":["Kuzbass State Technical University, Kemerovo, Russia","[Kuzbass State Technical University]"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kuzbass State Technical University, Kemerovo, Russia","institution_ids":["https://openalex.org/I45791419"]},{"raw_affiliation_string":"[Kuzbass State Technical University]","institution_ids":["https://openalex.org/I45791419"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5091042657","display_name":"Eugenia V. Peresypkina","orcid":"https://orcid.org/0000-0002-9870-9928","observed_orcids":["https://orcid.org/0000-0002-9870-9928"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]},{"id":"https://openalex.org/I4210143294","display_name":"Nikolaev Institute of Inorganic Chemistry","ror":"https://ror.org/04zpmt351","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210143294","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"E. V. Peresypkina","raw_affiliation_strings":["Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","Russian Academy of Sciences"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210127387","https://openalex.org/I4210143294"]},{"raw_affiliation_string":"Russian Academy of Sciences","institution_ids":["https://openalex.org/I1313323035"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036942222","display_name":"A.V. Virovets","orcid":"https://orcid.org/0000-0002-8843-8503","observed_orcids":["https://orcid.org/0000-0002-8843-8503"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210127387","display_name":"Siberian Branch of the Russian Academy of Sciences","ror":"https://ror.org/02frkq021","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210127387"]},{"id":"https://openalex.org/I4210143294","display_name":"Nikolaev Institute of Inorganic Chemistry","ror":"https://ror.org/04zpmt351","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210143294","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"A. V. Virovets","raw_affiliation_strings":["Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","Russian Academy of Sciences"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210127387","https://openalex.org/I4210143294"]},{"raw_affiliation_string":"Russian Academy of Sciences","institution_ids":["https://openalex.org/I1313323035"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109096238","display_name":"\u0415. \u0412. \u0427\u0435\u0440\u043a\u0430\u0441\u043e\u0432\u0430","orcid":"https://orcid.org/0009-0001-4696-3545","observed_orcids":["https://orcid.org/0009-0001-4696-3545"]},"institutions":[{"id":"https://openalex.org/I45791419","display_name":"Kuzbass State Technical University","ror":"https://ror.org/02hfhf494","country_code":"RU","type":"education","lineage":["https://openalex.org/I45791419"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"E. V. Cherkasova","raw_affiliation_strings":["Kuzbass State Technical University, Kemerovo, Russia","[Kuzbass State Technical University]"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kuzbass State Technical University, Kemerovo, Russia","institution_ids":["https://openalex.org/I45791419"]},{"raw_affiliation_string":"[Kuzbass State Technical University]","institution_ids":["https://openalex.org/I45791419"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111022380","display_name":"Tatyana Grigorievna Cherkasova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I45791419","display_name":"Kuzbass State Technical University","ror":"https://ror.org/02hfhf494","country_code":"RU","type":"education","lineage":["https://openalex.org/I45791419"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"T. G. Cherkasova","raw_affiliation_strings":["Kuzbass State Technical University, Kemerovo, Russia","[Kuzbass State Technical University]"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kuzbass State Technical University, Kemerovo, Russia","institution_ids":["https://openalex.org/I45791419"]},{"raw_affiliation_string":"[Kuzbass State Technical University]","institution_ids":["https://openalex.org/I45791419"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5111022380"],"corresponding_institution_ids":["https://openalex.org/I45791419"],"apc_list":null,"apc_paid":null,"fwci":0.3014,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.53231063,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":95},"biblio":{"volume":"57","issue":"5","first_page":"684","last_page":"691"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.003800000064074993,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.0032999999821186066,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ammonium-reineckate","display_name":"ammonium reineckate","score":0.8619999885559082},{"id":"https://openalex.org/keywords/caprolactam","display_name":"caprolactam","score":0.8420000076293945},{"id":"https://openalex.org/keywords/cr-iii-complexes","display_name":"chromium(III) complexes","score":0.8240000009536743},{"id":"https://openalex.org/keywords/isothiocyanate-ligands","display_name":"isothiocyanate ligands","score":0.871999979019165},{"id":"https://openalex.org/keywords/schiff-base-ligands","display_name":"Schiff base ligands","score":0.5109999775886536},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5720000267028809},{"id":"https://openalex.org/keywords/coordination-geometry","display_name":"coordination geometry","score":0.42800000309944153},{"id":"https://openalex.org/keywords/crystal-packing","display_name":"crystal packing","score":0.34200000762939453},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.5669999718666077},{"id":"https://openalex.org/keywords/ph-dependent-reaction","display_name":"pH-dependent reaction","score":0.3440000116825104},{"id":"https://openalex.org/keywords/aqueous-solutions","display_name":"aqueous solutions","score":0.5590000152587891},{"id":"https://openalex.org/keywords/supramolecular-networks","display_name":"supramolecular networks","score":0.4449999928474426},{"id":"https://openalex.org/keywords/supramolecular-chemistry","display_name":"supramolecular chemistry","score":0.41999998688697815},{"id":"https://openalex.org/keywords/supramolecular-polymorphism","display_name":"supramolecular polymorphism","score":0.49799999594688416},{"id":"https://openalex.org/keywords/supramolecular-topology","display_name":"supramolecular topology","score":0.3059999942779541}],"concepts":[{"id":"https://openalex.org/C42228675","wikidata":"https://www.wikidata.org/wiki/Q376927","display_name":"Triclinic crystal system","level":3,"score":0.805061399936676},{"id":"https://openalex.org/C2779537395","wikidata":"https://www.wikidata.org/wiki/Q409397","display_name":"Caprolactam","level":2,"score":0.7821338176727295},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.7522708773612976},{"id":"https://openalex.org/C2777873363","wikidata":"https://www.wikidata.org/wiki/Q13533436","display_name":"Tetra","level":2,"score":0.7338727712631226},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7261065244674683},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5513368844985962},{"id":"https://openalex.org/C2779870022","wikidata":"https://www.wikidata.org/wiki/Q190901","display_name":"Ammonium","level":2,"score":0.5322009921073914},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5100322365760803},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.5054116249084473},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.44165700674057007},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.38504019379615784},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.38165271282196045},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.15095379948616028},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.12688982486724854},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.09714251756668091}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1134/s0036023612030096","doi":"https://doi.org/10.1134/s0036023612030096","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s0036023612030096","pdf_url":null,"source":{"id":"https://openalex.org/S127769916","display_name":"Russian Journal of Inorganic Chemistry","issn_l":"0036-0236","issn":["0036-0236","1531-8613","3034-560X"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["dongbi-d","norway-1","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Russian Journal of Inorganic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":14,"referenced_works":["https://openalex.org/W390683569","https://openalex.org/W643549464","https://openalex.org/W2020336861","https://openalex.org/W2023884802","https://openalex.org/W2131350133","https://openalex.org/W2139042029","https://openalex.org/W2147304506","https://openalex.org/W2323460218","https://openalex.org/W2334386467","https://openalex.org/W2788471725","https://openalex.org/W3012250859","https://openalex.org/W3021865823","https://openalex.org/W4285719527","https://openalex.org/W6600248772"],"related_works":["https://openalex.org/W2023884802","https://openalex.org/W2365701598","https://openalex.org/W2037725329","https://openalex.org/W2589939646","https://openalex.org/W2605313459","https://openalex.org/W2039240850","https://openalex.org/W2006337818","https://openalex.org/W7049268491","https://openalex.org/W4239221753","https://openalex.org/W2950564172"],"abstract_inverted_index":{"A":[0],"reaction":[1],"of":[2,40,176],"ammonium":[3],"tetra(isothiocyanato)diamminechromate(III)":[4],"(ammonium":[5],"reineckate)":[6],"with":[7],"\u025b-caprolactam":[8,36,178],"in":[9],"aqueous":[10],"solution":[11],"at":[12],"different":[13],"pH":[14],"values":[15],"gave":[16],"the":[17,163,173,177,180,186],"novel":[18],"complexes":[19,41],"(NH4)[Cr(NH3)2(NCS)4]":[20,24],"\u00b7":[21,25,27],"7Cpl":[22],"(I),":[23],"2.5Cpl":[26],"0.5(H2O)":[28],"(II),":[29],"and":[30],"(HCpl2)[Cr(NH3)2(NCS)4]":[31],"(III),":[32],"where":[33],"Cpl":[34],"is":[35],"(\u025b-C6H11NO).":[37],"The":[38,149],"crystals":[39],"I\u2013III":[42],"are":[43],"triclinic,":[44],"space":[45],"group":[46],"$P\\bar":[47],"1$":[48],";":[49],"I:":[50],"a":[51,84,117,168],"=":[52,56,60,64,67,70,73,77,81,85,89,93,97,100,103,106,110,114,118,122,126,130,133,136,139,143,147],"12.7058(4)":[53],"\u00c5,":[54,58,62,87,91,95,120,124,128],"b":[55,88,121],"13.2544(4)":[57],"c":[59,92,125],"19.4487(7)":[61],"\u03b1":[63,96,129],"105.2360(10)\u00b0,":[65],"\u03b2":[66,99,132],"106.6410(10)\u00b0,":[68],"\u03b3":[69,102,135],"91.5290(10)\u00b0,":[71],"V":[72,105,138],"3009.37(17)":[74],"\u00c53,":[75,108,141],"\u03c1calc":[76,109,142],"1.245":[78],"g/cm3,":[79,112,145],"Z":[80,113,146],"2;":[82],"II:":[83],"12.3144(5)":[86],"12.6518(5)":[90],"23.3300(8)":[94],"75.4580(10)\u00b0,":[98],"80.0760(10)\u00b0,":[101],"61.0830(10)\u00b0,":[104],"3074.1(2)":[107],"1.358":[111],"4;":[115],"III:":[116],"6.4701(4)":[119],"12.5973(9)":[123],"16.5556(12)":[127],"108.769(2)\u00b0,":[131],"98.543(2)\u00b0,":[134],"90.345(2)\u00b0,":[137],"1261.36(15)":[140],"1.437":[144],"2.":[148],"structure":[150],"refinement":[151],"for":[152,185],"(HCpl2)3[Cr(NCS)6]":[153],"(IV)":[154],"was":[155,182],"revised.":[156],"Like":[157],"complex":[158,160],"III,":[159],"IV":[161],"contains":[162],"cation":[164,181],"(HCpl2)+":[165],"stabilized":[166],"by":[167],"strong":[169],"hydrogen":[170],"bond":[171],"between":[172],"O":[174],"atoms":[175],"molecules;":[179],"structurally":[183],"characterized":[184],"first":[187],"time.":[188]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2015,"cited_by_count":2}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}