{"id":"https://openalex.org/W1985479565","doi":"https://doi.org/10.1021/jp111151n","title":"Conformational Adaptation and Electronic Structure of 2H-Tetraphenylporphyrin on Ag(111) during Fe Metalation","display_name":"Conformational Adaptation and Electronic Structure of 2H-Tetraphenylporphyrin on Ag(111) during Fe Metalation","publication_year":2011,"publication_date":"2011-02-22","ids":{"openalex":"https://openalex.org/W1985479565","doi":"https://doi.org/10.1021/jp111151n","mag":"1985479565"},"language":"en","primary_location":{"id":"doi:10.1021/jp111151n","doi":"https://doi.org/10.1021/jp111151n","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp111151n","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5011974375","display_name":"Giovanni Di Santo","orcid":"https://orcid.org/0000-0001-9394-2563","observed_orcids":["https://orcid.org/0000-0001-9394-2563"]},"institutions":[{"id":"https://openalex.org/I2802561039","display_name":"Elettra-Sincrotrone Trieste S.C.p.A.","ror":"https://ror.org/01c3rrh15","country_code":"IT","type":"facility","lineage":["https://openalex.org/I2801626668","https://openalex.org/I2802561039"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Giovanni Di Santo","raw_affiliation_strings":["Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy","institution_ids":["https://openalex.org/I2802561039"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010979377","display_name":"Carla Castellarin-Cudia","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I2802561039","display_name":"Elettra-Sincrotrone Trieste S.C.p.A.","ror":"https://ror.org/01c3rrh15","country_code":"IT","type":"facility","lineage":["https://openalex.org/I2801626668","https://openalex.org/I2802561039"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Carla Castellarin-Cudia","raw_affiliation_strings":["Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy","institution_ids":["https://openalex.org/I2802561039"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089038012","display_name":"Mattia Fanetti","orcid":"https://orcid.org/0000-0002-2437-5179","observed_orcids":["https://orcid.org/0000-0002-2437-5179"]},"institutions":[{"id":"https://openalex.org/I2802561039","display_name":"Elettra-Sincrotrone Trieste S.C.p.A.","ror":"https://ror.org/01c3rrh15","country_code":"IT","type":"facility","lineage":["https://openalex.org/I2801626668","https://openalex.org/I2802561039"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Mattia Fanetti","raw_affiliation_strings":["Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy","institution_ids":["https://openalex.org/I2802561039"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062125728","display_name":"Bidini A. Taleatu","orcid":"https://orcid.org/0000-0001-7022-6118","observed_orcids":["https://orcid.org/0000-0001-7022-6118"]},"institutions":[{"id":"https://openalex.org/I12323705","display_name":"The Abdus Salam International Centre for Theoretical Physics (ICTP)","ror":"https://ror.org/009gyvm78","country_code":"IT","type":"facility","lineage":["https://openalex.org/I12323705","https://openalex.org/I1286959531","https://openalex.org/I1293226324","https://openalex.org/I2801247003"]},{"id":"https://openalex.org/I2802561039","display_name":"Elettra-Sincrotrone Trieste S.C.p.A.","ror":"https://ror.org/01c3rrh15","country_code":"IT","type":"facility","lineage":["https://openalex.org/I2801626668","https://openalex.org/I2802561039"]},{"id":"https://openalex.org/I45711476","display_name":"Obafemi Awolowo University","ror":"https://ror.org/04snhqa82","country_code":"NG","type":"education","lineage":["https://openalex.org/I45711476"]}],"countries":["IT","NG"],"is_corresponding":false,"raw_author_name":"Bidini Taleatu","raw_affiliation_strings":["Department of Physics, Obafemi Awolowo University - Ile-Ife, Nigeria","International Center of Theoretical Physics, St. Costiera 11, 34151 Trieste, Italy","Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics, Obafemi Awolowo University - Ile-Ife, Nigeria","institution_ids":["https://openalex.org/I45711476"]},{"raw_affiliation_string":"International Center of Theoretical Physics, St. Costiera 11, 34151 Trieste, Italy","institution_ids":["https://openalex.org/I12323705"]},{"raw_affiliation_string":"Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy","institution_ids":["https://openalex.org/I2802561039"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5107336253","display_name":"Patrizia Borghetti","orcid":"https://orcid.org/0000-0003-3290-9086","observed_orcids":["https://orcid.org/0000-0003-3290-9086"]},"institutions":[{"id":"https://openalex.org/I103320735","display_name":"Universit\u00e0 Cattolica del Sacro Cuore","ror":"https://ror.org/03h7r5v07","country_code":"IT","type":"education","lineage":["https://openalex.org/I103320735"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Patrizia Borghetti","raw_affiliation_strings":["Department of Physics, Universit\u00e0 Cattolica del Sacro Cuore Brescia, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics, Universit\u00e0 Cattolica del Sacro Cuore Brescia, Italy","institution_ids":["https://openalex.org/I103320735"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5031808751","display_name":"L. Sangaletti","orcid":"https://orcid.org/0000-0001-9312-5862","observed_orcids":["https://orcid.org/0000-0001-9312-5862"]},"institutions":[{"id":"https://openalex.org/I103320735","display_name":"Universit\u00e0 Cattolica del Sacro Cuore","ror":"https://ror.org/03h7r5v07","country_code":"IT","type":"education","lineage":["https://openalex.org/I103320735"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Luigi Sangaletti","raw_affiliation_strings":["Department of Physics, Universit\u00e0 Cattolica del Sacro Cuore Brescia, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Physics, Universit\u00e0 Cattolica del Sacro Cuore Brescia, Italy","institution_ids":["https://openalex.org/I103320735"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050423774","display_name":"Luca Floreano","orcid":"https://orcid.org/0000-0002-3654-3408","observed_orcids":["https://orcid.org/0000-0002-3654-3408"]},"institutions":[{"id":"https://openalex.org/I4210101608","display_name":"Istituto Officina dei Materiali","ror":"https://ror.org/00yfw2296","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210101608","https://openalex.org/I4210155236"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Luca Floreano","raw_affiliation_strings":["Istituto Officina dei Materiali-CNR, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Istituto Officina dei Materiali-CNR, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy","institution_ids":["https://openalex.org/I4210101608"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042035503","display_name":"Elena Magnano","orcid":"https://orcid.org/0000-0001-6465-807X","observed_orcids":["https://orcid.org/0000-0001-6465-807X"]},"institutions":[{"id":"https://openalex.org/I4210101608","display_name":"Istituto Officina dei Materiali","ror":"https://ror.org/00yfw2296","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210101608","https://openalex.org/I4210155236"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Elena Magnano","raw_affiliation_strings":["Istituto Officina dei Materiali-CNR, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Istituto Officina dei Materiali-CNR, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy","institution_ids":["https://openalex.org/I4210101608"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077767395","display_name":"Federica Bondino","orcid":"https://orcid.org/0000-0001-6505-9319","observed_orcids":["https://orcid.org/0000-0001-6505-9319"]},"institutions":[{"id":"https://openalex.org/I4210101608","display_name":"Istituto Officina dei Materiali","ror":"https://ror.org/00yfw2296","country_code":"IT","type":"facility","lineage":["https://openalex.org/I4210101608","https://openalex.org/I4210155236"]}],"countries":["IT"],"is_corresponding":false,"raw_author_name":"Federica Bondino","raw_affiliation_strings":["Istituto Officina dei Materiali-CNR, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Istituto Officina dei Materiali-CNR, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy","institution_ids":["https://openalex.org/I4210101608"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5042598526","display_name":"A. Goldoni","orcid":"https://orcid.org/0000-0001-9989-3889","observed_orcids":["https://orcid.org/0000-0001-9989-3889"]},"institutions":[{"id":"https://openalex.org/I2802561039","display_name":"Elettra-Sincrotrone Trieste S.C.p.A.","ror":"https://ror.org/01c3rrh15","country_code":"IT","type":"facility","lineage":["https://openalex.org/I2801626668","https://openalex.org/I2802561039"]}],"countries":["IT"],"is_corresponding":true,"raw_author_name":"Andrea Goldoni","raw_affiliation_strings":["Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Sincrotrone Trieste S.C.p.A. s.s.14 Km. 163.5, 34012 Trieste, Italy","institution_ids":["https://openalex.org/I2802561039"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5042598526"],"corresponding_institution_ids":["https://openalex.org/I2802561039"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.231,"has_fulltext":false,"cited_by_count":85,"citation_normalized_percentile":{"value":0.95700358,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"115","issue":"10","first_page":"4155","last_page":"4162"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.8598999977111816,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12285","display_name":"Surface Chemistry and Catalysis","score":0.8598999977111816,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.13099999725818634,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10913","display_name":"Molecular Junctions and Nanostructures","score":0.004999999888241291,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/iron-porphyrin","display_name":"iron porphyrin","score":0.8040000200271606},{"id":"https://openalex.org/keywords/ag-111","display_name":"Ag(111)","score":0.8889999985694885},{"id":"https://openalex.org/keywords/conformational-adaptation","display_name":"conformational adaptation","score":0.8880000114440918},{"id":"https://openalex.org/keywords/electronic-structure","display_name":"electronic structure","score":0.7409999966621399},{"id":"https://openalex.org/keywords/monolayer-adsorption","display_name":"monolayer adsorption","score":0.6110000014305115},{"id":"https://openalex.org/keywords/photoemission","display_name":"photoemission","score":0.8820000290870667},{"id":"https://openalex.org/keywords/charge-transfer","display_name":"charge transfer","score":0.7170000076293945},{"id":"https://openalex.org/keywords/metal-substrate-interaction","display_name":"metal-substrate interaction","score":0.6169999837875366},{"id":"https://openalex.org/keywords/ultra-high-vacuum","display_name":"ultrahigh vacuum","score":0.7540000081062317}],"concepts":[{"id":"https://openalex.org/C2778401137","wikidata":"https://www.wikidata.org/wiki/Q3985292","display_name":"Tetraphenylporphyrin","level":3,"score":0.9089834690093994},{"id":"https://openalex.org/C2775855785","wikidata":"https://www.wikidata.org/wiki/Q2270356","display_name":"Metalation","level":2,"score":0.826633632183075},{"id":"https://openalex.org/C7070889","wikidata":"https://www.wikidata.org/wiki/Q902488","display_name":"Monolayer","level":2,"score":0.7901929616928101},{"id":"https://openalex.org/C2779480358","wikidata":"https://www.wikidata.org/wiki/Q422926","display_name":"Porphyrin","level":2,"score":0.5989617705345154},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5910203456878662},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5571581125259399},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.49504223465919495},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.4720768928527832},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.4610947370529175},{"id":"https://openalex.org/C86025842","wikidata":"https://www.wikidata.org/wiki/Q5358432","display_name":"Electronic structure","level":2,"score":0.4196256697177887},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4144981801509857},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3820536434650421},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.28500181436538696},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.21336498856544495},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.18099772930145264},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0912531316280365},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jp111151n","doi":"https://doi.org/10.1021/jp111151n","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp111151n","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1552100057","https://openalex.org/W1971670691","https://openalex.org/W1976832485","https://openalex.org/W1977107653","https://openalex.org/W1977405828","https://openalex.org/W1979692823","https://openalex.org/W1980190258","https://openalex.org/W1991521158","https://openalex.org/W1996086056","https://openalex.org/W1998260542","https://openalex.org/W2008761313","https://openalex.org/W2012889524","https://openalex.org/W2028110208","https://openalex.org/W2030719255","https://openalex.org/W2031788637","https://openalex.org/W2051708176","https://openalex.org/W2059484645","https://openalex.org/W2080718857","https://openalex.org/W2088472901","https://openalex.org/W2093290320","https://openalex.org/W2120383161","https://openalex.org/W2120476692","https://openalex.org/W2127367521","https://openalex.org/W2138208692","https://openalex.org/W2151126694","https://openalex.org/W2152327709","https://openalex.org/W2171099129","https://openalex.org/W3004655996","https://openalex.org/W3188261643","https://openalex.org/W4241711684","https://openalex.org/W4247923851","https://openalex.org/W4248439880"],"related_works":["https://openalex.org/W1992726444","https://openalex.org/W1994934688","https://openalex.org/W2030719255","https://openalex.org/W76267424","https://openalex.org/W2095806939","https://openalex.org/W1009310373","https://openalex.org/W1987730697","https://openalex.org/W2143299877","https://openalex.org/W654811848","https://openalex.org/W2138208692"],"abstract_inverted_index":{"In-situ":[0],"metalation":[1,77],"of":[2,10,16,28,40,61,69],"porphyrin":[3],"molecules":[4],"in":[5,19],"ultrahigh":[6],"vacuum":[7],"(UHV)":[8],"is":[9],"great":[11],"interest":[12],"for":[13,75],"the":[14,26,29,33,38,58,62,76,83,94,101,105],"characterization":[15,27],"pure":[17,41],"species":[18],"a":[20,70],"controlled":[21],"environment.":[22],"Here,":[23],"we":[24],"report":[25],"electronic":[30],"states":[31],"and":[32,44,90],"molecules\u02bc":[34],"geometrical":[35],"adaptation":[36],"during":[37],"formation":[39],"2H-5,10,15,20-tetraphenylporphyrin":[42],"(2H-TPP)":[43],"Fe-":[45],"tetraphenylporphyrin":[46],"(Fe-TPP)":[47],"layers":[48],"on":[49],"Ag(111)":[50],"single":[51],"crystal.":[52],"Core":[53],"level":[54],"absorption":[55],"spectra":[56],"indicate":[57],"flat":[59],"conformation":[60],"monolayer":[63,95],"suggesting":[64],"an":[65],"adatom":[66],"hopping":[67],"instead":[68],"surface":[71],"mediated":[72],"dopant":[73],"diffusion":[74],"process.":[78],"Photoemission":[79],"points":[80],"out":[81],"that":[82],"interaction":[84],"between":[85],"Fe":[86],"d":[87],"z":[88],"-states":[89],"Ag":[91],"bands":[92],"increases":[93],"metallic":[96],"character":[97],"already":[98],"induced":[99],"by":[100],"charge":[102],"transfer":[103],"from":[104],"substrate.":[106]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":4},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":8},{"year":2020,"cited_by_count":6},{"year":2019,"cited_by_count":7},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":8},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":9},{"year":2012,"cited_by_count":9}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}