{"id":"https://openalex.org/W1985355154","doi":"https://doi.org/10.1007/s10570-011-9622-z","title":"First report on the kinetics of the uncatalyzed esterification of cellulose under homogeneous reaction conditions: a rationale for the effect of carboxylic acid anhydride chain-length on the degree of biopolymer substitution","display_name":"First report on the kinetics of the uncatalyzed esterification of cellulose under homogeneous reaction conditions: a rationale for the effect of carboxylic acid anhydride chain-length on the degree of biopolymer substitution","publication_year":2011,"publication_date":"2011-11-25","ids":{"openalex":"https://openalex.org/W1985355154","doi":"https://doi.org/10.1007/s10570-011-9622-z","mag":"1985355154"},"language":"en","primary_location":{"id":"doi:10.1007/s10570-011-9622-z","doi":"https://doi.org/10.1007/s10570-011-9622-z","is_oa":false,"landing_page_url":"https://doi.org/10.1007/s10570-011-9622-z","pdf_url":null,"source":{"id":"https://openalex.org/S130536152","display_name":"Cellulose","issn_l":"0969-0239","issn":["0969-0239","1572-882X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Cellulose","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5060080598","display_name":"Haq Nawaz","orcid":"https://orcid.org/0000-0003-0101-4335","observed_orcids":["https://orcid.org/0000-0003-0101-4335"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Haq Nawaz","raw_affiliation_strings":["Institute of Chemistry, University of S\u00e3o Paulo, P. O. B. 26077, S\u00e3o Paulo, SP, 05513-970, Brazil","Institute of Chemistry, University of Sao P\u00e3ulo, S\u00e3o Paulo, Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Chemistry, University of S\u00e3o Paulo, P. O. B. 26077, S\u00e3o Paulo, SP, 05513-970, Brazil","institution_ids":["https://openalex.org/I17974374"]},{"raw_affiliation_string":"Institute of Chemistry, University of Sao P\u00e3ulo, S\u00e3o Paulo, Brazil","institution_ids":["https://openalex.org/I17974374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061970822","display_name":"Romeu Casarano","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Romeu Casarano","raw_affiliation_strings":["Institute of Chemistry, University of S\u00e3o Paulo, P. O. B. 26077, S\u00e3o Paulo, SP, 05513-970, Brazil","Institute of Chemistry, University of Sao P\u00e3ulo, S\u00e3o Paulo, Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Chemistry, University of S\u00e3o Paulo, P. O. B. 26077, S\u00e3o Paulo, SP, 05513-970, Brazil","institution_ids":["https://openalex.org/I17974374"]},{"raw_affiliation_string":"Institute of Chemistry, University of Sao P\u00e3ulo, S\u00e3o Paulo, Brazil","institution_ids":["https://openalex.org/I17974374"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5032254338","display_name":"Omar A. El Seoud","orcid":"https://orcid.org/0000-0003-1683-5953","observed_orcids":["https://orcid.org/0000-0003-1683-5953"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]}],"countries":["BR"],"is_corresponding":true,"raw_author_name":"Omar A. El Seoud","raw_affiliation_strings":["Institute of Chemistry, University of S\u00e3o Paulo, P. O. B. 26077, S\u00e3o Paulo, SP, 05513-970, Brazil","Institute of Chemistry, University of Sao P\u00e3ulo, S\u00e3o Paulo, Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Chemistry, University of S\u00e3o Paulo, P. O. B. 26077, S\u00e3o Paulo, SP, 05513-970, Brazil","institution_ids":["https://openalex.org/I17974374"]},{"raw_affiliation_string":"Institute of Chemistry, University of Sao P\u00e3ulo, S\u00e3o Paulo, Brazil","institution_ids":["https://openalex.org/I17974374"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5032254338"],"corresponding_institution_ids":["https://openalex.org/I17974374"],"apc_list":{"value":4390,"currency":"USD","value_usd":4390},"apc_paid":null,"fwci":1.3093,"has_fulltext":false,"cited_by_count":33,"citation_normalized_percentile":{"value":0.75697615,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"19","issue":"1","first_page":"199","last_page":"207"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10610","display_name":"Advanced Cellulose Research Studies","score":0.9854000210762024,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10610","display_name":"Advanced Cellulose Research Studies","score":0.9854000210762024,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12192","display_name":"Polysaccharides Composition and Applications","score":0.0017999999690800905,"subfield":{"id":"https://openalex.org/subfields/1106","display_name":"Food Science"},"field":{"id":"https://openalex.org/fields/11","display_name":"Agricultural and Biological Sciences"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10869","display_name":"Polysaccharides and Plant Cell Walls","score":0.0017999999690800905,"subfield":{"id":"https://openalex.org/subfields/1110","display_name":"Plant Science"},"field":{"id":"https://openalex.org/fields/11","display_name":"Agricultural and Biological Sciences"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cellulose-esterification","display_name":"cellulose esterification","score":0.875},{"id":"https://openalex.org/keywords/acylation-kinetics","display_name":"acylation kinetics","score":0.7699999809265137},{"id":"https://openalex.org/keywords/microcrystalline-cellulose","display_name":"microcrystalline cellulose","score":0.902999997138977},{"id":"https://openalex.org/keywords/carboxylic-anhydrides","display_name":"carboxylic acid anhydrides","score":0.9760000109672546},{"id":"https://openalex.org/keywords/acyl-chain-length","display_name":"acyl chain length","score":0.8809999823570251},{"id":"https://openalex.org/keywords/degree-of-substitution","display_name":"degree of substitution","score":0.7400000095367432},{"id":"https://openalex.org/keywords/trans-1-2-cyclohexanediol","display_name":"trans-1,2-cyclohexanediol","score":0.9919999837875366},{"id":"https://openalex.org/keywords/enthalpy-and-entropy-of-activation","display_name":"activation enthalpy and entropy","score":0.8190000057220459}],"concepts":[{"id":"https://openalex.org/C193557335","wikidata":"https://www.wikidata.org/wiki/Q61424","display_name":"Acylation","level":3,"score":0.7770675420761108},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6962558627128601},{"id":"https://openalex.org/C2779251873","wikidata":"https://www.wikidata.org/wiki/Q80294","display_name":"Cellulose","level":2,"score":0.6278290748596191},{"id":"https://openalex.org/C2779351475","wikidata":"https://www.wikidata.org/wiki/Q417374","display_name":"Microcrystalline cellulose","level":3,"score":0.5872479677200317},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.5367449522018433},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4606483280658722},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.45749765634536743},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4490547478199005},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.42263540625572205},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.41951581835746765},{"id":"https://openalex.org/C2779074116","wikidata":"https://www.wikidata.org/wiki/Q134856","display_name":"Carboxylic acid","level":2,"score":0.41693180799484253},{"id":"https://openalex.org/C13723534","wikidata":"https://www.wikidata.org/wiki/Q367131","display_name":"Entropy of activation","level":4,"score":0.41346442699432373},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.26111099123954773},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.09075403213500977},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1007/s10570-011-9622-z","doi":"https://doi.org/10.1007/s10570-011-9622-z","is_oa":false,"landing_page_url":"https://doi.org/10.1007/s10570-011-9622-z","pdf_url":null,"source":{"id":"https://openalex.org/S130536152","display_name":"Cellulose","issn_l":"0969-0239","issn":["0969-0239","1572-882X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Cellulose","raw_type":"journal-article"},{"id":"pmh:oai:www.producao.usp.br:BDPI/34036","doi":null,"is_oa":false,"landing_page_url":"http://www.producao.usp.br/handle/BDPI/34036","pdf_url":null,"source":{"id":"https://openalex.org/S4306401373","display_name":"Scientific Electronic Library Online (S\u00e3o Paulo Research Foundation, Latin American and Caribbean Center on Health Sciences Information, Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I2982035970","host_organization_name":"Costa Rican Department of Social Security","host_organization_lineage":["https://openalex.org/I2982035970"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"","raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320997","display_name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","ror":"https://ror.org/02ddkpn78"},{"id":"https://openalex.org/F4320326304","display_name":"Consejo Nacional para Investigaciones Cient\u00edficas y Tecnol\u00f3gicas","ror":"https://ror.org/011fq2d43"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":39,"referenced_works":["https://openalex.org/W620132298","https://openalex.org/W640137375","https://openalex.org/W658459357","https://openalex.org/W1968707830","https://openalex.org/W1976550411","https://openalex.org/W1977429866","https://openalex.org/W1978429264","https://openalex.org/W1978521559","https://openalex.org/W1999625725","https://openalex.org/W2003136985","https://openalex.org/W2005241027","https://openalex.org/W2005725452","https://openalex.org/W2005805030","https://openalex.org/W2008717507","https://openalex.org/W2013530619","https://openalex.org/W2015126796","https://openalex.org/W2022381070","https://openalex.org/W2033365358","https://openalex.org/W2046761411","https://openalex.org/W2053508649","https://openalex.org/W2054791240","https://openalex.org/W2057728381","https://openalex.org/W2070229990","https://openalex.org/W2073151768","https://openalex.org/W2088890518","https://openalex.org/W2093033465","https://openalex.org/W2116136372","https://openalex.org/W2155649389","https://openalex.org/W2313972826","https://openalex.org/W2324595407","https://openalex.org/W2462013614","https://openalex.org/W2477690752","https://openalex.org/W2478995755","https://openalex.org/W2483473499","https://openalex.org/W2495348596","https://openalex.org/W2951746867","https://openalex.org/W3004157836","https://openalex.org/W3011759179","https://openalex.org/W4239146293"],"related_works":["https://openalex.org/W2057728381","https://openalex.org/W2093033465","https://openalex.org/W2020605416","https://openalex.org/W2068018657","https://openalex.org/W2005241027","https://openalex.org/W7120600355","https://openalex.org/W2075283153","https://openalex.org/W2145232771","https://openalex.org/W2165454147","https://openalex.org/W4379614976"],"abstract_inverted_index":null,"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":5},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":3}],"updated_date":"2026-09-04T10:56:28.161419","created_date":"2016-06-24T00:00:00"}