{"id":"https://openalex.org/W1985283158","doi":"https://doi.org/10.1063/1.464072","title":"A molecular model for tilting phase transitions between condensed phases of Langmuir monolayers","display_name":"A molecular model for tilting phase transitions between condensed phases of Langmuir monolayers","publication_year":1993,"publication_date":"1993-02-15","ids":{"openalex":"https://openalex.org/W1985283158","doi":"https://doi.org/10.1063/1.464072","mag":"1985283158"},"language":"en","primary_location":{"id":"doi:10.1063/1.464072","doi":"https://doi.org/10.1063/1.464072","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.464072","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5011985395","display_name":"Vladimir M. Kaganer","orcid":"https://orcid.org/0000-0001-9146-8503","observed_orcids":["https://orcid.org/0000-0001-9146-8503"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210132917","display_name":"A.V. Shubnikov Institute of Crystallography","ror":"https://ror.org/049ecjx61","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210096333","https://openalex.org/I4210132917"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"V. M. Kaganer","raw_affiliation_strings":["Institute of Crystallography, Russian Academy of Sciences, Leninskii pr.59, 117333 Moscow, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Crystallography, Russian Academy of Sciences, Leninskii pr.59, 117333 Moscow, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210132917"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108435138","display_name":"M. A. Osipov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4577782","display_name":"Technische Universit\u00e4t Berlin","ror":"https://ror.org/03v4gjf40","country_code":"DE","type":"education","lineage":["https://openalex.org/I4577782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"M. A. Osipov","raw_affiliation_strings":["Institut f\u00fcr Theoretische Physik, Technische Universit\u00e4t Berlin, PN 7-1, Handenbergstrasse 36, D 1000 Berlin 12, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Theoretische Physik, Technische Universit\u00e4t Berlin, PN 7-1, Handenbergstrasse 36, D 1000 Berlin 12, Germany","institution_ids":["https://openalex.org/I4577782"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111754882","display_name":"I. R. Peterson","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"I. R. Peterson","raw_affiliation_strings":["Institut f\u00fcr Physikalische Chemie, Johannes Gutenberg Universit\u00e4t, Jakob Welder Weg 11, D 6500 Mainz, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Physikalische Chemie, Johannes Gutenberg Universit\u00e4t, Jakob Welder Weg 11, D 6500 Mainz, Germany","institution_ids":["https://openalex.org/I197323543"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":5.1032,"has_fulltext":false,"cited_by_count":54,"citation_normalized_percentile":{"value":0.96678606,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"98","issue":"4","first_page":"3512","last_page":"3527"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":0.8070999979972839,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10306","display_name":"Liquid Crystal Research Advancements","score":0.8070999979972839,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10591","display_name":"Theoretical and Computational Physics","score":0.06830000132322311,"subfield":{"id":"https://openalex.org/subfields/3104","display_name":"Condensed Matter Physics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10407","display_name":"Lipid Membrane Structure and Behavior","score":0.04749999940395355,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/langmuir-monolayers","display_name":"Langmuir monolayers","score":0.9929999709129333},{"id":"https://openalex.org/keywords/rigid-rod-model","display_name":"rigid rod model","score":0.9089999794960022},{"id":"https://openalex.org/keywords/hexatic-order","display_name":"hexatic order","score":0.8230000138282776},{"id":"https://openalex.org/keywords/orientational-entropy","display_name":"orientational entropy","score":0.722000002861023},{"id":"https://openalex.org/keywords/steric-repulsion","display_name":"steric repulsion","score":0.9200000166893005},{"id":"https://openalex.org/keywords/van-der-waals-attraction","display_name":"van der Waals attraction","score":0.9750000238418579},{"id":"https://openalex.org/keywords/hexagonal-close-packed-structure","display_name":"hexagonal close-packed structure","score":0.8659999966621399},{"id":"https://openalex.org/keywords/first-order-phase-transition","display_name":"first-order phase transition","score":0.843999981880188},{"id":"https://openalex.org/keywords/second-order-phase-transition","display_name":"second-order phase transition","score":0.9449999928474426},{"id":"https://openalex.org/keywords/area-per-molecule","display_name":"area per molecule","score":0.7390000224113464},{"id":"https://openalex.org/keywords/long-chain-molecules","display_name":"long-chain molecules","score":0.5920000076293945},{"id":"https://openalex.org/keywords/mean-field-approximation","display_name":"mean-field approximation","score":0.7689999938011169}],"concepts":[{"id":"https://openalex.org/C7070889","wikidata":"https://www.wikidata.org/wiki/Q902488","display_name":"Monolayer","level":2,"score":0.8914425373077393},{"id":"https://openalex.org/C126061179","wikidata":"https://www.wikidata.org/wiki/Q189627","display_name":"van der Waals force","level":3,"score":0.6325526237487793},{"id":"https://openalex.org/C149288129","wikidata":"https://www.wikidata.org/wiki/Q185357","display_name":"Phase transition","level":2,"score":0.5985920429229736},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5668284296989441},{"id":"https://openalex.org/C162184086","wikidata":"https://www.wikidata.org/wiki/Q505544","display_name":"Rod","level":3,"score":0.5573446750640869},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5434108972549438},{"id":"https://openalex.org/C2779844322","wikidata":"https://www.wikidata.org/wiki/Q2919140","display_name":"Tilt (camera)","level":2,"score":0.5084542036056519},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5006625652313232},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.4885495603084564},{"id":"https://openalex.org/C90626534","wikidata":"https://www.wikidata.org/wiki/Q4523381","display_name":"Hexagonal lattice","level":3,"score":0.4832616448402405},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.46500739455223083},{"id":"https://openalex.org/C2781204021","wikidata":"https://www.wikidata.org/wiki/Q6497091","display_name":"Lattice (music)","level":2,"score":0.4465590715408325},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.41944774985313416},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.4169886112213135},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.34135007858276367},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.2722850441932678},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.21953922510147095},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.09296262264251709},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C155355069","wikidata":"https://www.wikidata.org/wiki/Q575224","display_name":"Antiferromagnetism","level":2,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C24890656","wikidata":"https://www.wikidata.org/wiki/Q82811","display_name":"Acoustics","level":1,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.464072","doi":"https://doi.org/10.1063/1.464072","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.464072","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320308269","display_name":"Alexander von Humboldt-Stiftung","ror":"https://ror.org/012kf4317"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":56,"referenced_works":["https://openalex.org/W1963695814","https://openalex.org/W1966424963","https://openalex.org/W1973869419","https://openalex.org/W1976565467","https://openalex.org/W1977044855","https://openalex.org/W1982003973","https://openalex.org/W1987621436","https://openalex.org/W1988778563","https://openalex.org/W1990024899","https://openalex.org/W1990552566","https://openalex.org/W1990730547","https://openalex.org/W1994737969","https://openalex.org/W1997015726","https://openalex.org/W2002397648","https://openalex.org/W2005209695","https://openalex.org/W2009659568","https://openalex.org/W2010129065","https://openalex.org/W2011538612","https://openalex.org/W2012519722","https://openalex.org/W2015595640","https://openalex.org/W2018037758","https://openalex.org/W2019750783","https://openalex.org/W2021142922","https://openalex.org/W2022827633","https://openalex.org/W2024212557","https://openalex.org/W2026647854","https://openalex.org/W2032477252","https://openalex.org/W2033411687","https://openalex.org/W2035712563","https://openalex.org/W2039044721","https://openalex.org/W2039696862","https://openalex.org/W2041718558","https://openalex.org/W2046169131","https://openalex.org/W2064975101","https://openalex.org/W2066244721","https://openalex.org/W2066380048","https://openalex.org/W2068279800","https://openalex.org/W2069747066","https://openalex.org/W2072502436","https://openalex.org/W2076448195","https://openalex.org/W2077706662","https://openalex.org/W2078328526","https://openalex.org/W2079610729","https://openalex.org/W2088831649","https://openalex.org/W2089148829","https://openalex.org/W2090426221","https://openalex.org/W2091522031","https://openalex.org/W2092680833","https://openalex.org/W2101032950","https://openalex.org/W2119281732","https://openalex.org/W2135761356","https://openalex.org/W2136679488","https://openalex.org/W2159255236","https://openalex.org/W2163429420","https://openalex.org/W2323278574","https://openalex.org/W2476609189"],"related_works":["https://openalex.org/W98587895","https://openalex.org/W2008401841","https://openalex.org/W2012791063","https://openalex.org/W2050960210","https://openalex.org/W1970828335","https://openalex.org/W2074936235","https://openalex.org/W2089148829","https://openalex.org/W2124634661","https://openalex.org/W2017557786","https://openalex.org/W1993637673"],"abstract_inverted_index":{"A":[0],"model":[1,25,63,258],"of":[2,15,45,61,136,164,170,202,246,256],"interacting":[3],"rigid":[4],"rods":[5,38,122,138],"is":[6,176,196],"proposed":[7],"to":[8,55,81,95,97,124,140,217],"describe":[9],"tilting":[10],"phase":[11,158,230],"transitions":[12],"in":[13,88,118,132,167,227,243],"monolayers":[14],"freely":[16],"rotating":[17],"long-chain":[18],"molecules":[19,166],"with":[20,66,206,239,253,261,265],"hexatic":[21],"in-plane":[22],"order.":[23],"The":[24,116,250],"takes":[26],"into":[27],"account":[28],"steric":[29],"repulsion":[30],"and":[31,87,182,221,264],"van":[32],"der":[33],"Waals":[34],"attraction":[35],"between":[36,121,151],"neighboring":[37],"as":[39,41],"well":[40],"the":[42,56,62,70,75,77,89,91,98,101,113,119,126,130,133,137,144,149,156,165,168,171,180,183,187,190,193,203,207,212,228,240,244,247,254],"orientational":[43],"entropy":[44],"individual":[46],"rods,":[47],"all":[48],"within":[49],"a":[50,82,104,235],"mean":[51],"field":[52],"approximation":[53],"limited":[54],"unit":[57],"cell.":[58],"Two":[59],"variants":[60],"are":[64,79,259],"proposed,":[65],"different":[67],"constraints":[68],"on":[69,103,112,189],"polar":[71,204],"molecular":[72,194],"headgroups.":[73],"In":[74,209],"first,":[76],"headgroups":[78],"grafted":[80],"hexagonal":[83],"close-packed":[84],"(hcp)":[85],"lattice,":[86],"second,":[90],"headgroup":[92],"lattice":[93],"deforms":[94],"accommodate":[96],"tilt.":[99],"For":[100,186],"monolayer":[102,188],"solid":[105],"substrate,":[106],"tilt":[107,163,195,242],"has":[108],"two":[109,153],"opposing":[110],"actions":[111],"internal":[114],"energy.":[115],"decrease":[117,131],"distance":[120],"acts":[123,139],"reduce":[125],"interaction":[127,214],"energy,":[128],"while":[129],"overlapping":[134],"length":[135],"increase":[141],"it.":[142],"As":[143],"area":[145],"per":[146],"molecule":[147],"increases,":[148],"competition":[150],"these":[152],"effects":[154],"drives":[155],"first-order":[157,229],"transition":[159,175,231],"U(untilted":[160],"molecules)\u2192NNN":[161],"(collective":[162],"direction":[169,245],"next-nearest":[172],"neighbor).":[173],"This":[174],"present":[177],"for":[178],"both":[179],"fixed":[181],"deformable":[184],"lattices.":[185],"water":[191],"surface,":[192],"accompanied":[197],"by":[198,234],"an":[199],"increasing":[200],"contact":[201],"heads":[205],"water.":[208],"this":[210,257],"case,":[211],"effective":[213],"potential":[215],"appears":[216],"be":[218],"temperature":[219],"dependent":[220],"under":[222],"some":[223],"circumstances":[224],"can":[225],"result":[226],"being":[232],"replaced":[233],"second-order":[236],"one":[237],"(U\u2192NN)":[238],"collective":[241],"nearest":[248],"neighbor.":[249],"results":[251],"obtained":[252],"help":[255],"compared":[260],"computer":[262],"simulations":[263],"experiment.":[266]},"counts_by_year":[{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2015,"cited_by_count":2},{"year":2012,"cited_by_count":1}],"updated_date":"2026-05-21T06:26:12.895304","created_date":"2016-06-24T00:00:00"}