{"id":"https://openalex.org/W1985264017","doi":"https://doi.org/10.1366/00037020360625998","title":"Monitoring the Formation and Decay of Transient Photosensitized Intermediates Using Pump-Probe UV Resonance Raman Spectroscopy. II: Kinetic Modeling and Multidimensional Least-Squares Analysis","display_name":"Monitoring the Formation and Decay of Transient Photosensitized Intermediates Using Pump-Probe UV Resonance Raman Spectroscopy. II: Kinetic Modeling and Multidimensional Least-Squares Analysis","publication_year":2003,"publication_date":"2003-04-01","ids":{"openalex":"https://openalex.org/W1985264017","doi":"https://doi.org/10.1366/00037020360625998","mag":"1985264017","pmid":"https://pubmed.ncbi.nlm.nih.gov/14658642"},"language":"en","primary_location":{"id":"doi:10.1366/00037020360625998","doi":"https://doi.org/10.1366/00037020360625998","is_oa":false,"landing_page_url":"https://doi.org/10.1366/00037020360625998","pdf_url":null,"source":{"id":"https://openalex.org/S67069294","display_name":"Applied Spectroscopy","issn_l":"0003-7028","issn":["0003-7028","1943-3530"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","medline","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320017","host_organization_name":"SAGE Publishing","host_organization_lineage":["https://openalex.org/P4310320017"],"host_organization_lineage_names":["SAGE Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Applied Spectroscopy","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5032619164","display_name":"James A. Kleimeyer","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I223532165","display_name":"University of Utah","ror":"https://ror.org/03r0ha626","country_code":"US","type":"education","lineage":["https://openalex.org/I223532165"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James A. Kleimeyer","raw_affiliation_strings":["Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850","institution_ids":["https://openalex.org/I223532165"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5078927573","display_name":"Joel Mark Harris","orcid":"https://orcid.org/0000-0002-7081-8188","observed_orcids":["https://orcid.org/0000-0002-7081-8188"]},"institutions":[{"id":"https://openalex.org/I223532165","display_name":"University of Utah","ror":"https://ror.org/03r0ha626","country_code":"US","type":"education","lineage":["https://openalex.org/I223532165"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joel M. Harris","raw_affiliation_strings":["Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850","institution_ids":["https://openalex.org/I223532165"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I223532165"],"apc_list":{"value":4400,"currency":"USD","value_usd":4400},"apc_paid":null,"fwci":0.4651,"has_fulltext":false,"cited_by_count":4,"citation_normalized_percentile":{"value":0.55752488,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"57","issue":"4","first_page":"448","last_page":"453"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.7651000022888184,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.7651000022888184,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10640","display_name":"Spectroscopy and Chemometric Analyses","score":0.10080000013113022,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.07649999856948853,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/benzophenone","display_name":"benzophenone","score":0.7540000081062317},{"id":"https://openalex.org/keywords/triplet-state","display_name":"triplet state","score":0.7599999904632568},{"id":"https://openalex.org/keywords/h-atom-abstraction","display_name":"H-atom abstraction","score":0.8640000224113464},{"id":"https://openalex.org/keywords/kinetic-modeling","display_name":"kinetic modeling","score":0.6320000290870667},{"id":"https://openalex.org/keywords/self-modeling-curve-resolution","display_name":"self-modeling curve resolution","score":0.8970000147819519},{"id":"https://openalex.org/keywords/factor-analysis","display_name":"factor analysis","score":0.796999990940094},{"id":"https://openalex.org/keywords/radical-recombination","display_name":"radical recombination","score":0.7519999742507935}],"concepts":[{"id":"https://openalex.org/C2778128264","wikidata":"https://www.wikidata.org/wiki/Q900863","display_name":"Ketyl","level":3,"score":0.8512873649597168},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7794987559318542},{"id":"https://openalex.org/C2778279444","wikidata":"https://www.wikidata.org/wiki/Q409482","display_name":"Benzophenone","level":2,"score":0.7243305444717407},{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.6958301663398743},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.6524856090545654},{"id":"https://openalex.org/C2781340169","wikidata":"https://www.wikidata.org/wiki/Q7315737","display_name":"Resonance Raman spectroscopy","level":3,"score":0.5512901544570923},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.5250033140182495},{"id":"https://openalex.org/C76766466","wikidata":"https://www.wikidata.org/wiki/Q3036629","display_name":"Triplet state","level":3,"score":0.502739429473877},{"id":"https://openalex.org/C169573571","wikidata":"https://www.wikidata.org/wiki/Q466824","display_name":"Raman scattering","level":3,"score":0.45920780301094055},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.44627413153648376},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.442449688911438},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.19055625796318054},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.17098656296730042},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.07893133163452148},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.06797000765800476},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D000465","descriptor_name":"Algorithms","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D000588","descriptor_name":"Amines","qualifier_ui":"Q000528","qualifier_name":"radiation effects","is_major_topic":false},{"descriptor_ui":"D000588","descriptor_name":"Amines","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D001577","descriptor_name":"Benzophenones","qualifier_ui":"Q000528","qualifier_name":"radiation effects","is_major_topic":false},{"descriptor_ui":"D001577","descriptor_name":"Benzophenones","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007834","descriptor_name":"Lasers","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D008968","descriptor_name":"Molecular Conformation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010777","descriptor_name":"Photochemistry","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D013056","descriptor_name":"Spectrophotometry, Ultraviolet","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D013059","descriptor_name":"Spectrum Analysis, Raman","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D016018","descriptor_name":"Least-Squares Analysis","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D017319","descriptor_name":"Photosensitizing Agents","qualifier_ui":"Q000528","qualifier_name":"radiation effects","is_major_topic":false},{"descriptor_ui":"D017319","descriptor_name":"Photosensitizing Agents","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1366/00037020360625998","doi":"https://doi.org/10.1366/00037020360625998","is_oa":false,"landing_page_url":"https://doi.org/10.1366/00037020360625998","pdf_url":null,"source":{"id":"https://openalex.org/S67069294","display_name":"Applied Spectroscopy","issn_l":"0003-7028","issn":["0003-7028","1943-3530"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","medline","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320017","host_organization_name":"SAGE Publishing","host_organization_lineage":["https://openalex.org/P4310320017"],"host_organization_lineage_names":["SAGE Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Applied Spectroscopy","raw_type":"journal-article"},{"id":"pmid:14658642","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/14658642","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Applied spectroscopy","raw_type":"Comparative Study"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":30,"referenced_works":["https://openalex.org/W86660280","https://openalex.org/W1964964139","https://openalex.org/W1972326413","https://openalex.org/W1974846593","https://openalex.org/W1974912007","https://openalex.org/W1982309347","https://openalex.org/W1986157931","https://openalex.org/W1993343612","https://openalex.org/W2004528774","https://openalex.org/W2004808208","https://openalex.org/W2005141749","https://openalex.org/W2006099880","https://openalex.org/W2012761071","https://openalex.org/W2026752499","https://openalex.org/W2029742513","https://openalex.org/W2048766065","https://openalex.org/W2061966319","https://openalex.org/W2069946229","https://openalex.org/W2073275614","https://openalex.org/W2074867833","https://openalex.org/W2076487377","https://openalex.org/W2082290593","https://openalex.org/W2088907427","https://openalex.org/W2093929694","https://openalex.org/W2324072193","https://openalex.org/W2951024732","https://openalex.org/W2952085953","https://openalex.org/W3004586357","https://openalex.org/W3004697493","https://openalex.org/W3004893275"],"related_works":["https://openalex.org/W2004808208","https://openalex.org/W1977676909","https://openalex.org/W2069946229","https://openalex.org/W4321080736","https://openalex.org/W2068664218","https://openalex.org/W371996142","https://openalex.org/W394968220","https://openalex.org/W2030733790","https://openalex.org/W1993343612","https://openalex.org/W85510578"],"abstract_inverted_index":{"Analysis":[0],"of":[1,29,38,71,109,124,139],"transient":[2,12],"excited-state":[3],"Raman":[4,31,103,127],"spectra":[5,32,138],"is":[6,93,119],"a":[7,47,60],"challenging":[8],"spectroscopic":[9],"measurement":[10],"since":[11],"spectral":[13,115],"features":[14],"are":[15,66],"often":[16],"overlapped":[17],"with":[18,68,158],"dominant":[19],"ground-state":[20,150],"and":[21,80,106,134,146,149,162],"solvent":[22,148],"bands.":[23],"In":[24],"the":[25,34,57,69,78,96,101,107,122,125,147,159],"previous":[26],"manuscript,":[27],"resolution":[28],"component":[30],"from":[33,77],"time-resolved":[35],"amine":[36,79],"quenching":[37],"excited-triplet":[39,141],"benzophenone":[40,140],"was":[41],"accomplished":[42],"using":[43,130],"self-modeling":[44],"curve":[45],"resolution,":[46],"model-free":[48],"factor":[49],"analysis":[50,123],"technique":[51],"that":[52],"relies":[53],"on":[54,100],"correlation":[55],"in":[56,95],"data":[58,105,129],"along":[59],"changing":[61],"composition":[62],"dimension.":[63],"The":[64,117,152],"results":[65],"consistent":[67],"production":[70],"diphenylketyl":[72],"radicals":[73],"by":[74,84,113],"H-atom":[75],"abstraction":[76],"subsequent":[81],"free-radical":[82],"decay":[83],"recombination":[85],"reactions.":[86],"A":[87],"kinetic":[88,154],"model":[89,118],"for":[90],"this":[91],"chemistry":[92],"developed":[94],"present":[97],"work,":[98],"based":[99],"observed":[102],"scattering":[104,128],"structures":[108],"product":[110],"species":[111],"confirmed":[112],"mass":[114],"analysis.":[116],"applied":[120],"to":[121],"time-dependent":[126,160],"multidimensional":[131],"least-squares":[132],"methods,":[133],"it":[135],"yielded":[136],"well-resolved":[137],"states,":[142],"diphenyl":[143],"ketyl":[144],"radical,":[145],"precursors.":[151],"best-fit":[153],"parameters":[155],"agree":[156],"well":[157],"triplet-state":[161],"ketyl-radical":[163],"concentration":[164],"profiles.":[165]},"counts_by_year":[{"year":2016,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}