{"id":"https://openalex.org/W1983709591","doi":"https://doi.org/10.1021/cm010281p","title":"Effect of Substitution on the Electrochemical and Xerographic Properties of Triarylamines: Correlation to the Hammett Parameter of the Substituent and Calculated HOMO Energy Level","display_name":"Effect of Substitution on the Electrochemical and Xerographic Properties of Triarylamines: Correlation to the Hammett Parameter of the Substituent and Calculated HOMO Energy Level","publication_year":2001,"publication_date":"2001-10-30","ids":{"openalex":"https://openalex.org/W1983709591","doi":"https://doi.org/10.1021/cm010281p","mag":"1983709591"},"language":"en","primary_location":{"id":"doi:10.1021/cm010281p","doi":"https://doi.org/10.1021/cm010281p","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cm010281p","pdf_url":null,"source":{"id":"https://openalex.org/S66104727","display_name":"Chemistry of Materials","issn_l":"0897-4756","issn":["0897-4756","1520-5002"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry of Materials","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5088168772","display_name":"Timothy P. Bender","orcid":"https://orcid.org/0000-0002-6086-7445","observed_orcids":["https://orcid.org/0000-0002-6086-7445"]},"institutions":[{"id":"https://openalex.org/I4210159094","display_name":"Xerox (Canada)","ror":"https://ror.org/04z9w5078","country_code":"CA","type":"company","lineage":["https://openalex.org/I4210132870","https://openalex.org/I4210159094"]}],"countries":["CA"],"is_corresponding":true,"raw_author_name":"Timothy P. Bender","raw_affiliation_strings":["Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario, Canada L5K 2L1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario, Canada L5K 2L1","institution_ids":["https://openalex.org/I4210159094"]}]},{"author_position":"middle","author":{"id":null,"display_name":"John F. Graham","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210159094","display_name":"Xerox (Canada)","ror":"https://ror.org/04z9w5078","country_code":"CA","type":"company","lineage":["https://openalex.org/I4210132870","https://openalex.org/I4210159094"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"John F. Graham","raw_affiliation_strings":["Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario, Canada L5K 2L1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario, Canada L5K 2L1","institution_ids":["https://openalex.org/I4210159094"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5113666867","display_name":"J. M. Duff","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210159094","display_name":"Xerox (Canada)","ror":"https://ror.org/04z9w5078","country_code":"CA","type":"company","lineage":["https://openalex.org/I4210132870","https://openalex.org/I4210159094"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"James M. Duff","raw_affiliation_strings":["Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario, Canada L5K 2L1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario, Canada L5K 2L1","institution_ids":["https://openalex.org/I4210159094"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5088168772"],"corresponding_institution_ids":["https://openalex.org/I4210159094"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.5099,"has_fulltext":false,"cited_by_count":90,"citation_normalized_percentile":{"value":0.8798169,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"13","issue":"11","first_page":"4105","last_page":"4111"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.4595000147819519,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.4595000147819519,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10660","display_name":"Conducting polymers and applications","score":0.17749999463558197,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10611","display_name":"Organic Light-Emitting Diodes Research","score":0.05770000070333481,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/triarylamine","display_name":"triarylamine","score":0.996999979019165},{"id":"https://openalex.org/keywords/substituent-effects","display_name":"substituent effects","score":0.7670000195503235},{"id":"https://openalex.org/keywords/hammett-parameters","display_name":"Hammett parameters","score":0.9340000152587891},{"id":"https://openalex.org/keywords/homo-energy-level","display_name":"HOMO energy level","score":0.9120000004768372},{"id":"https://openalex.org/keywords/electrochemical-properties","display_name":"electrochemical properties","score":0.7870000004768372},{"id":"https://openalex.org/keywords/oxidation-potential","display_name":"oxidation potential","score":0.6800000071525574},{"id":"https://openalex.org/keywords/charge-transport","display_name":"charge transport","score":0.6840000152587891},{"id":"https://openalex.org/keywords/ullmann-condensation","display_name":"Ullmann condensation","score":0.7950000166893005},{"id":"https://openalex.org/keywords/organic-semiconductors","display_name":"organic semiconductors","score":0.6650000214576721}],"concepts":[{"id":"https://openalex.org/C2778689049","wikidata":"https://www.wikidata.org/wiki/Q898422","display_name":"Substituent","level":2,"score":0.9313207864761353},{"id":"https://openalex.org/C2779244968","wikidata":"https://www.wikidata.org/wiki/Q186414","display_name":"Aniline","level":2,"score":0.7186246514320374},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.6670475006103516},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.49560534954071045},{"id":"https://openalex.org/C200093464","wikidata":"https://www.wikidata.org/wiki/Q166583","display_name":"Condensation","level":2,"score":0.4418042302131653},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.39938583970069885},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3659617304801941},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.337592214345932},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.29937875270843506},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28108906745910645},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.15771064162254333},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.1542646288871765},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.07743051648139954}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/cm010281p","doi":"https://doi.org/10.1021/cm010281p","is_oa":false,"landing_page_url":"https://doi.org/10.1021/cm010281p","pdf_url":null,"source":{"id":"https://openalex.org/S66104727","display_name":"Chemistry of Materials","issn_l":"0897-4756","issn":["0897-4756","1520-5002"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry of Materials","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":15,"referenced_works":["https://openalex.org/W1966814641","https://openalex.org/W1989127565","https://openalex.org/W2006787354","https://openalex.org/W2018198233","https://openalex.org/W2020507707","https://openalex.org/W2026838096","https://openalex.org/W2029125182","https://openalex.org/W2051144648","https://openalex.org/W2056395837","https://openalex.org/W2057834459","https://openalex.org/W2069676030","https://openalex.org/W2083877774","https://openalex.org/W2089364837","https://openalex.org/W2950627420","https://openalex.org/W3139641332"],"related_works":["https://openalex.org/W2668640773","https://openalex.org/W2144821221","https://openalex.org/W2052488518","https://openalex.org/W2327817312","https://openalex.org/W2042984582","https://openalex.org/W2343826273","https://openalex.org/W2605772921","https://openalex.org/W2317552540","https://openalex.org/W7165206896","https://openalex.org/W2280000332"],"abstract_inverted_index":{"It":[0],"has":[1],"been":[2,47,95],"found":[3],"that":[4,31],"both":[5,124],"the":[6,18,27,108,117,125,129,132,138],"electrochemical":[7],"and":[8,26,131],"xerographic":[9,83,104],"properties":[10,105],"of":[11,14,29,38,43,52,60,88,92,116,128,137],"a":[12,34,41,66,89],"series":[13,37],"triarylamines":[15],"vary":[16],"with":[17,57,107],"nature":[19],"(quantified":[20],"by":[21,49,65],"its":[22],"Hammett":[23,126],"parameter,":[24],"\u03c3)":[25],"frequency":[28],"substituents":[30],"make":[32],"up":[33],"triarylamine.":[35,139],"Three":[36],"triarylamines,":[39],"encompassing":[40],"total":[42],"35":[44],"compounds,":[45],"have":[46,94],"synthesized":[48],"Ullman":[50],"condensation":[51],"an":[53,58,61],"appropriately":[54,62],"substituted":[55,63],"aniline":[56],"excess":[59],"iodophenylene":[64],"published":[67],"procedure":[68],"[Goodbrand,":[69],"H.":[70],"B.;":[71],"Hu,":[72],"N.":[73],"X.":[74],"J.":[75],"Org.":[76],"Chem.":[77],"1999,":[78],"64":[79],"(2),":[80],"670\u2212674].":[81],"The":[82,102],"properties,":[84,87],"including":[85],"transport":[86],"select":[90],"number":[91],"compounds":[93],"measured":[96,109],"as":[97],"solid-state":[98],"solutions":[99],"in":[100,120],"polycarbonate-Z.":[101],"recorded":[103],"varied":[106],"oxidation":[110],"potential":[111],"(":[112],"E":[113],"1/2":[114],")":[115],"molecule,":[118],"which":[119],"turn":[121],"correlates":[122],"to":[123],"parameter":[127],"substituent":[130],"calculated":[133],"HOMO":[134],"energy":[135],"level":[136]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":5},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":7},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":4}],"updated_date":"2026-09-27T08:07:27.782135","created_date":"2016-06-24T00:00:00"}